Imaging and analysis of photomechanical effects induced in water by high-power laser-target interaction

The kinetics of cavitation and associated photo-mechanical effects induced by underwater pulsed-laser irradiation of solid targets has been studied experimentally and analyzed with theoretical methods. A xenon-chloride excimer laser of 150 ns pulse duration has been utilized to produce ablation and local photofragmentation of artificial samples of hard tissues at fluences of 12–24 J/cm². The evolution of pressure wave and cavitation formations developing in the liquid from the target surface after laser irradiation has been observed with a time-resolved imaging technique employing a pump-probe laser arrangement. The analysis of experimental results has been performed by using the theoretical model of point explosion that has been successfully applied to fit the cavitation kinetics, providing also quantitative information on the energy transfer during photo-acoustic interactions.     

Thermal behavior and crystallization kinetics of random poly(ethylene‐Co‐2,2‐Bis[4‐(ethylenoxy)‐1,4‐phenylene]propane terephthalate) copolyesters

The thermal behavior of poly(ethylene‐co‐2,2‐bis[4‐(ethylenoxy)‐1,4‐phenylene]propane terephthalate) (PET/BHEEBT) copolymers was investigated by thermogravimetric analysis and differential scanning calorimetry. A good thermal stability was found for all the samples. The thermal analysis carried out using DSC technique showed that the T_m of the copolymers decreased with increasing BHEEBT unit content, differently from T_g, which on the contrary increased. Wide‐angle X‐ray diffraction measurements permitted identifying the kind of crystalline structure of PET in all the semicrystalline samples. The multiple endotherms similar to PET were also evidenced in the PET/BHEEBT samples, due to melting and recrystallization processes. By applying the Hoffman–Weeks' method, the T_m° of PET and its copolymers was derived. The isothermal crystallization kinetics was analyzed according to Avrami's treatment and values of the exponent n close to 3 were obtained, independently of T_c and composition. Moreover, the introduction of BHEEBT units was found to decrease PET crystallization rate. Lastly, the presence of a crystal‐amorphous interphase was evidenced. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 1441–1454, 2005     

Excitation of the dynamical dipole in the charge asymmetric reaction O + Sn

The γ-ray emission from the dynamical dipole formed in heavy-ion collisions during the process leading to fusion was measured for the N/Z asymmetric reaction ¹⁶O + ¹¹⁶Sn at beam energies of 8.1 and 15.6 MeV/nucleon. High-energy γ-rays and charged particles were measured in coincidence with the heavy recoiling residual nuclei. The data are compared with those from the N/Z symmetric reaction ⁶⁴Ni + ⁶⁸Zn at bombarding energies of 4.7 and 7.8 MeV/nucleon, leading to the same CN with the same excitation energies as calculated from kinematics. The measured yield of the high-energy γ-rays from the ¹⁶O-induced reaction is found to exceed that of the thermalized CN and the excess yield increases with bombarding energy. The data are in rather good agreement with the predictions for the dynamical dipole emission based on the Boltzmann–Nordheim–Vlasov model. In addition, a comparison with existing data in the same mass region is performed to extract information on the dipole moment dependence.     

New stereoselective beta-C-glycosidation by uncatalyzed 1,4-addition of organolithium reagents to a glycal-derived vinyl oxirane

[reaction: see text] Epoxide 4 is generated in situ from d-glucal-derived hydroxy mesylate 3. Reaction of epoxide 4 with a series of alkyl- and aryllithium reagents affords 2,3-unsaturated beta-C-glycosides with excellent 1,4-regioselectivity and complete stereoselectivity for the beta-glycoside. Other organometallic reagents demonstrate more complex behavior in their reactions with epoxide 4.     

