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121.
Multipath arrivals at a receiving sensor are frequently encountered in many signal-processing areas, including sonar, radar, and communication problems. In underwater acoustics, numerous approaches to source localization, geoacoustic inversion, and tomography rely on accurate multipath arrival extraction. A novel method for estimation of time delays and amplitudes of arrivals with maximum a posteriori (MAP) estimation is presented here. MAP estimation is optimal if appropriate statistical models are selected for the data; implementation, requiring maximization of a multidimensional function, is computationally demanding. Gibbs sampling is proposed as an efficient means for estimating necessary posterior probability distributions, bypassing analytical calculations. The Gibbs sampler includes as unknowns time delays, amplitudes, noise variance, and number of arrivals. Through Monte Carlo simulations, the method is shown to have a performance very close to that of analytical MAP estimation. The method is also shown to be superior to expectation-maximization, which is often applied to time-delay estimation. The Gibbs sampling approach is demonstrated to be more informative than other time-delay estimation methods, providing complete posterior distributions compared to just point estimates; the distributions capture the uncertainty in the problem, presenting likely values of the unknowns that are different from simple point estimates. 相似文献
122.
123.
We introduce an efficient lattice regularization scheme for quantum Monte Carlo calculations of realistic electronic systems. The kinetic term is discretized by a finite difference Laplacian with two mesh sizes, a and a', chosen so that the electrons can diffuse in a configuration space which is in practice indistinguishable from the continuum, and the different length scales in the system can be efficiently taken in account. The regularized Hamiltonian goes to the continuous limit for a --> 0 and allows the inclusion of nonlocal potentials in a consistent variational scheme, substantially improving the accuracy upon previous nonvariational approaches. 相似文献
124.
Cusano A Iadicicco A Pilla P Contessa L Campopiano S Cutolo A Giordano M 《Optics letters》2005,30(19):2536-2538
We theoretically and experimentally investigated the reorganization of cladding modes in high-refractive-index- (HRI-) coated long-period gratings (LPGs), focusing on the influence of refractive-index sensitivity. When azimuthally symmetric nanoscale HRI coatings are deposited along LPG devices, a significant modification of the distribution of cladding modes occurs, depending on the layers' features (refractive index and thickness) and on the external refractive index. In particular, if these parameters are properly chosen, a transition between cladding modes and overlay modes occurs. Numerical and experimental effects of the mode transition on the sensitivity of the surrounding refractive index are described. 相似文献
125.
Near a Mott transition, strong electron correlations may enhance Cooper pairing. This is demonstrated in the dynamical mean field theory solution of a twofold-orbital degenerate Hubbard model with an inverted on-site Hund rule exchange, favoring local spin-singlet configurations. Close to the Mott insulator (which here is a local version of a valence bond insulator) a pseudogap non-Fermi-liquid metal, a superconductor, and a normal metal appear, in striking similarity with the physics of cuprates. The strongly correlated s-wave superconducting state has a larger Drude weight than the corresponding normal state. The role of the impurity Kondo problem is underscored. 相似文献
126.
Bolognese A Correale G Manfra M Lavecchia A Novellino E Barone V 《Organic & biomolecular chemistry》2004,2(19):2809-2813
Microwave irradiation of a mixture of benzylidene-anilines and mercaptoacetic acid in benzene gives 1,3-thiazolidin-4-ones in very high yield (65-90%), whereas the same reaction performed through using the conventional method, at reflux temperature, requires a much longer time and gives a much lower yield (25-69%). This difference seems to be due to some intermediates and by-products formed during the conventional reaction. On the basis of 1H NMR studies, two different mechanisms, acting in benzene and in DMF, respectively, have been hypothesized for the thiazolidin-4-one system formation. 相似文献
127.
