全文获取类型
收费全文 | 280篇 |
免费 | 7篇 |
专业分类
化学 | 225篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 12篇 |
物理学 | 47篇 |
出版年
2023年 | 2篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 10篇 |
2019年 | 2篇 |
2018年 | 3篇 |
2017年 | 2篇 |
2016年 | 11篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 8篇 |
2012年 | 14篇 |
2011年 | 14篇 |
2010年 | 14篇 |
2009年 | 8篇 |
2008年 | 10篇 |
2007年 | 24篇 |
2006年 | 19篇 |
2005年 | 12篇 |
2004年 | 14篇 |
2003年 | 10篇 |
2002年 | 9篇 |
2001年 | 10篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 7篇 |
1986年 | 1篇 |
1985年 | 6篇 |
1984年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1971年 | 2篇 |
1968年 | 1篇 |
1957年 | 2篇 |
1932年 | 1篇 |
排序方式: 共有287条查询结果,搜索用时 9 毫秒
51.
Schlund S Schmuck C Engels B 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(23):6644-6653
Arginine forms much less stable dimers than 2-(guanidiniocarbonyl)-1H-pyrrole-5-carboxylate although the principal binding interactions are very similar. The reasons for this difference are addressed in this work by state-of-the-art ab initio computations. The investigation shows that the extraordinary high stability of the 2-(guanidiniocarbonyl)-1H-pyrrole-5-carboxylate dimer results to about 50 % from the rigidity of its monomer. Within this study monomer and dimer conformers of arginine were calculated leading to new low lying structures which have not been reported before as well as new global minima are predicted. In these structures stacking interactions with the guanidinium moiety are especially important. For the monomer we predict the energy minimum to be the canonical form with the lowest lying zwitterionic structure being only 9 kJ mol(-1) less stable. During the course of these calculations we found that DFT did not predict the structures and their relative energy correctly in comparison to perturbation theory (MP2) and some potential reasons for the failure of DFT in these cases are discussed. Vibrational frequencies of the various structures are presented and a suitable wavenumber region for an experimental determination of the global minimum of the arginine monomer is identified. The effect of molecular rigidity on the self-assembly is probed using a local minimum of the arginine monomer which does not possess any intramolecular stabilizing effects. Our results suggest that the deliberate control of the conformational flexibility is a powerful instrument to steer the complex affinity of artificial hosts. 相似文献
52.
The syntheses of several bis-cations 1-5 with a simple primary ammonium cation attached via flexible linkers of varying length to a guanidiniocarbonyl pyrrole oxo anion binding site are reported. In UV-binding studies in aqueous buffer solution these bis-cations showed efficient binding of various N-acetyl amino acid carboxylates. However, complex affinity is significantly depending on both the anion and the length of the linker in the bis-cation. With increasing linker length, complex stability first increases until an optimum is reached for bis-cation 3 with a C4-linker. Then the complex stability decreases again. The best binding substrate in this series is N-acetyl phenyl alanine, most likely due to additional cation-pi-interactions between the aromatic ring and the guanidiniocarbonyl pyrrole cation. The formation of the complex between bis-cation 3 and N-acetyl phenyl alanine carboxylate was investigated further by fluorescence titrations and NOE studies, as well as molecular mechanics calculations. 相似文献
53.
54.
Schäfer M Schmuck C Heil M Cooper HJ Hendrickson CL Chalmers MJ Marshall AG 《Journal of the American Society for Mass Spectrometry》2003,14(11):1282-1289
The activation energy for the unimolecular dissociation of a non-covalent supramolecular complex between an Artificial Cationic Receptor A ([Gua-Val-Val-Val-Amide]+, in which Gua is guanidiniocarbonyl pyrrole) and an Anionic Tetrapeptide B ([N-Acetyl-Val-Val-Ile-Ala]-) has been determined by measurement of the dissociation rate constant as a function of infrared CO2 laser power density. Singly-charged quasimolecular [A + B + H]+ ions are isolated, stored in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer, and irradiated by IR photons. The rate constant for dissociation of the non-covalent complex is determined at five different laser power densities. A plot of the natural logarithm of the first-order rate constant versus the natural logarithm of the laser power density yields a straight line, the slope of which provides an approximate measure of the activation energy (Ea(laser)) for dissociation. Ea(laser) is calculated by a relationship derived earlier by Dunbar and with a newly proposed equation by Paech et al. The results of the two approaches deliver significantly different activation energy values for the unimolecular dissociation of the non-covalent complex. We obtain EaI(laser) = 0.67 eV (Dunbar approximation) and EaII(laser) = 1.12 eV (Paech et al. approximation). Differences between the two approaches are discussed with respect to non-covalent complexes. 相似文献
55.
