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91.
Metin Ak Mine Sulak Ak Gülbin Kurtay Mustafa Güllü Levent Toppare 《Solid State Sciences》2010,12(7):1199-1204
A new thiophene-based monomer; 1,2-bis(thiophen-3-ylmethoxy)benzene (BTMB) has been synthesized and chemical structure of the monomer was characterized. Polymerization of BTMB and characterization of the resulting polymer P(BTMB) were performed. Spectroelectrochemical analysis of the P(BTMB) reflected electronic transitions at 400 nm, 520 nm and ~720 nm, corresponding to π–π* transition, polaron and bipolaron band formation respectively. Switching ability was evaluated by a kinetic study via measuring the transmittance (%T) at the maximum contrast. Dual type all polymer electrochromic device (ECD) based on P(BTMB) and poly(ethylene dioxythiophene) (PEDOT) was constructed. Spectroelectrochemistry and switching ability of the devices were investigated by UV–vis spectroscopy. 相似文献
92.
Emre Gür S. Tüzemen Kadem Meral Y. Onganer 《Applied Physics A: Materials Science & Processing》2009,94(3):549-554
The photoluminescence (PL), recombination lifetime (RL), and X-ray diffraction (XRD) spectra of the samples grown at various
O2 fractions of 0.290 (Zn-rich), 0.585 (moderate), and 0.836 (O-rich) over the total pressures in the growth chamber were investigated.
XRD measurements revealed that all the films show highly preferred (0002) orientation. The PL measurements exhibit different
dominant emissions in the ultraviolet (UV), violet and blue regions for Zn-rich, moderate and O-rich samples, respectively.
Well-known green emission and high intensity of free exciton (FX) transition has been observed in Zn-rich sample after the
sample is annealed at vacuum probably due to the oxygen deficiencies. Annealing the moderate sample gives rise to the UV emission
at energy of 3.263 eV similar to the observed PL emission spectrum for the Zn-rich thin film. O-rich thin film exhibits a
338 meV acceptor level above the valance band maximum, most probably related to zinc vacancy (VZn). Free exciton RL measurements result in 568.23, 397.65, and 797.46 ps for Zn-rich, moderate, and O-rich thin films, respectively.
A good correlation was found between crystallite size and the lifetime values. 相似文献
93.
Beril Anilanmert Ali Acar Ozdemir Muhammet Aydin Meral Akgül Salih Cengiz 《Chemical Papers》2015,69(12):1532-1540
Ethyl glucuronide (EtG) is a metabolite and a specific marker of alcohol consumption that can be detected days after the complete elimination of alcohol after drinking. A rapid, simple, and sensitive LC-ESI-MS/MS method for the determination of urinary ethyl glucuronide was developed and fully validated in accordance with analytical standards, using the C18 column. The whole process including sample preparation and LC-MS/MS lasted 10 min. A comprehensive validation including HorRat, measurement uncertainty, system suitability and intermediate precision calculations among analysts, and a cut-off limit study was performed. The method was applied to real samples and a cutoff limit determination study. The LOD and LOQ (using the IUPAC and Eurachem methods) were determined as 104.21 ng mL?1 and 165.00 ng mL?1. A cut-off limit of ≈ 818 ng mg?1 (normalised to creatinine) was found for urinary EtG. The results showed that the cut-off limits currently in use should be re-considered in further studies and standardised on a global scale. Normalisation to creatinine is important because of the risk of the dilution of urine intentionally or with a change of diet. The concentrations of real samples from subjects who had consumed alcohol were successfully predicted using this method, after zero HS-GC/MS results of urine alcohol concentration. 相似文献
94.
Hasan Tanak Karataş Şadiye Meral Seher Ağar Ayşen Alaman 《Crystallography Reports》2020,65(7):1221-1225
Crystallography Reports - A novel Schiff base compound was synthesized and characterized by IR spectroscopy and X-ray diffraction method. The compound crystallizes in monoclinic space group P21/c... 相似文献
95.
Hasan Tanak Karataş Şadiye Meral Seher Ağar Ayşen Alaman 《Crystallography Reports》2020,65(7):1212-1216
Crystallography Reports - N-(2-Fluorophenyl)-1-(5-nitrothiophen-2-yl)methanimine has been synthesized and characterized by single-crystal X-ray determination. Molecular geometry from X-ray... 相似文献
96.
97.
Inactivation effect of an electric current treatment combining both 188 μA/m2 DC and 251 μA/m2 AC on Gram negative, Gram positive bacteria and their mixed culture, which were isolated from hides, was separately analyzed. This electric treatment, applied for 16 min was found to be fairly effective in reducing the bacterial cell count (7.10–7.48 log10 colony forming units/mL) to a relatively low level (4.52–4.90 log10 colony forming units/mL). At this level bacterial damage to the hides is reduced in soak liquors. Cheap and efficient electric current may be applied to rapidly reduce the destructive bacterial populations in main hide-soak liquors. 相似文献
98.
Trans‐bis(ethanolamine)bis(saccharinato)mercury(II), [Hg(ea)2(sac)2], where ea and sac denote the ethanolamine molecule and the saccharinate anion, respectively, crystallizes in the triclinic space group P (No. 2) with a = 9.4651 (5), b = 10.4365 (5), c = 11.9314 (6) Å, α = 84.402 (1)° β = 78.313 (1)°, γ = 75.307 (1)°, Z = 2, V = 1115.11 (10) Å3. The structure consists of isolated [Hg(ea)2(sac)2] units in which the Hg(II) ion is octahedrally coordinated by two nitrogen and two oxygen atoms of two neutral ea ligands, and two nitrogen atoms of two sac ligands. The ea acts as a bidentate N‐ and O‐donor ligand and occupies the trans positions of the equatorial plane of the coordination octahedron forming a fivemembered chelate ring, while sac behaves as a monodentate N‐donor ligand occupying the axial positions. The average Hg‐Nsac and Hg‐Nea bond distances are 2.739 (3) and 2.114 (7) Å, respectively. The crystal exhibits extensive hydrogen bonds between the hydroxyl and amine hydrogen atoms of the ea ligands and the sulfonyl, carbonyl and amine groups of the sac ligands. 相似文献
99.
Park HS Blewitt G Cortez BG Foster GW Gajewski W Haines TJ Kielczewska D LoSecco JM Bionta RM Bratton CB Casper D Chrysicopoulou P Claus R Errede S Ganezer KS Goldhaber M Jones TW Kropp WR Learned JG Lehmann E Reines F Schultz J Seidel S Shumard E Sinclair D Sobel HW Stone JL Sulak LR Svoboda R van der Velde JC Wuest C 《Physical review letters》1985,54(1):22-25
100.
Synthesis of ferrocenyl-substituted pyrazoles via the reaction between (2-formyl-1-chlorovinyl)ferrocene and hydrazine derivatives is described. Depending upon the substitution pattern of hydrazine, the reaction affords 1-alkyl/aryl-5-ferrocenylpyrazoles and/or 1-alkyl/aryl-3-ferrocenylpyrazoles. The reaction appears to be general for a variety of hydrazine derivatives. 相似文献