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941.
942.
Conversion-type electrode materials are discussed in this critical review. Most of the conversion materials are significantly less expensive than modern intercalation-type materials, and the materials involved are appreciably abundant in the nature. However, up to now, no practically viable battery with conversion material-based electrodes was reported, as there are several major barriers to a practical employment of these materials. First, material utilization and cell energy performance are seriously compromised by a low conductivity of the most conversion materials and by a substantial electrolyte involvement in the electrochemical process. Second, the conversion reactions usually demonstrate a severe volume effect, and also conversion electrodes interact with electrolyte developing thick and resistant solid electrolyte interphase films; both of these features result in impractically low electrode cyclability. Third, a large lithiation/de-lithiation voltage hysteresis results in impractically low charge/discharge energy efficiency and suggests a severe battery heating in the course of the battery operation. All these problems present serious challenges for the researchers in the field; the approaches for handling these issues are discussed in the review. For the foreseeable future, there are grounds to expect progress in tackling some of these issues. The issue of high voltage hysteresis is a bottleneck, though, and it actually precludes conversion materials from any practical application. 相似文献
943.
944.
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946.
Georgy Ivanov Nam-Gyu Kang Alexander Vasil’ev 《Complex Analysis and Operator Theory》2016,10(7):1591-1617
It was realized recently that the chordal, radial and dipolar Schramm–Löwner evolution (SLEs) are special cases of a general slit holomorphic stochastic flow. We characterize those slit holomorphic stochastic flows which generate level lines of the Gaussian free field. In particular, we describe the modifications of the Gaussian free field (GFF) corresponding to the chordal and dipolar SLE with drifts. Finally, we develop a version of conformal field theory based on the background charge and Dirichlet boundary condition modifications of GFF and present martingale-observables for these types of SLEs. 相似文献
947.
948.
Nanoaggregation of the thermally stable bis(2-hydroxy-9(10),16(17),23(24)-tri-tert-butylphthalocyanine) of J-type was observed by the field emission scanning electron microscopy (FE-SEM). Ordered phases, represented as threads composed of about 200 nm diameter circles were discovered, unlike the parent dimeric magnesium complex, in which similar circles combine together to give visually distinguishable zones with widths of about 600 nm and the same distance between them. 相似文献
949.
Leonid Kikot Alexander Lyapunov Tatiana Bogaschenko Sergey Smola Catherine Kulygina 《合成通讯》2013,43(4):478-484
A new facile synthetic route to benzils containing fragments of 12-crown-4, 15-crown-5, and 18-crown-6 by oxidation of corresponding stilbenes was developed. The first representative of a new family of fluorescent sensors was obtained by reaction of bis(15-crown-5)benzil with o-phenylenediamine. The latter exhibits great fluorescence enhancement upon association with K+ and Rb+ compared to Na+ and Cs+. 相似文献
950.
Mladenova Emiliya Burdin Blagoy Milchev Alexander 《Journal of Solid State Electrochemistry》2017,21(6):1567-1569
Journal of Solid State Electrochemistry - Kinetics of electrochemical nucleation and growth of three-dimensional clusters on a foreign substrate are considered in case of multi- and single-step ion... 相似文献