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11.
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A. Dönni P. Fischer A. Furrer P. Bonville F. Hulliger H. R. Ott 《Zeitschrift für Physik B Condensed Matter》1990,81(1):83-88
A polycrystalline smaple of nonstoichiometric ytterbium phosphide, YbP0.84, was investigated by neutron scattering, Mössbauer spectroscopy and bulk magnetic measurements. Neutron diffraction experiments prove the existence of antiferromagnetic type II ordering belowT
N
=0.64 K, in contrast to the observed antiferromagnetic type III ordering in the stoichiometric Kondo-like compounds YbN and YbAs. The temperature dependence of the average ordered magnetic moment per Yb3+ ion with saturation value Yb = 1.03(7)
B
is similar to that of YbN. Mössbauer experiments prove the magnetic phase transition to be first order with different regions in the sample having slightly different transition temperatures. By means of inelastic neutron scattering the crystal-field level scheme was established to be
6 –
8(19meV) –
7(43meV). 相似文献
13.
The variable exo/endo rate ratios observed in the solvolysis of 6-exo-substituted exo- and endo-2-norbornyl p-toluenesulfonates are due to differential transmission of polar effects in the transition state for ionization. 相似文献
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The Nature of the vibronic intensity borrowing mechanism in the 1B3u(n)1Ag() transition of pyrazine
The transition intensities of the S0S1 gas phase absorption spectra of pyrazine-d0 and -d4 were carefully measured. A discussion of the various aspects of vibronic intensity borrowing for this unique case is presented using our new experimental results. 相似文献
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W. Bell K. Braune G. Claesson D. Drijard M. A. Faessler H. G. Fischer H. Frehse R. W. Frey S. Garpman W. Geist C. Gruhn P. Hanke M. Heiden W. Herr P. G. Innocenti T. J. Ketel E. E. Kluge I. Lund G. Mornacchi T. Nakada I. Otterlund M. Panter B. Povh A. Putzer E. Stenlund T. J. M. Symons R. Szwed O. Ullaland 《Zeitschrift fur Physik C Particles and Fields》1986,30(4):513-520
Properties of secondaries associated with a high-p T charged trigger particle (3<p T <5 GeV/c) were studied for αp and αα interactions at c.m. energies \(\sqrt s = 88\) GeV and 125 GeV, respectively. Thep T distributions of secondaries in the away-jet and trigger-jet regions were compared with those for high-p T pp interactions. No statistically significant differences were seen, except at lowp T . Momentum and angular distributions of spectator and leading protons were studied as a function of charge and rapidity of the trigger hadron. The observed correlations between trigger charge and number of spectator protons provide evidence of valence quark contributions to the trigger jet. 相似文献
20.
Cushman M Yang D Gerhardt S Huber R Fischer M Kis K Bacher A 《The Journal of organic chemistry》2002,67(16):5807-5816
A series of 6-carboxyalkyl and 6-phosphonoxyalkyl derivatives of 7-oxo-8-D-ribityllumazine were synthesized as inhibitors of both Escherichia coli riboflavin synthase and Bacillus subtilis lumazine synthase. The compounds were designed to bind to both the ribitylpurine binding site and the phosphate binding site of lumazine synthase. In the carboxyalkyl series, maximum activity against both enzymes was observed with the 3'-carboxypropyl compound 22. Lengthening or shortening the chain linking the carboxyl group to the lumazine by one carbon resulted in decreased activity. In the phosphonoxyalkyl series, the 3'-phosphonoxypropyl compound 33 was more potent than the 4'-phosphonoxybutyl derivative 39 against lumazine synthase, but it was less potent against riboflavin synthase. Molecular modeling suggested that the terminal carboxyl group of 6-(3'-carboxypropyl)-7-oxo-8-D-ribityllumazine (22) may bind to the side chains of Arg127 and Lys135 of the enzyme. A hypothetical molecular model was also constructed for the binding of 6-(2'-carboxyethyl)-7-oxolumazine (15) in the active site of E. coli riboflavin synthase, which demonstrated that the active site could readily accommodate two molecules of the inhibitor. 相似文献