全文获取类型
收费全文 | 203432篇 |
免费 | 3008篇 |
国内免费 | 972篇 |
专业分类
化学 | 114228篇 |
晶体学 | 2725篇 |
力学 | 8318篇 |
综合类 | 8篇 |
数学 | 23531篇 |
物理学 | 58602篇 |
出版年
2021年 | 1387篇 |
2020年 | 1669篇 |
2019年 | 1682篇 |
2018年 | 1529篇 |
2017年 | 1534篇 |
2016年 | 3206篇 |
2015年 | 2684篇 |
2014年 | 3408篇 |
2013年 | 9288篇 |
2012年 | 8255篇 |
2011年 | 10161篇 |
2010年 | 6100篇 |
2009年 | 6136篇 |
2008年 | 9363篇 |
2007年 | 9196篇 |
2006年 | 8917篇 |
2005年 | 8314篇 |
2004年 | 7380篇 |
2003年 | 6310篇 |
2002年 | 6163篇 |
2001年 | 6496篇 |
2000年 | 5015篇 |
1999年 | 3859篇 |
1998年 | 2991篇 |
1997年 | 3013篇 |
1996年 | 2989篇 |
1995年 | 2577篇 |
1994年 | 2522篇 |
1993年 | 2353篇 |
1992年 | 2648篇 |
1991年 | 2579篇 |
1990年 | 2262篇 |
1989年 | 2207篇 |
1988年 | 2227篇 |
1987年 | 2178篇 |
1986年 | 2050篇 |
1985年 | 3124篇 |
1984年 | 3069篇 |
1983年 | 2467篇 |
1982年 | 2708篇 |
1981年 | 2525篇 |
1980年 | 2502篇 |
1979年 | 2393篇 |
1978年 | 2467篇 |
1977年 | 2401篇 |
1976年 | 2320篇 |
1975年 | 2291篇 |
1974年 | 2169篇 |
1973年 | 2222篇 |
1972年 | 1278篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
12.
NaY zeolite samples loaded with sodium metal by vapor phase deposition have been investigated using129Xe NMR spectroscopy. At low sodium concentration, the129Xe NMR spectrum showed three resonance lines which clearly indicate the existence of distinct domains in the zeolite sample. Such an observation suggests that the diffusion of the xenon atoms into each domain only occurs with respect to the NMR time scale (2.9 ms). As the sodium concentration increases, observation of a single broad line indicate a macroscopic homogenization of the system. The shift of this line is explained in part due to a paramagnetic interaction between the xenon atoms and the unpaired electrons of particles containing an odd number of sodium atoms. The linewidth is due to the distribution of the local magnetic fields partially averaged by the rapid motion of the xenon atoms and to the statistical distribution of the sodium particles in the supercage cavities. The paramagnetic interaction vanishes with the oxidation of the sample leading to a narrowing and a shift of the line to higher magnetic fields. 相似文献
13.
14.
15.
16.
A. J. Parsons S. D. J. Inglethorpe D. J. Morgan A. C. Dunham 《Journal of Thermal Analysis and Calorimetry》1997,48(1):49-62
Using a system based on non-dispersive infrared (NDIR) detectors, evolved gas analysis (EGA) was able to identify and quantify the principal volatiles produced by heating powdered samples of UK brick clays. From these results, atmospheric emissions likely to result from brick production can be predicted. In addition, EGA results for extruded brick clay test pieces are significantly different from those of powdered samples. Within an extruded brick clay body, evolved gases are contained within a pore system and evolved gas-solid phase reactions also occur. This EGA study provides further evidence on the nature of firing reactions within brick clay bodies. The qualitative and quantitative influence of heating rate — a key process condition in brick manufacture — on gas release is also outlined.Dedicated to Dr. Robert Mackenzie on the occasion of his 75th birthday 相似文献
17.
The effect of iodine sorption on the free volume of polycarbonate is investigated by Positron Annihilation Lifetime method.
The observed results are interpreted in terms of the Charge Transfer Complex formation and precipitation of iodine at the
initial and final stages of sorption, respectively. At higher levels of sorption, changes in the second lifetime and its intensity
seem to suggest a conformational transformation, probably due to the net change in the amorphous-crystalline boundary regions
of the polymer matrix. The free volume cavities have been predominantly occupied by I-
3 species and the diffusion process obeys Fick’s law. An exponential type correlation has been observed between fractional
free volume and the diffusion coefficient.
Received: 13 June 1996/Accepted: 20 September 1996 相似文献
18.
Summary Experiments and simulations prove that correlation chromatography can greatly reduce the disadvantage of a non-linear response of the chromatographic column. A factor that has been accepted as being an important source of error in correlation or multiplex chromatography, has been shown not to be. Separations affected, improve dramatically when correlation chromatography is used, and a substantial amount of correlation noise only arises when there is a large difference in separation between a conventional chromatogram and a correlogram.A model has been developed for simulating these nonlinearities. It is shown that, especially for correlation chromatography, the simulation results match the practical measurements very well. 相似文献
19.
20.
J. Escudi C. Couret H. Ranaivonjatovo J. Satge 《Coordination chemistry reviews》1994,130(1-2):427-480
During the last 10 years, several compounds of the type Ge=X (X = C, Ge, N, P, S) have been isolated as monomers. The stabilization of such derivatives, which are generally highly polymerizable, was achieved by using very bulky groups both on the germanium atom and on the heteroelement X. Conjugation (particularly in a few germenes and germaimines) and intramolecular or intermolecular coordination with oxygen or nitrogen, also contributes, in some cases, to the stabilization. The X-ray analyses of such compounds show a significant bond shortening of the double bond (8–10%) relative to the corresponding single bond and a planar or nearly planar germanium. These doubly bonded germanium derivatives are usually thermally stable but must be handled in an inert atmosphere because of their high sensitivity to oxygen and moisture; they are extremely reactive, much more than the corresponding carbon analogues. Nearly quantitative additions on the double bond have been observed with electrophiles and nucleophiles, and various types of cycloadditions also occur. Except in one case, a germylene behavior has not been observed, proving that such compounds retain their structural integrity in solution. 相似文献