Boiocchi M Bonizzoni M Fabbrizzi L Foti F Licchelli M Poggi A Taglietti A Zema M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(13):3209-3216
The demetallation in acidic solution of the Cu(II) complexes with open-chain and cyclic tetramines containing a piperazine unit (2 and 3) has been investigated in terms of its kinetic aspects and compared with the behaviour of unsubstituted counterparts (tetramines 1 and 4). The presence of the piperazine fragment slows demetallation of the open-chain-ligand complex owing to the activation barrier associated with the conformational change from boat-to-half-boat; however, it does not affect the demetallation of the macrocyclic complex, which involves the spontaneous boat-to-twist conformational change. Thus, lateral reinforcement of a cyclam-like ligand does not add any further contribution to the typical inertness in demetallation of macrocyclic complexes. 相似文献
128.
Mimmi MC Gullotti M Santagostini L Battaini G Monzani E Pagliarin R Zoppellaro G Casella L 《Dalton transactions (Cambridge, England : 2003)》2004,(14):2192-2201
The dinuclear and trinuclear Cu(II) complexes of an octadentate ligand derived from (S)-1,1'-binaphthyl-2,2'-diamine have been prepared and characterized by UV/Vis, CD, EPR and NMR spectroscopy. The ligand contains two tridentate aminobis(benzimidazole) donor arms connected to a central bidentate diaminobinaphthyl linker, which hosts the chiral unit. In the dinuclear Cu complex the ligation occurs essentially within the tridentate arms of the ligand. The two Cu centers are EPR nonequivalent and noninteracting. The EPR data suggests that one of the Cu ions additionally interacts with one of the tertiary aminonaphthyl donors. In the trinuclear complex the two aminonaphthyl donors bind the third Cu ion. The EPR spectrum of this complex shows the signal for a mononuclear Cu(II) center bound to a tridentate arm, while the remaining two Cu(II) centers are coupled through hydroxo groups. The CD spectrum shows that in the free ligand a severe reduction of the dihedral angle between the naphthyl groups from the strain free range occurs. This conformation is stabilized by ring stacking interactions with the benzimidazole groups. On complex formation this interaction is removed because the benzimidazole groups are involved in metal binding. In the dinuclear Cu complex the conformation of the binaphthyl chromophore probably approaches the strain free range, while in the trinuclear Cu complex a marked flattening of the dihedral angle between the two naphthyl rings occurs. Both complexes are active catalysts in the oxidation of L-/D-Dopa derivatives to quinones. High enantioselectivity is observed in the oxidation of L-/D-Dopa methyl ester catalyzed by the dinuclear Cu complex, which exhibits strong preference for the d enantiomer. The enantioselectivity is largely lost for the trinuclear Cu complex. 相似文献
129.
Villoresi P Bonora S Pascolini M Poletto L Tondello G Vozzi C Nisoli M Sansone G Stagira S De Silvestri S 《Optics letters》2004,29(2):207-209
We present a method for the optimization of high-order harmonic generation based on wave-front correction of the driving laser beam. The technique exploits wave-front adaptive control by means of a deformable mirror, governed by an optimization procedure. 相似文献
130.
N. Beverini G. Carelli A. De Michele M. Finotti N. Ioli A. Moretti 《Applied physics. B, Lasers and optics》2003,77(1):93-95
By means of a new CO2 laser we performed a new investigation of the far-infrared laser emission spectrum of hydrazine excited by the 10P(32) and 10R(8) CO2 laser lines. We found seven new lines and measured the frequency of four of them; moreover we measured the frequencies of two more lines previously reported in the literature with only wavelength measurements. The frequencies of the far-infrared laser emissions have been measured by means of a frequency-synthesis chain based on new InP Schottky diodes. The detected signal was beat-note generated in a Schottky diode between the far-infrared radiation, the harmonics of a 72 GHz frequency reference and a rf signal. We also characterized all of the observed lines by their polarization relative to the pumping CO2 laser, the optimum pressure and the offset relative to the CO2 center frequency. PACS 42.55.Lt; 42.62.Fi 相似文献