1H-ENDOR investigations on gamma-irradiated betaine calcium chloride dihydrate at room temperature

The ENDOR technique is applied to study the structure of the free radical N(CH₃)₃, found in the high temperature phase in the incommensurate crystal BCCD after γ-irradiation. The radical possesses a planar structure with strong deviation from the C₃ symmetry. The hybridization of the nitrogen atom is sp². Each of the three methyl groups exhibits a single ENDOR line, indicating the rotation of groups at room temperature. The deviation of the¹H hyperfine tensors of the methyl groups from axial symmetry is not a hint as to a hindered rotation of the groups. This is predicted by the C₂ symmetry of the system consisting of a π orbital and a rotating CH₃ group.     

Die ar?ometrische Analyse des Bieres

Ohne Zusammenfassung     

Synthesis and immobilization of molecular switches onto titaniumdioxide nanowires

The precursor [Fe^III(L)Cl (L = N,N′-bis(2′-hydroxy-3′-methyl-benzyliden)-1,7-diamino-4-azaheptane) is combined with [Mo(CN)₈]^4? yields a star shaped nona-nuclear cluster, [Mo^IV{(CN)Fe^III(L)}₈]Cl₄. This Fe₈Mo molecule is a high-spin system at room temperature. On cooling to 20 K some of the iron(III) centres in the molybdenum(IV)-star switch to the low-spin state as proven by Mössbauer spectroscopy. This molecule was deposited on TiO₂ nanowires by electrostatic interactions between the cluster cations and the surface functionalized titanium oxide nanowire. The synthesis and surface binding of the multistable molecular switch was demonstrated using IR and UV–Vis spectroscopy (high-resolution) transmission electron microscopy ((HR)TEM) and Mössbauer spectroscopy. High- and low-temperature Mössbauer spectra indicate that the spin state transition of the free cluster molecules is preserved after surface binding. The above results emphasize the possibility of fabricating molecule-based low-dimensional structures by using traditional bottom-up approaches based on the electrostatic interaction between the cluster cations and polymer functionalized nanowires. These results can be generalized for the application to both charged and non-charged molecules.     

Power scaling of laser diode pumped Pr3+:LiYF4 cw lasers: efficient laser operation at 522.6 nm, 545.9 nm, 607.2 nm, and 639.5 nm

We report efficient cw laser operation of laser diode pumped Pr(3+)-doped LiYF4 crystals in the visible spectral region. Using two InGaN laser diodes emitting at λ(P)=443.9?nm with maximum output power of 1?W each and a 2.9-mm-long crystal with a doping concentration of 0.5%, output powers of 938?mW, 418?mW, 384?mW, and 773?mW were achieved for the laser wavelengths 639.5?nm, 607.2?nm, 545.9?nm, and 522.6?nm, respectively. The maximum absorbed pump powers were approximately 1.5?W, resulting in slope efficiencies of 63.6%, 32.0%, 52.1%, and 61.5%, as well as electro-optical efficiencies of 9.4%, 4.2%, 3.8%, and 7.7%, respectively. Within these experiments, laser diode-pumped laser action at 545.9?nm was demonstrated for what is believed to be the first time.     

A New Proof for the Convergence of an Individual Based Model to the Trait Substitution Sequence

We consider a continuous time stochastic individual based model for a population structured only by an inherited vector trait and with logistic interactions. We consider its limit in a context from adaptive dynamics: the population is large, the mutations are rare and the process is viewed in the timescale of mutations. Using averaging techniques due to Kurtz (in Lecture Notes in Control and Inform. Sci., vol. 177, pp. 186–209, 1992), we give a new proof of the convergence of the individual based model to the trait substitution sequence of Metz et al. (in Trends in Ecology and Evolution 7(6), 198–202, 1992), first worked out by Dieckman and Law (in Journal of Mathematical Biology 34(5–6), 579–612, 1996) and rigorously proved by Champagnat (in Theoretical Population Biology 69, 297–321, 2006): rigging the model such that “invasion implies substitution”, we obtain in the limit a process that jumps from one population equilibrium to another when mutations occur and invade the population.