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991.
In this paper we introduce a new preconditioner for linear systems of saddle point type arising from the numerical solution of the Navier-Stokes equations. Our approach is based on a dimensional splitting of the problem along the components of the velocity field, resulting in a convergent fixed-point iteration. The basic iteration is accelerated by a Krylov subspace method like restarted GMRES. The corresponding preconditioner requires at each iteration the solution of a set of discrete scalar elliptic equations, one for each component of the velocity field. Numerical experiments illustrating the convergence behavior for different finite element discretizations of Stokes and Oseen problems are included. 相似文献
992.
New predictions for the antineutrino flux from nuclear reactors suggest that reactor experiments may have measured a deficit in this flux, which can be interpreted in terms of oscillations between the known active neutrinos and new sterile states. We perform a reanalysis of global short-baseline neutrino oscillation data in a framework with one or two sterile neutrinos. While one sterile neutrino is still not sufficient to reconcile the signals suggested by reactor experiments and by the LSND and MiniBooNE experiments with null results from other searches, we find that, with the new reactor flux prediction, the global fit improves considerably when two sterile neutrinos are introduced. 相似文献
993.
K(3) picene is a superconducting molecular crystal with a critical temperature of T(c) = 7 or 18 K, depending on the preparation conditions. Using density functional theory we show that electron-phonon interaction accounts for T(c) 3-8 K. The average electron-phonon coupling, calculated by including the phonon energy scale in the electron-phonon scattering, is λ = 0.73 and ω(log) = 18.0 meV. Intercalant and intermolecular phonon modes contribute substantially (40%) to λ as also shown by the isotope exponents of potassium (0.19) and carbon (0.31). The relevance of these modes makes superconductivity in K-doped picene peculiar and different from that of fullerenes. 相似文献
994.
By means of ab initio simulations we here provide a comprehensive scenario for hydrogen oxidation reactions at the Ni/zirconia anode of solid oxide fuel cells. The simulations have also revealed that in the presence of water chemisorbed at the oxide surface, the active region for H oxidation actually extends beyond the metal/zirconia interface unraveling the role of water partial pressure in the decrease of the polarization resistance observed experimentally. 相似文献
995.
In a previous paper the structure and the physical properties of melt mixed polyamide 66 (PA66)/polyamide 12 (PA12) blends characterized by different compositions have been investigated by means of morphological and physical analyses. A low amount of organically‐modified layered silicate (OMLS, 4 wt%) was introduced in order to evaluate its effect on blends structure and components miscibility. This paper completes the characterization of these materials investigating their thermal properties by means of standard and modulated differential scanning calorimetry (DSC, MDSC), dynamic‐mechanical analysis (DMA), and thermogravimetric analysis (TGA). The partial miscibility of PA66 and PA12, with phase separation depending on blend composition, has been confirmed by analyzing the glass transition temperature (Tg) dependence on composition as well as the existence of strong segmental interactions between polymer components. A compatibilizing action of OMLS has been observed because of a lowering of interfacial tension avoiding coalescence phenomena between particles during melt mixing process. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
996.
Xue C Yonet-Tanyeri N Brouette N Sferrazza M Braun PV Leckband DE 《Langmuir : the ACS journal of surfaces and colloids》2011,27(14):8810-8818
The protein resistance of poly(N-isopropylacrylamide) brushes grafted from silicon wafers was investigated as a function of the chain molecular weight, grafting density, and temperature. Above the lower critical solution temperature (LCST) of 32 °C, the collapse of the water-swollen chains, determined by ellipsometry, depends on the grafting density and molecular weight. Ellipsometry, radio assay, and fluorescence imaging demonstrated that, below the lower critical solution temperature, the brushes repel protein as effectively as oligoethylene oxide-terminated monolayers. Above 32 °C, very low levels of protein adsorb on densely grafted brushes, and the amounts of adsorbed protein increase with decreasing brush-grafting-densities. Brushes that do not exhibit a collapse transition also bind protein, even though the chains remain extended above the LCST. These findings suggest possible mechanisms underlying protein interactions with end-grafted poly(N-isopropyl acrylamide) brushes. 相似文献
997.
