Applications of fast atom bombardment mass spectrometry (FAB MS) to organometallic and coordination chemistry

This article describes the technique of fast atom bombardment mass spectrometry (FAB MS) and its applications to the analysis of organometallic and coordination complexes. Sections on ion generation and matrices are followed by a Periodic Group-based review of FAB MS results obtained from Transition Metal and Main Group compounds, organometallic cluster carbonyls and their derivatives, and salts of poly-oxo-anions. The literature has been surveyed from 1981 to approximately mid-1986.     

The driving torque of a rotating levitated cylindrical permanent magnet above a superconductor

Due to the Meissner effect, a permanent magnet is levitated, when released above a high temperature superconductor. When there is an inhomogeneous temperature field around the magnet, the magnet might start to oscillate with increasing amplitude until it remains in a continuous rotation. A mathematical model for the described effect is presented which couples heat transfer and electromagnetic forces with the equation of motion, yielding to a multiphysics task. In a detailed analysis it is found, that the torque which drives the rotation of the magnet, is explicitly given in terms of Bessel functions and the Fourier coefficients of order zero and one of the temperature field of the surrounding air.     

Time interval distributions of atoms in atomic beams

We report an experimental investigation of two-particle correlations between neutral atoms in a Hanbury Brown and Twiss experiment. Both an atom laser beam and a pseudo-thermal atomic beam are extracted from a Bose–Einstein condensate and the atom flux is measured with a single atom counter. We determine the conditional and the unconditional detection probabilities for the atoms in the beam and find good agreement with the theoretical predictions. PACS 03.75.Pp; 05.30.Jp; 07.77.Gx; 42.50.Pq     

Scale invariance rule in electromagnetic scattering

The volume integral equation formalism is used to prove the scale invariance rule for an arbitrarily sized scatterer with an arbitrary shape, morphology, and orientation. The only assumptions are that the scatterer is made of optically isotropic linear materials and is embedded in a homogeneous, linear, isotropic, and nonabsorbing infinite medium.     

A finite cutting plane method for facial disjunctive programs

This paper shows that any linear disjunctive program with a finite number of constraints can be transformed into an equivalent facial program. Based upon linear programming technique, a new, finite cutting plane method is presented for the facial programs.

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Zusammenfassung Die Arbeit zeigt, daß jedes lineare disjunktive Optimierungsproblem mit endlich vielen Restriktionen in ein äquivalentes Fazetten-Problem transformiert werden kann. Auf der Grundlage von linearer Optimierungstechnik wird für das Fazetten-Problem ein neues, endliches Schnittebenenverfahren vorgestellt.

     

Fejér means of functions on noncommutative Vilenkin groups with respect to the character system

Summary It is known that the Fejér means - with respect to the character system of the Walsh, and bounded Vilenkin groups - of an integrable function converge to the function a.e. In this work we discuss analogous problems on the complete product of finite, not necessarily Abelian groups with respect to the character system for functions that are constant on the conjugacy classes. We find that the nonabelian case differs from the commutative case. We prove the a.e. convergence of the (C,1) means of the Fourier series of square integrable functions. We also prove the existence of a function f∊L^q for some q >1 such that sup |σ_n f | = + ∞ a.e. This is a sharp contrast between the Abelian and the nonabelian cases.     

Uniqueness of the group topology of some homeomorphism groups

In this paper, we generalize a theorem of Kallman [2, Theorem 1.1] and we resolve the unsettled case there.     

Estimating the largest singular values of large sparse matrices via modified moments

We describe a procedure for determining a few of the largest singular values of a large sparse matrix. The method by Golub and Kent which uses the method of modified moments for estimating the eigenvalues of operators used in iterative methods for the solution of linear systems of equations is appropriately modified in order to generate a sequence of bidiagonal matrices whose singular values approximate those of the original sparse matrix. A simple Lanczos recursion is proposed for determining the corresponding left and right singular vectors. The potential asynchronous computation of the bidiagonal matrices using modified moments with the iterations of an adapted Chebyshev semi-iterative (CSI) method is an attractive feature for parallel computers. Comparisons in efficiency and accuracy with an appropriate Lanczos algorithm (with selective re-orthogonalization) are presented on large sparse (rectangular) matrices arising from applications such as information retrieval and seismic reflection tomography. This procedure is essentially motivated by the theory of moments and Gauss quadrature.This author's work was supported by the National Science Foundation under grants NSF CCR-8717492 and CCR-910000N (NCSA), the U.S. Department of Energy under grant DOE DE-FG02-85ER25001, and the Air Force Office of Scientific Research under grant AFOSR-90-0044 while at the University of Illinois at Urbana-Champaign Center for Supercomputing Research and Development.This author's work was supported by the U.S. Army Research Office under grant DAAL03-90-G-0105, and the National Science Foundation under grant NSF DCR-8412314.