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941.
Fe2O3--V2O5 catalysts doped with Cs2SO4 (molar ratio: V:Fe:Cs=1:0.74:0.06) were found to be a rather inhomogeneous mixture of various crystalline and amorphous iron
vanadate phases. After calcination in air the catalyst was divided into three different parts which were analyzed separately
revealing the formation of FeVO4 in the top and bottom fraction of the crucible and Fe2V4O13 in the middle fraction. As compared to the well crystallized FeVO4 reference sample, the quadrupole splittings of FeVO4 in the Cs-doped catalysts were larger pointing to more distorted iron sites which were assumed to be responsible for high
catalytic selectivities. In contrast, the quadrupole splittings of FeVO4 in the less selective K- and Rb-doped Fe2O3--V2O5 catalysts were smaller. Additional components in the bottom fraction were also α-Fe2O3 and Fe1-xS. As indicated by the CEMS spectra the latter is located preferentially on the surface of the catalyst particles.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
942.
A. S. Romanyuk 《Ukrainian Mathematical Journal》1997,49(9):1409-1422
We obtain order estimates for some approximate characteristics of the Besov classes B
p,ϑ
r
of periodic functions of many variables.
Institute of Mathematics, Ukrainian Academy of Sciences, Kiev. Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 49,
No. 9, pp. 1250–1261, September, 1997. 相似文献
943.
Based on polarization measurements of the low-frequency Raman spectra of p-bromochlorobenzene and calculations of the frequency spectra of lattice vibrations by the Dean method it is shown that the
structure may contain vacancies. Their presence affects the appearance of additional lines in the low-frequency spectrum,
particularly in the vicinity of 70 cm−1, and their positions depend weakly on the orientational disorder of the molecules with respect to the para substituents. The activation energies for diffusion in a randomly disordered p-bromochlorobenzene crystal with vacancies in the structure is calculated from atom-atom potentials. It is shown that the
value of the activation energy varies along a selected direction and depends on the arrangement of the p-bromochlorobenzene molecules with respect to the para substituents, in contrast to the results for ordered p-dibromobenzene and p-dichlorobenzene.
Fiz. Tverd. Tela (St. Petersburg) 40, 1835–1838 (October 1998) 相似文献
944.
The possibility of the existence of a magnetostatic analog of Love surface elastic waves is predicted. They appear in situations
where the conditions for the existence of magnetostatic volume waves hold in the upper layer of a ferromagnetic bilayer, but
not in the lower layer.
Zh. Tekh. Fiz. 68, 85–90 (October 1998) 相似文献
945.
A. P. Golub 《Ukrainian Mathematical Journal》1989,41(6):690-694
Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 41, No. 6, pp. 803–808, June, 1989. 相似文献
946.
A simple experimental technique using an instrumented pin was developed for the measurement of the load-contact variation in a clearance-fit, pin-loaded hole. The method is applicable to both conducting and nonconducting materials. 相似文献
947.
In this paper, we introduce a new class of function systems generalizing the classical Faber-Schauder system. Under the condition that the generating sequence is bounded, we show that systems of such a class constitute bases in the space of continuous functions and prove some properties of series expansions of functions in these systems. 相似文献
948.
A. S. Mart’yanov 《Mathematical Notes》2007,82(1-2):57-66
In this paper, we study a dynamic reconstruction algorithm which reconstructs the unknown unbounded input and all unobservable phase coordinates from the results of measurements of part of the coordinates. An upper and a lower bound for the accuracy of the reconstruction is obtained. We determine the class of inputs for which the upper bound is uniform. We give a condition for optimally matching the algorithm parameters, ensuring the highest order of the upper bound and equating the orders of the upper and lower bounds. Thus, we establish the sharpness of the upper bound. 相似文献
949.
Mechanisms for the formation of toxisterol A are suggested. The connection between the conformation of the initial previtamin and the stereochemistry of the reaction products is discussed.Lensoviet Leningrad Technological Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 225–229, March–April, 1989. 相似文献
950.