STM characterization of size-selected V1, V2, VO,and VO2 clusters on a TiO2(110)-(1 × 1) surface at room temperature

We use ultra-high vacuum scanning tunneling microscopy (UHV–STM) to probe, at the atomic level, the structure of mass-selected isolated V₁, V₂, VO and VO₂ clusters deposited on rutile TiO₂(110) by ion soft landing. All four species interact differently with the TiO₂ surface and the ultimate binding site and configuration strikes a balance between the gas-phase structure and the ligation of this cluster by the TiO₂ surface. Our results show that vanadium atoms prefer to bind in the upper threefold hollow sites on the surface and have a slight tendency to pair along the [1–10] direction, while vanadium dimers bind to the surface oriented along the [001] direction exclusively. VO clusters bind with the vanadium atom in the upper threefold hollow site and with the oxygen atom bound to an adjacent fivefold coordinated Ti atom (5c-Ti). The VO₂ cluster also binds with the vanadium atom in the upper threefold hollow site and with both oxygen atoms bound to adjacent 5c-Ti atoms or with only one oxygen bound to the surface and the other directed out of the plane of the surface.     

New hybrid nanostructures based on oxacillin-hydrotalcite-like anionic clays and their textural properties

New hybrid nanostructures based on inorganic matrices of hydrotalcite-like anionic clays (HT) incorporated with oxacillin are obtained by using calcinations-restructure method. XRD and TEM analyses are used to study the structural and textural characteristics of the clay containing hybrids. When nanoparticles of iron oxides are loaded on the layered anionic clay matrix a more effective delivery system of the drug is obtained. The results can be used to reduce the toxic side effects of oxacillin (e.g. upset stomach, diarrhea, cholestastic hepatitis), its aggregation process in aqueous solutions and also can open new perspectives for targeted the drug delivery.     

Three-dimensional turbulent boundary layer on wind turbine blades

The momentum integral technique for predicting the boundary–layer growth in three–dimensional flow has been extended to include the entrainment equation as the closure model. Special attention has been devoted to those terms in the differential equations that change the boundary–layer structure from that of cvasi two–dimensional steady flow, at outboard locations, to a tree–dimensional flow pattern. It is concluded that the stall is delayed due to the boundary–layer reattachment at inboard sections in conjunction with the onset of a spanwise vortex like structure. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

A two-algebraic turbulence model for compressible flow in turbomachinery cascade

The objective of this study is to examine the Baldwin–Lomax turbulence model in a finite volume solver to introduce a computer code for complex two–dimensional flows in turbomachinery. The turbulent model was tested with investigating the turbulent flow over a flat plate and other test cases. Three test cases are presented and the computed results are compared with experimental data. The calculated velocity profile agreed well with the experimental data in plate test case and the solver is validated in test case of flow over a semi NACA–0012 airfoil. The solver is used for flow through a multi–blade cascade of an axial compressor in design condition to show its capability of multi–block solution. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

A stall-delay model for rotating blades

The paper is aimed at describing a fundamental phenomenon: the effect of rotation on the inboard blade boundary layer on a wind turbine. The three-dimensional incompressible steady momentum integral boundary-layer equations are used to predict the boundary-layer growth and limiting streamline angles on the blade surface for both attached and separating flow. The chordwise skin friction coefficient is used to identify boundary layer separation and shear layer reattachment locations. The nature of flow near the axis of rotation is discussed and the physical mechanism associated with 3-D and rotational effects is identified. A semi-empirical correction law for the lift coefficient based on 2-D airfoil data is established. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Quantifying nonclassicality of one-mode Gaussian states of the radiation field

We define the degree of nonclassicality of a one-mode Gaussian state of the quantum electromagnetic field in terms of the Bures distance between the state and the set of all classical one-mode Gaussian states. We find the closest classical Gaussian state and the degree of nonclassicality using a recently established expression for the Uhlmann fidelity of two single-mode Gaussian states. The decrease of nonclassicality under thermal mapping is carefully analyzed. Along the same lines, we finally present the evolution of nonclassicality during linear amplification.     

MIMO capacity for deterministic channel models: sublinear growth

This is the second paper by the authors in a series concerned with the development of a deterministic model for the transfer matrix of a MIMO system. In our previous paper, we started from the Maxwell equations and described the generic structure of such a deterministic transfer matrix. In the current paper, we apply those results in order to study the (Shannon‐Foschini) capacity behavior of a MIMO system as a function of the deterministic spread function of the environment and the number of transmitting and receiving antennas. The antennas are assumed to fill in a given fixed volume. Under some generic assumptions, we prove that the capacity grows much more slowly than linearly with the number of antennas. These results reinforce previous heuristic results obtained from statistical models of the transfer matrix, which also predict a sublinear behavior. Copyright © 2012 John Wiley & Sons, Ltd.     

The Cayley transform applied to non-interacting quantum transport

We extend the Landauer–Büttiker formalism in order to accommodate both unitary and self-adjoint operators which are not bounded from below. We also prove that the pure point and singular continuous subspaces of the decoupled Hamiltonian do not contribute to the steady current. One of the physical applications is a stationary charge current formula for a system with four pseudo-relativistic semi-infinite leads and with an inner sample which is described by a Schrödinger operator defined on a bounded interval with dissipative boundary conditions. Another application is a current formula for electrons described by a one dimensional Dirac operator; here the system consists of two semi-infinite leads coupled through a point interaction at zero.     

Minimum-error method for scattering problems in quantum mechanics: Two stable and efficient implementations

We examine here, by using a simple example, two implementations of the minimum error method (MEM), a least-squares minimization for scattering problems in quantum mechanics, and show that they provide an efficient, numerically stable alternative to Kohn variational principle. MEM defines an error-functional consisting of the sum of the values of (HPsi - EPsi)2 at a set of grid points. The wave function Psi, is forced to satisfy the scattering boundary conditions and is determined by minimizing the least-squares error. We study two implementations of this idea. In one, we represent the wave function as a linear combination of Chebyshev polynomials and minimize the error by varying the coefficients of the expansion and the R-matrix (present in the asymptotic form of Psi). This leads to a linear equation for the coefficients and the R-matrix, which we solve by matrix inversion. In the other implementation, we use a conjugate-gradient procedure to minimize the error with respect to the values of Psi at the grid points and the R-matrix. The use of the Chebyshev polynomials allows an efficient and accurate calculation of the derivative of the wave function, by using Fast Chebyshev Transforms. We find that, unlike KVP, MEM is numerically stable when we use the R-matrix asymptotic condition and gives accurate wave functions in the interaction region.     

Dual action of Impurities in Crystal Growth from Solutions

A dual action of impurities becomes evidently in growth kinetic of prismatic faces of KDP. At higher supersaturation two-dimensional nucleation mechanism due to impurities prevails. At smaller supersaturation the blocking effect of the steps created by the dislocation mechanism of growth become efficient. The limit of the “dead” growth zone depending on the impurity's concentration and the solution pH is a result of this last effect and agrees with the Cabrera-Vermilyea mechanism.