Trigo M Sheu YM Arms DA Chen J Ghimire S Goldman RS Landahl E Merlin R Peterson E Reason M Reis DA 《Physical review letters》2008,101(2):025505
Ultrafast laser excitation of an InGaAs/InAlAs superlattice (SL) creates coherent folded acoustic phonons that subsequently leak into the bulk (InP) substrate. Upon transmission, the phonons become "unfolded" into bulk modes and acquire a wave vector much larger than that of the light. We show that time-resolved x-ray diffraction is sensitive to this large-wave vector excitation in the substrate. Comparison with dynamical diffraction simulations of propagating strain supports our interpretation. 相似文献
56.
57.
Inhibition of corrosion of commercial mild steel in presence of tetrazole derivatives in acid medium
V. Violet Dhayabaran I. Sharmila Lydia J. Princy Merlin P. Srirenganayaki 《Ionics》2004,10(1-2):123-125
The inhibitive influence of tetrazole derivatives namely, 1-(91-acridinyl)-5-(4′-aminophenyl) tetrazole, 1-(9′-acridinyl)-5-(4′-hydroxy phenyl) tetrazole and 1-(9′-acridinyl)-5-(4′-chlorophenyl)
tetrazole on the corrosion of commercial mild steel in 1 N hydrochloric acid medium was studied by weight loss method. The
monolayer adsorption has been confirmed by fitting the data to the Langmuir adsorption isotherm. Weight loss studies have
been carried out at 303K, 318K and 333K. Thermodynamic parameters like heat of adsorption, activation energy and free energy
change have been calculated. The maximum inhibition of efficiency of tetrazole derivatives, 1-(9′-acridinyl)-5-(4′-amoinophenyl)
tetrazole, 1-(9′acridinyl)-5-(4′-hydroxyphenyl) tetrazole and 1-(9′-acridinyl)-5-(4′-Chlorphenyl) tetrazole was found to be
60.59%, 89.00% and 92.74, respectively.
Paper presented at the 2nd International Conference on Ionic Devices, Anna University, Chennai, India, Nov. 28–30, 2003. 相似文献
58.
V. Violet Dhayabaran J. Princy Merlin I. Sharmila Lydia R. Shanthi R. Sivaraj 《Ionics》2004,10(3-4):288-290
The influence of Fluorescein in conjunction with calcium oxide on the corrosion of Aluminium in 1.0 N NaOH was studied by
galvanostatic studies and weight loss studies. It has been found that the inhibition of corrosion of aluminium increased with
the increasing concentration of the inhibitor. The maximum inhibition efficiency of fluorescein alone was found to be 30.80%.
However, the addition of calcium oxide increased the maximum inhibition efficiency to 53.71%. The corrosion process was found
to be under the anodic control, in the presence or in the absence of inhibitor. The inhibition was found to be mixed type.
Paper presented at the 2nd International Conference on Ionic Devices, Anna University, Chennai, Inida, Nov. 28–30, 2003. 相似文献
59.
60.
C. Colvard R. Fischer T.A. Gant M.V. Klein R. Merlin H. Morkoc A.C. Gossard 《Superlattices and Microstructures》1985,1(1):81-86
Phonon modes in GaAsAlxGa1?xAs superlattices simplify when the phonon wavevector q is perpendicular to the plane of the layers. We have studied such modes using a Raman back-scattering technique on SL's grown by MBE. The results are consistent with simple ideas of LA phonon freedom and LO phonon confinement suggested by one-dimensional lattice dynamical calculations. The longitudinal acoustic (LA) modes show zone folding due to mini-zone formation. Their frequencies occur in doublets linearly dependent on q and show little mini-gap formation. This is consistent with a picture of approximately free plane wave propagating through the interfaces with Raman coupling due to SL layering of the photoelastic coefficient. By contrast, Raman data on LO modes in small period GaAsAlAs SL's suggest that these modes are standing waves strongly confined in either GaAs or AlAs. 相似文献