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11.
12.
The variational principle is used to obtain solutions to Schrödinger's equation for a particle in the Yukawa potential. A Laguerre basis set extended by an extra function is employed in the calculations. A special parameter used in the extra function and its relation with the systems energy results in utilizing an auto-coherent scheme. Considerable improvement seems to be achieved especially in the critical region where the screening parameter approaches its threshold value. 相似文献
13.
This paper considers the prospect for there being multiple solutions to the control of classically modelled molecular dynamical systems. The research presented here follows up on a parallel study based on quantum mechanics. For polyatomic molecules it is generally expected that a classical mechanical model will be adequate and necessary as a means for designing optical fields for molecular control. The prospect for multiple control field solutions existing in this domain is important to establish in terms of ultimate laboratory realization of molecular control. A general formulation of the multiplicity problem is considered and the existence of a denumerably infinite number of solutions for the control field amplitude is shown to be the case under certain mild limitations on the physical variables. 相似文献
14.
A bifunctional amido-thiophene namely hexamethylene (bis-3-thiophene acetamide) (HMTA) was synthesized by the reaction of 3-thiophene acetic acid with hexamethylene diamine. Copolymerization in the presence of thiophene was achieved electrochemically in tetrabutylammonium tetrafluoroborate/acetonitrile (TBAFB/AN). Spectroelectrochemical analysis of the resulting copolymer [P(HMTA-co-Th)] reflected electronic transitions at 505 nm, 740 nm and ∼1000 nm, revealing π to π* transition, polaron and bipolaron band formation respectively. Switching ability was evaluated by a kinetic study via measuring the transmittance (%T) at the maximum contrast. Dual type polymer electrochromic devices (ECDs) based on P(HMTA-co-Th) and poly(ethylene dioxythiophene) (PEDOT) have been constructed. Spectroelectrochemistry, switching ability and stability of the devices were investigated by UV-vis spectroscopy and cyclic voltammetry. These devices exhibit low switching voltages (between 0.0 V and +1.6 V), short switching times with reasonable switching stability under atmospheric conditions. 相似文献
15.
The bromination of 3-bromo-6, 7-benzobicyclo [3.2.1] octa-2, 6-diene at ?50°C has been found to give only one product, the tribromide(7) produced via Wagner-Meerwein rearrangement with accompanying aryl migration. The bromination at 0°C produced nonrearranged tribromides beside the rearranged product. The structures of the products were determined by means of spectral data. The addition mechanism is discussed in terms of exo- and endo-attack. 相似文献
16.
(1R,2R)-1,2-bis-(5-amino-1,3,4-thiadiazole-2-yl)ethane-1,2-diol (L) has been prepared by the reaction of thiosemicarbazide with (2R,3R)-(+)-tartaric
acid (I) and phosphorous oxychloride, and its complexes with Co(II), Ni(II) and Cu(II) have been obtained. The structures
of the ligand and its complexes have been established by i. r., 1H- and 13C-n.m.r. spectra, u.v.–vis–nir spectroscopy, elemental analyses, T.g.-D.t.a. and magnetic susceptibility measurements. 相似文献
17.
A squarate-based synthesis of 2-ferrocenylidene-4-cyclopentene-1,3-diones is described. When refluxed in dioxane at 100 °C, heated with silica gel as a solvent free grinded solid mixture at 125 °C or stirred with silica gel in ethyl acetate at room temperature, 4-ferrocenylethynyl-4-hydroxy-2-cyclobutenones, prepared from ethynylferrocene and 3-cyclobutene-1,2-diones, afforded 2-ferrocenylidene-4-cyclopentene-1,3-diones as the major or single product of the reaction. In some cases, ferrocenyl quinones also resulted from these reactions as the minor products. The major or exclusive formation of 2-ferrocenylidene-4-cyclopentene-1,3-diones is attributed to the radical-stabilizing ability of the ferrocenyl group. 相似文献
18.
This is the second part of the trilogy on the probabilistic evolution approach and related to the quantum dynamical systems as the first part is. In this sense this work extends the content of the first part to the perhaps secondary but very important details. The spectral investigation of the evolution matrix reveals important issues first and brings the importance of the zero eigenvalues to the surface. The asymptotic convergence possibility and difficulties arising from there can be softened by redefining the state vector. Beside the redefinition, the dimensional extension by adding new elements to the state vector may facilitate the utilization of evolution matrix by bringing conicality or at least multinomiality. The space extension may also help us to deal with singular Hamiltonian systems. All these issues are focused on rather phenomenologically. Illustrative or not, no comprehensive implementation is given since the main purpose is just conceptuality. 相似文献
19.
20.
A. A. Ershov A. M. Gribushin A. I. Dem’yanov A. A. Kaminskii 《Physics of Particles and Nuclei》2018,49(1):23-25
The HF RADMON system monitors radiation environment in the region of the forward calorimeter of the CMS setup. Measurements of neutron fluxes at energies of 7, 8, and 13 GeV are carried out; estimates of the radiation shielding efficiency are obtained. Modernization of the system for operating under high luminosity conditions is completed and its capabilities to be used as an additional luminometer are confirmed. 相似文献