排序方式: 共有109条查询结果,搜索用时 15 毫秒
81.
Seyed Meysam Baghbanian 《中国化学快报》2015,26(9):1113-1116
In this work, the natural nanozeolite clinoptilolite (Nano CP) was successfully functionalized by propylsulfonic acid and applied as efficient heterogeneous catalyst for the synthesis of quinoxaline derivatives in aqueous media. The nanocatalyst was characterized by various techniques such as CHN, XRD, FT-IR, BET, TGA/DTA, SEM, TEM and TEM-EDS. The results show its applicability as green, reusable and promising catalyst in organic synthesis. It was found that the nanocatalysts could be recycled and reused eight times without significant loss of catalytic activities. 相似文献
82.
Polypyrrole (PPy) coatings were synthesized on copper by electrochemical polymerization of pyrrole monomer in aqueous acidic and basic solutions by cyclic voltammetry. The coatings were characterized with CV, UV-visible absorption spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, and scanning electron microscopy (SEM) techniques. The corrosion protection aspects of PPy coatings have been investigated using the potentiodynamic polarization technique and electrochemical impedance spectroscopy (EIS). The potentiodynamic polarization measurements show that the PPy coating has ability to protect the copper against corrosion. It was concluded that a complete corrosion protective PPy film could not be obtained through direct electro-oxidation procedure. This may be due to copper dissolution in the monomer oxidation potential range. 相似文献
83.
A simple, new two-step procedure for the synthesis of novel tricyclic pyrrolo[2,1-a]isoquinoline derivatives is described. The initially prepared polysubstituted pyrroles obtained via the four-component condensation of arylglyoxals, cyclic 1,3-dicarbonyls, aminoacetaldehyde dimethyl acetal, and β-keto esters subsequently underwent intramolecular acid-catalyzed cyclization to the desired products in moderate to good yields. 相似文献
84.
Safari Meysam Yamini Yadollah Masoomi Mohammad Yaser Morsali Ali Mani-Varnosfaderani Ahmad 《Mikrochimica acta》2017,184(5):1555-1564
Microchimica Acta - The authors describe the preparation of two kinds of metal-organic frameworks (MOFs), referred to as TMU-8 and TMU-9. The MOFs were applied to the preconcentration of the ions... 相似文献
85.
Extraction and preconcentration of formaldehyde in water by polypyrrole‐coated magnetic nanoparticles and determination by high‐performance liquid chromatography
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Meysam Safari Yadollah Yamini Elham Tahmasebi Farzad Latifeh 《Journal of separation science》2015,38(19):3421-3427
In this study, a simple and rapid extraction method based on the application of polypyrrole‐coated Fe3O4 nanoparticles as a magnetic solid‐phase extraction sorbent was successfully developed for the extraction and preconcentration of trace amounts of formaldehyde after derivatization with 2,4‐dinitrophenylhydrazine. The analyses were performed by high‐performance liquid chromatography followed by UV detection. Several variables affecting the extraction efficiency of the formaldehyde, i.e., sample pH, amount of sorbent, salt concentration, extraction time and desorption conditions were investigated and optimized. The best working conditions were as follows: sample pH, 5; amount of sorbent, 40 mg; NaCl concentration, 20% w/v; sample volume, 20 mL; extraction time, 12 min; and 100 μL of methanol for desorption of the formaldehyde within 3 min. Under the optimal conditions, the performance of the proposed method was studied in terms of linear dynamic range (10–500 μg/L), correlation coefficient (R2 ≥ 0.998), precision (RSD% ≤ 5.5) and limit of detection (4 μg/L). Finally, the developed method was successfully applied for extraction and determination of formaldehyde in tap, rain and tomato water samples, and satisfactory results were obtained. 相似文献
86.
Seyed Meysam Hashemnejad Santanu Kundu 《Journal of Polymer Science.Polymer Physics》2016,54(17):1767-1775
Alginate hydrogels are polysaccharide biopolymer networks widely useful in biomedical and food applications. Here, we report nonlinear mechanical responses of ionically crosslinked alginate hydrogels captured using large amplitude oscillatory shear experiments. Gelation was performed in situ in a rheometer and the rheological investigations on these samples captured the strain‐stiffening behavior for these gels as a function of oscillatory strain. In addition, negative normal stress was observed, which has not been reported earlier for any polysaccharide networks. The magnitude of negative normal stress increases with the applied strain amplitude and can exceed that of the shear stress at large‐strain. Fitting a constitutive relationship to the stress‐strain curves reveals that the mode of deformation involves stretching of the alginate chains and bending of both the chains and the junction zones. The contribution of bending increases near saturation of G blocks as Ca2+ concentration was increased. The results presented here provide an improved understanding of the deformation behavior of alginate hydrogels and such understanding can be extended to other crosslinked polysaccharide networks. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1767–1775 相似文献
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As a main part of a railroad system, sleepers have important duty in conveying the load from rails to the ballast. The different situations in which the sleepers should function necessitate making them from different materials, such as various types of wood, reinforced concrete and even steel. In this work, the effects of Young’s modulus on response of railway sleeper are evaluated. As a main consideration, Winkler’s theorem is used to model the behavior of the elastic foundation. First, the response of a sleeper on a Winkler’s foundation is found. To evaluate the results of the closed form solution, a finite element model is used. Good agreement between the results of the closed form solution and the finite element model proves the validity of the results. In the next stage, the Young’s modulus is considered as a variable and the fundamental diagrams of the beam are plotted based on the variation of Young’s modulus. 相似文献
89.
Meysam Alishahi 《Discrete Applied Mathematics》2011,159(2-3):152-156
90.
Maryam Maleki Seyed Meysam Baghbanian Mahmood Tajbakhsh 《Journal of the Iranian Chemical Society》2018,15(2):359-368
A new magnetic oxidation catalyst was prepared using immobilization of tungstophosphoric acid on poly(N-vinylimidazole) entrapped magnetic nanozeolite and characterized by FTIR, TGA, XRD, SEM, TEM, EDX, VSM, and ICP-OES. The resulting heterogeneous catalyst displays high catalytic performance for selective oxidation of alcohols compared to the other catalysts. The catalyst could be reused eight times without any loss of catalytic activity. 相似文献