Dessy A Kubowicz S Alderighi M Bartoli C Piras AM Schmid R Chiellini F 《Colloids and surfaces. B, Biointerfaces》2011,87(2):236-242
Therapeutic properties of Dead Sea Water (DSW) in the treatment of skin diseases such as atopic dermatitis, psoriasis and photo aging UV damaged skin have been well established. DSW is in fact rich in minerals such as calcium, magnesium, sodium, potassium, zinc and strontium which are known to exploit anti-inflammatory effects and to promote skin barrier recovery. In order to develop a Dead Sea Minerals (DSM) based drug delivery system for topical therapy of skin diseases, polymeric nanoparticles based on Poly (maleic anhydride-alt-butyl vinyl ether) 5% grafted with monomethoxy poly(ethyleneglycol) 2000 MW (PEG) and 95% grafted with 2-methoxyethanol (VAM41-PEG) loaded with DSM were prepared by means of a combined miniemulsion/solvent evaporation process. The resulting nanoparticles were characterized in terms of dimension, morphology, biocompatibility, salt content and release. Cytocompatible spherical nanoparticles possessing an average diameter of about 300 nm, a time controlled drug release profile and a high formulation yield were obtained. 相似文献
998.
Stefano Toffanin Raffaella Capelli Wouter Koopman Gianluca Generali Susanna Cavallini Andrea Stefani Davide Saguatti Giampiero Ruani Michele Muccini 《Laser \u0026amp; Photonics Reviews》2013,7(6):1011-1019
Organic light‐emitting transistors (OLETs) are multifunctional optoelectronic devices that hold great promise for a variety of applications, including flat panel displays, integrated light sources for sensing and optical communication systems. The narrow illumination area within the device channel is considered intrinsic to the device architecture and is a severe technological drawback for all those applications where a controlled, wide and homogeneous emission area is required. Here it is shown that not only the position but also the extension of the emission area is voltage‐tunable, and the entire channel of the transistor can be homogeneously illuminated. The modeling of the exciton distribution within the channel at the different bias conditions coupled to the modeling of the device emission profile highlights that excitons are spread through the entire channel width and across the bulk of the central emission layer of the p‐channel/emitter/n‐channel trilayer active heterostructure. 相似文献
999.
Hamza Bouzid Mario Prosa Margherita Bolognesi Nadia Chehata Desta Gedefaw Cristiano Albonetti Mats R. Andersson Michele Muccini Abdelaziz Bouazizi Mirko Seri 《Journal of polymer science. Part A, Polymer chemistry》2019,57(4):487-494
High‐performance polymer solar cells (PSCs) are typically fabricated by spin coating in inert atmosphere from toxic halogenated solvents such as 1,2‐dichlorobenzene (o‐DCB) and chlorobenzene. This fabrication process is potentially hazardous for both the humans and the environment and dramatically impacts the possibility for the organic photovoltaic technology to be adopted at large scale. In this work, efficient PSCs blade coated in air using nonhalogenated 1,2,4‐trimethylbenzene (TMB) as processing solvent are demonstrated. The active layer, based on a previously synthesized benchmark polymer PFQ2T‐benzodithiophene blended with [6,6]‐phenyl‐C61‐butyric acid methyl ester (PC61BM), showed an enhanced solid‐state aggregation induced by the use of TMB. Compared to o‐DCB‐processed devices, the solar cells fabricated from TMB resulted 10% more efficient with a power conversion efficiency of 4.20%. Interestingly, the improved photovoltaic performance resulted from the combination of synergic effects promoted by a more favorable film morphology, such as high exciton dissociation efficiency and lower bimolecular recombinations resulting in higher charge collection efficiency at the electrodes. The positive effect of TMB, compared to that of commonly employed halogenated solvents, confirms the great potential of this approach for the development of efficient PSCs for practical applications with reduced environmental impact. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 487–494 相似文献
1000.
De Filippo Michele Kuang Jun Shang 《Journal of Optimization Theory and Applications》2021,190(2):540-564
Journal of Optimization Theory and Applications - Nowadays, large part of the technical knowledge associated with collapses of slabs is based on past failures of bridges, floors, flat roofs and... 相似文献