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In the solid state, [{Cp(CO)3Mo}InCl2]∞ forms a one‐dimensional coordination polymer in which the indium atoms are coordinated by four chlorine atoms (In? Cl: 2.448(2)–3.004(2) Å) and a {Cp(CO)3Mo} group (In? Mo: 2.750(1) Å) in a distorted trigonal bipyramidal environment. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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The 3-(N,N-Dimethylamino)prop-1-enyl Group as a Chelate Ligand in Indium Organyls InBr3 reacts with Me2NCH2CH?CHMgCl (molar ratio 1 : 2) to form (Me2NCH2CH?CH)2InBr ( 1 ) as the first indium alkenyl compound with amino-functionalized alkenyl groups. The X-ray structure determination shows the formation of a chelate complex. 1 crystallizes in the orthorhombic space group Fddd with the unit cell parameters a = 14.904(2) Å, b = 17.140(1) Å and c = 21.035(2) Å. By reaction of Me2InBr with Me2NCH2CH?CHMgCl (molar ratio 1 : 1) (Me2NCH2CH?CH)InMe2 ( 2 ) is formed as a colorless, at room temperature liquid, monomeric compound. The n.m.r. and mass spectra are discussed. 相似文献