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991.
Michael Eyer Karl Schlögl Michael Widhalm 《Monatshefte für Chemie / Chemical Monthly》1984,115(12):1429-1442
Chiral title compounds have been resolved by medium pressure liquid chromatography (MPLC) on triacetylcellulose in ethanol. Whereas a quantitative separation was achieved for16 and20, a recycling technique had to be applied to1,4,6,10 and15 leading to a 100% e.e. for1,6 and15 and to ca. 60% e.e. for4 and10.An unambiguous assignment of the chirality (+)-(R)
a
-(S)
m
for tricarbonylchromium-6,6-dimethyl-diphenicacid dimethylester (4) was deduced both from the photochemical decomplexation to (-)-5 with the known chirality (R)
a
(whose e.e. was determined by MPLC on triacetylcellulose) and by comparison of the1H-n.m.r. spectra of4 and5 thereby proving the structure 4 for the former.Other chiralities both for mono and bis(tricarbonylchromium)biphenyl complexes were established by chemical correlations and comparison of the CD spectra with those of key compounds.
Herrn Prof. Dr.H. Tuppy mit besten Wünschen zum 60. Geburtstag gewidmet. 相似文献
992.
-The luminescence at 1.27 μm from the 3 →→1 δg transition of the oxygen molecule has been detected from a variety of liquid systems. A Q-switched laser delivering pulses of 532 nm light was the excitation source, a germanium photodiode was the detector and substituted porphyrins were used as photosensitizers. Protio- and deutero- forms of several solvents were studied and the singlet oxygen lifetimes determined directly agreed well with published values. Tδ in D2 O was found to be 55 μs and, by extrapolation from a series of H2 O - D2 O mixtures, a value of 3.3 μs was obtained for Tδ in H2 O. The technique was shown to be useful in measuring Tδ values in several microheterogeneous systems such as surfactant micelles, vesicles and human serum albumin. 相似文献
993.
J.E. House Jr. G.L. Jeyaraj David A. Engel Michael D. Lowery 《Thermochimica Acta》1983,70(1-3):189-193
The decomposition of Li2S2O6·2 H2O, Na2S2O6·2 H2O, and MgS2O6·7 H2O has been studied using TG and DTG. Both sodium and lithium dithionates dehydrate in one step. Magnesium dithionate dehydrates in three separate steps. All three of the dithionates undergo further decomposition and lose sulfur dioxide to give stable sulfates. Kinetic parameters are presented for these reactions. 相似文献
994.
Abstract— The rate constant for total quenching of singlet oxygen by ascorbic acid has been determined using the inhibition of the bleaching of 9, 10-dimethylanthracene by AA in pyridine. The rate constant was 8.4 × 10-6 M -1 s-1 , as determined photochemically, and 1.06 10-7 M -1 s-1 as determined in a dark reaction. 相似文献
995.
David Wei Wang Michael M. Fisher 《Journal of polymer science. Part A, Polymer chemistry》1983,21(3):671-677
A two-phase polycondensation reaction was used to prepare high molecular weight linear poly-(amino-s-triazine)s from aminodichloro-s-triazines and diamines. These polymers contain a high concentration of melamine-type units in the polymer backbone. Molded specimens exhibited good mechanical properties and resistance to organic solvents. Dimethyl substitution at the exocyclic amino group led to a significant reduction in indentation resistance, strength, and modulus. 相似文献
996.
997.
998.