Anisotropic admixture in color-superconducting quark matter

The analysis of color-superconducting two-flavor deconfined quark matter at moderate densities is extended to include a particular spin-1 Cooper pairing of those quarks which do not participate in the standard spin-0 diquark condensate. (i) The relativistic spin-1 gap delta(') implies spontaneous breakdown of rotation invariance manifested in the form of the quasifermion dispersion law. (ii) The critical temperature of the anisotropic component is approximately given by the relation T(')(c) approximately delta(')(T=0)/3. (iii) For massless fermions the gas of anisotropic Bogolyubov-Valatin quasiquarks becomes effectively gapless and two dimensional. Consequently, its specific heat depends quadratically on temperature. (iv) All collective Nambu-Goldstone excitations of the anisotropic phase have a linear dispersion law and the whole system remains a superfluid. (v) The system exhibits an electromagnetic Meissner effect.     

New measurement of the elastic scattering cross section of μd muonic atoms off deuterons

We have measured the elastic scattering cross section for the process μd + d → μd + d in ultrapure gaseous deuterium at 14 atm and at room temperature. The results is σ_dd = (8 ± 2) × 10^?20 cm².     

Structure sensitivity of alkynol hydrogenation on shape- and size-controlled palladium nanocrystals: which sites are most active and selective?

The activity and selectivity of structure-sensitive reactions are strongly correlated with the shape and size of the nanocrystals present in a catalyst. This correlation can be exploited for rational catalyst design, especially if each type of surface atom displays a different behavior, to attain the highest activity and selectivity. In this work, uniform Pd nanocrystals with cubic (in two different sizes), octahedral, and cuboctahedral shapes were synthesized through a solution-phase method with poly(vinyl pyrrolidone) (PVP) serving as a stabilizer and then tested in the hydrogenation of 2-methyl-3-butyn-2-ol (MBY). The observed activity and selectivity suggested that two types of active sites were involved in the catalysis--those on the planes and at edges--which differ in their coordination numbers. Specifically, semihydrogenation of MBY to 2-methyl-3-buten-2-ol (MBE) occurred preferentially at the plane sites regardless of their crystallographic orientation, Pd(111) and/or Pd(100), whereas overhydrogenation occurred mainly at the edge sites. The experimental data can be fit with a kinetic modeling based on a two-site Langmuir-Hinshelwood mechanism. By considering surface statistics for nanocrystals with different shapes and sizes, the optimal catalyst in terms of productivity of the target product MBE was predicted to be cubes of roughly 3-5 nm in edge length. This study is an attempt to close the material and pressure gaps between model single-crystal surfaces tested under ultra-high-vacuum conditions and real catalytic systems, providing a powerful tool for rational catalyst design.     

Chemico-physical characterisation and in vivo biocompatibility assessment of DLC-coated coronary stents

The vast majority of stent thrombosis occurs in the acute and sub-acute phases and is more common in patients with acute coronary syndromes, due to the thrombotic milieu where stent struts are positioned. Stent thrombosis is likely due to incomplete tissue coverage of metallic stents as the contact between metallic stents and blood elements may lead to platelet adhesion and trigger vessel thrombosis. If a stent is covered after 7 days, the risk that it will be found uncovered at later stages is very low (<1 %). In this article, we demonstrate that diamond-like carbon (DLC) coatings, deposited by physical vapour deposition, promote rapid endothelisation of coronary stent devices, with very low platelets activation, reducing thrombotic clots. We relate these behaviours to the surface and bulk material properties of the DLC films, subjected to a comprehensive chemico-physical characterisation using several techniques (X-ray photoelectron spectroscopy, atomic force microscopy, field-emission scanning electron microscope, transmission electron microscopy combined with electron energy loss spectroscopy, Raman and dispersive X-ray spectroscopy). In vivo studies, conducted on 24 pigs, have shown complete endothelisation after 7 days, with no fibrin mesh and with only rare monocytes scattered on the endothelial layer while 30 and 180 days tests have shown reduced inflammatory activation and a complete stabilisation of the vessel healing, with a minimal neointimal proliferation. The integral and permanent DLC film coating improves haemo- and bio-compatibility and leads to an excellent early vessel healing of the stent whilst the extremely thin strut thickness reduces the amount of late neointima and consequently the risk of late restenosis. These data should translate into a reduced acute and sub-acute stent thrombosis.