The Zinc Selenide (ZnSe) thin films have been deposited on SnO2/glass substrates by a simple and inexpensive chemical bath deposition (CBD). The structural, optical and electrical properties of ZnSe films have been characterized by X-ray diffraction (XRD), Energy Dispersive X-ray Analysis (EDAX), optical absorption spectroscopy, and four point probe techniques, respectively. The films have been subjected to different annealing temperature in Argon (Ar) atmosphere. An increase in annealing temperature does not cause a complete phase transformation whereas it affects the crystallite size, dislocation density and strain. The optical band gap (Eg) of the as-deposited film is estimated to be 3.08 eV and decreases with increasing annealing temperature down to 2.43 eV at 773 K. The as-deposited and annealed films show typical semiconducting behaviour, dρ/dT > 0. Interestingly, the films annealed at 373 K, 473 K, and 573 K show two distinct temperature dependent regions of electrical resistivity; exponential region at high temperature, linear region at low temperature. The temperature at which the transition takes place from exponential to linear region strongly depends on the annealing temperature. 相似文献
Thermal behavior of 2,4,6-tris(4-(1H-pyrrol-1-yl)phenoxy)-1,3,5-triazine monomer, polypyrrole, and their star shaped copolymer, were investigated using TG and DTA methods. It was found that Tria melts at 517 K and after than it starts to decompose. Decomposition proceeded in two stages which were corresponding to removal of branched groups and remaining core structure degradation, respectively. Polypyrrole and copolymer showed similar thermal behaviors. These compounds decomposed in three stages which are removal of solvent, removal of dopant anion and rest of structure decomposition. The calculation of activation energies of all reactions were realized using model-free (KAS and FWO) methods. The graphs were prepared which show the alteration of activation energy with decomposition ratio. Thermal analysis results showed that dopant anion and solvent removal activation energy values for copolymer are lower than polypyrrole. Star shaped loose-packed novel structure greatly facilitates solvent and dopant anion removal from copolymer. It can be concluded also that thermal analysis can be used as predict package structure of conducting polymers. 相似文献
This paper aims to develop models to optimally manage costs associated with resources that can be downgraded. These resources are reused a number of times before becoming unsuitable for their original purpose, and then they are assigned for some other purpose. The typical decisions are the quantity of resources to purchase, to downgrade and to hold in the inventory. A network-based model is developed to formulate the problem and to investigate several special cases. As the model becomes an integer program due to some side constraints, several heuristics are developed here to overcome the challenges associated with solving the resulting integer program. A semiconductor industry application for test wafer management is presented using real-life data. 相似文献
We demonstrate a high optoelectronic performance and application potential of our random network, with subwavelength diameter, ultralong, and high‐quality silver nanowires, stabilized on a substrate with a UV binder. Our networks show very good optoelectronic properties, with the single best figure of merit of ∼1686, and excellent stability under harsh mechanical strain, as well as thermal, and chemical challenge. Our network transparency strongly exceeds the simple shading limit. We show that this transmission enhancement is due to plasmonic refraction, which in an effective medium picture involves localized plasmons, and identify the inhomogeneous broadening as the key factor in promoting this mechanism. Such networks could become a basis for a next generation of ultrahigh‐performance transparent conductors.
AbstractSince the two-directional functionally graded (2D-FG) materials can satisfy the new requirements raised based on the elimination of the stress concentration, delamination and cracking problems accompanying with the low cost and lightweight on the structures without sacrificing the stiffness and strength, the structural analyses of these structures become more important than ever. Moreover, the usage of the micro-electromechanical systems composed of 2D-FG materials has been increasing in automotive, military, space, biomedical, and nuclear energy industries. Within this study, the free vibration and buckling behaviors of 2D-FG porous microbeams are investigated based on the modified couple stress theory by employing a transverse shear-normal deformation beam theory and using finite element method. The effects of the thickness to material length scale parameter (MLSP) accompanying with the micro-porosity volume fraction ratio, boundary condition, aspect ratio, and gradient index on the dimensionless fundamental frequencies and dimensionless critical buckling loads of the 2D-FG porous microbeams are investigated. Moreover, with assumption of the variable material length scale parameters (VMLSP), the computed results are compared with ones obtained by employing constant MLSP. It is found that VMLSP increases the stiffness of the 2D-FG porous microbeams and effects the free vibration and buckling responses of these structures. 相似文献
We report the efficient preparation of furo[2,3‐d]pyridazin‐4(5H)‐one and its N‐substituted derivatives starting from methyl 2‐methylfuran‐3‐carboxylate. The Me group was converted to the aldehyde group, which was then condensed with hydrazine derivatives. Then, the ester functionalities were hydrolyzed to the corresponding acids, followed by treatment with SOCl2 to give N‐substituted furopyridazinone derivatives. 相似文献
By converting the rectangular basis potential V(x, y) into the form as \({V({r}) + V({r},\varphi)}\) described by the pseudo central plus noncentral potential, particular solutions of the two dimensional Schrödinger equation in plane-polar coordinates have been carried out through the analytic approaching technique of the Nikiforov and Uvarov. Both the exact bound state energy spectra and the corresponding bound state wavefunctions of the complete system are determined explicitly and in closed forms. Our presented results are identical to those of the previous works and they may also be useful for investigation and analysis of structural characteristics in a variety of quantum systems. 相似文献
Osmolytes are substances that affect osmosis and are used by cells to adapt to environmental stress. Here, we report a neutron reflectivity study on the influence of some osmolytes on protein adsorption at solid-liquid interfaces. Bovine ribonuclease A (RNase) and bovine insulin were used as model proteins adsorbing at a hydrophilic silica and at a hydrophobic polystyrene surface. From the neutron reflectivity data, the adsorbed protein layers were characterized in terms of layer thickness, protein packing density, and adsorbed protein mass in the absence and presence of urea, trehalose, sucrose, and glycerol. All data point to the clear effect of these nonionic cosolvents on the degree of protein adsorption. For example, 1 M sucrose leads to a reduction of the adsorbed amount of RNase by 39% on a silica surface and by 71% on a polystyrene surface. Trehalose was found to exhibit activity similar to that of sucrose. The changes in adsorbed protein mass can be attributed to a decreased packing density of the proteins in the adsorbed layers. Moreover, we investigated insulin adsorption at a hydrophobic surface in the absence and presence of glycerol. The degree of insulin adsorption is decreased by even 80% in the presence of 4 M of glycerol. The results of this study demonstrate that nonionic cosolvents can be used to tune and control nonspecific protein adsorption at aqueous-solid interfaces, which might be relevant for biomedical applications. 相似文献