Busby M Hartl F Matousek P Towrie M Vlcek A 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(23):6912-6923
Two multifunctional photoactive complexes [Re(Cl)(CO)(3)(MeDpe(+))(2)](2+) and [Re(MeDpe(+))(CO)(3)(bpy)](2+) (MeDpe(+)=N-methyl-4-[trans-2-(4-pyridyl)ethenyl]pyridinium, bpy=2,2'-bipyridine) were synthesized, characterized, and their redox and photonic properties were investigated by cyclic voltammetry; ultraviolet-visible-infrared (UV/Vis/IR) spectroelectrochemistry, stationary UV/Vis and resonance Raman spectroscopy; photolysis; picosecond time-resolved absorption spectroscopy in the visible and infrared regions; and time-resolved resonance Raman spectroscopy. The first reduction step of either complex occurs at about -1.1 V versus Fc/Fc(+) and is localized at MeDpe(+). Reduction alone does not induce a trans-->cis isomerization of MeDpe(+). [Re(Cl)(CO)(3)(MeDpe(+))(2)](2+) is photostable, while [Re(MeDpe(+))(CO)(3)(bpy)](2+) and free MeDpe(+) isomerize under near-UV irradiation. The lowest excited state of [Re(Cl)(CO)(3)(MeDpe(+))(2)](2+) has been identified as the Re(Cl)(CO)(3)-->MeDpe(+ 3)MLCT (MLCT=metal-to-ligand charge transfer), decaying directly to the ground state with lifetimes of approximately 42 (73 %) and approximately 430 ps (27 %). Optical excitation of [Re(MeDpe(+))(CO)(3)(bpy)](2+) leads to population of Re(CO)(3)-->MeDpe(+) and Re(CO)(3)-->bpy (3)MLCT states, from which a MeDpe(+) localized intraligand (3)pipi* excited state ((3)IL) is populated with lifetimes of approximately 0.6 and approximately 10 ps, respectively. The (3)IL state undergoes a approximately 21 ps internal rotation, which eventually produces the cis isomer on a much longer timescale. The different excited-state behavior of the two complexes and the absence of thermodynamically favorable interligand electron transfer in excited [Re(MeDpe(+))(CO)(3)(bpy)](2+) reflect the fine energetic balance between excited states of different orbital origin, which can be tuned by subtle structural variations. The complex [Re(MeDpe(+))(CO)(3)(bpy)](2+) emerges as a prototypical, multifunctional species with complementary redox and photonic behavior. 相似文献
999.
The effect of the addition of two cationic surfactants of different chain length (decyl and dodecyl trimethylammonium bromide, DeTMABr and DTMABr, respectively) and one anionic surfactant of identical chain length (sodium dodecyl sulfate, SDS) on phase behavior, structure, and macroscopic properties of a bilayer forming nonionic surfactant (Brij 30) has been investigated by means of phase studies, rheology, turbidity measurements, dynamic light scattering, and freeze-fracture transmission electron microscopy. We concentrated on DTMABr because of the generically similar behavior for the other ionic surfactants. It is found that already very small amounts of added ionic surfactant have a very pronounced effect on the phase behavior of these systems. The pure nonionic surfactant forms bilayers and has a tendency for the formation of vesicles which becomes enhanced by charging the bilayer through the incorporation of the ionic surfactant. The presence of the ionic surfactant leads to much more viscous systems, which already at a total surfactant concentration of 150 mM become gel-like. For a given surfactant concentration, the elastic properties of the gels increase largely upon the addition of ionic surfactant. This effect is strongly synergistic, requiring only very small amounts of added ionic surfactant, and the elastic properties pass through a maximum for a content of ionic surfactant of about 3-5 mol %. This behavior can be explained in a self-consistent way by a simple rheological model and by combining it with light scattering data. For the addition of larger amounts, the elastic properties decrease again and the formed vesicles become structurally less defined as one is leaving the range of conditions for forming well-defined vesicles, which are required for forming elastic vesicle gels. 相似文献
1000.
Transgenic plants offer a promising system for large-scale production of therapeutic proteins such as monoclonal antibodies (mAbs). This paper describes a membrane-based process suitable for purification of a humanized mAb expressed in tobacco. Most monoclonal antibody purification schemes rely on the use of Protein A as the affinity ligand for antibody capture. The main objective of our work was to develop non-Protein A-based purification methods to avoid some of the problems and limitations associated with this ligand, e.g. cost, immunotoxicity, and antibody aggregation during elution. Ion exchange membrane chromatography (IEMC) was used for primary capture and preliminary purification of the mAb from tobacco juice. Hydrophobic interaction membrane chromatography (HIMC) was then used for high-resolution purification, followed by ultrafiltration for polishing, desalting and buffer exchange. Using this scheme, both high mAb purity (single peak in size exclusion chromatogram, i.e., ca. 100% purity) and high recovery (77% of mAb spiked into the tobacco extract) were achieved. Membrane chromatography is generally considered unsuitable for resolving bound proteins by gradient elution and is therefore commonly used in the bind and elute mode with a single-step change of mobile phase. We show that the gradient elution process in the HIMC step can be optimized to increase the resolution and thereby obtain product of high purity. 相似文献