透射光栅的实验标定和衍射效率的理论模拟

透射光栅广泛应用于软X射线能谱测量.为了获得用于惯性约束聚变研究的透射光栅的各级衍射效率及其他参数,在北京同步辐射源上200—1600 eV能量范围内对其进行了标定,获得了透射光栅衍射效率的实验结果.扩展了透射光栅衍射效率的计算方法,提出了7边准梯形截面衍射效率计算模型.分析拟合了实验数据,理论结果与实验结果很好符合.得到了7边准梯形的透射光栅栅线截面结构. 关键词： 透射光栅 衍射效率 实验标定 光栅模型     

左手介质椭圆光波导基模传播特性

在椭圆柱坐标系中,采用分离变量方法,得出了左手介质椭圆光波导本征方程的近似解,通过数值计算,分析了椭圆波导偏心率、左手介质的电容率、磁导率对椭圆光波导基模传播特性的影响,并将左介质光波导与右手介质光波导基模特性进行对比,得出左手介质光波导的基模特性与右手介质光波导基模特性差别不大的结论.     

过量Zn对β-Zn4Sb3热电性能影响的研究

采用真空熔融缓冷方法制备了单相β-Zn4Sb3以及含有过量Zn的β-Zn4Sb3块体热电材料.在300—700K的温度范围内测试了材料的电导率、Seebeck系数和热导率,研究了β-Zn4Sb3化合物中过量Zn的分布状态及其对材料热电性能的影响规律.结果表明：过量的Zn作为第二相较均匀的分布在β-Zn4Sb3的晶界上,随着Zn含量增加,材料电导率和热导率上升,Seebeck系数下降,Zn第二相的引入能有效提高材料的功率因子,Zn过量2at%的材料在700K时其ZT值达到1.10.     

共焦腔增强的空气拉曼散射

拉曼光谱是一种无损、快速的物质成分分析和检测方法.由于拉曼信号强度微弱,使得拉曼光谱的检测应用受到极大的限制.针对增强拉曼散射信号强度、提高检测灵敏度这一问题,设计了一种用于自发拉曼散射信号增强的共焦腔样品池,开展了基于该共焦腔的空气拉曼散射信号增强研究.共焦腔的腔镜反射率为92%,这一设计在保证共焦腔通带宽度与激光器线宽匹配的同时能有效地降低共振调节难度.实验中采用0°探测构型收集拉曼信号,并由成像式拉曼光谱仪获取光谱信号.实验发现,在共振状态下,共焦腔的耦合效率达到87.5%,单向激光功率实现约11倍放大;与无共振腔相比,共焦腔对拉曼信号实现17倍放大,信噪比提高2倍.此外,空气中CO_2的3σ检测限达到200 ppm量级.结果表明,该系统对自发拉曼散射信号增强效果显著,并且有较高的检测灵敏度.     

Strength and equation of state of molybdenum triboride under 80 GPa pressure,using radial X-ray diffraction

The strength and equation of state of molybdenum triboride have been determined under nonhydrostatic compression up to 80?GPa, using an angle-dispersive radial X-ray diffraction technique in a diamond anvil cell (DAC). The RXD data yield a bulk modulus and its pressure derivative as K_0?=?342(6)?GPa with K₀′?=?2.11(17) at ψ?=?54.7°. Analysis of diffraction data using the strain theory indicates that the ratio of differential stress to shear modulus (t/G) ranges from 0.002 to 0.050 at pressures of 4–80?GPa. Together with theoretical results on the high pressure shear modulus, our results here show that molybdenum triboride sample under uniaxial compression can support a differential stress of ～10?GPa when it started to yield with plastic deformation at ～30?GPa. In addition, we draw a conclusion that MoB₃ is not a superhard material but a hard material.     

Entanglement Dynamics of a Generic-Spin Model

We investigate the entanglement dynamics of a generic-spin model with weak external field. We first derive the time-dependent solutions of angular momentum operators with short-time approximation and then numerically calculate the entangled witness. It’s shown that one can dynamically generate quantum entanglement by adjusting coupling strength.     

Ionic liquid-based electrolyte with dual-functional LiDFOB additive toward high-performance LiMn<Subscript>2</Subscript>O<Subscript>4</Subscript> batteries

Manganese oxide-based cathodes are one of the most promising lithium-ion battery (LIB) cathode materials due to their cost-effectiveness, high discharge voltage plateau (above 4.0 V vs. Li/Li⁺), superior rate capability, and environmental benignity. However, these batteries using conventional LiPF₆-based electrolytes suffer from Mn dissolution and poor cyclic capability at elevated temperature. In this paper, the ionic liquid (IL)-based electrolytes, consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfon)imidate (PYR_1,4-TFSI), propylene carbonate (PC), lithium bis(trifluoromethanesulfon)imide (LiTFSI), and lithium oxalyldifluoroborate (LiDFOB) additive, were explored for improving the high temperature performance of the LiMn₂O₄ batteries. It was demonstrated that LiTFSI-ILs/PC electrolyte associated with LiDFOB addition possessed less Mn dissolution and Al corrosion at the elevated temperature in LiMn₂O₄/Li batteries. Cyclic voltammetry and electrochemical impedance spectroscopy implied that this kind of electrolyte also contributed to the formation of a highly stable solid electrolyte interface (SEI), which was in accordance with the polarization measurement and the Li deposition morphology of the symmetric lithium metal cell, thus beneficial for improving the cycling performance of the LiMn₂O₄ batteries at the elevated temperature. Cyclic voltammetry and electrochemical impedance spectroscopy implied that the cells using this kind of electrolyte exhibited better interfacial stability, which was further verified by the polarization measurement and the Li deposition morphology of the symmetric lithium metal cell, thus beneficial for improving the cycling performance of the LiMn₂O₄ batteries at the elevated temperature. These unique characteristics would endow this kind of electrolyte a very promising candidate for the manganese oxide-based batteries.     

大功率半导体激光器阵列热串扰行为

以硬焊料传导制冷,30%填充因子半导体激光器阵列为例,建立了三维有限元模型,对阵列内部各发光单元之间的热串扰行为进行了分析研究。结果表明,当其连续波工作时间大于1.2 ms后,阵列内发光单元之间出现热串扰现象;当次热沉由CuW合金改为铜金刚石复合材料时,阵列内发光单元自热阻和相邻发光单元的串扰热阻降低,有效地降低了各发光单元之间的热串扰行为。保持阵列宽度、发光单元数目及发光单元周期不变,发现随阵列填充因子的增加,器件热阻以指数衰减趋势逐渐降低,而发光单元间的热串扰特性对此变化并不敏感;保持阵列单个发光单元输出功率,发光单元尺寸及阵列宽度不变,增加发光单元个数后,阵列内各发光单元之间热串扰加剧,填充因子越高阵列升温速率越快;但在最初约70 s内,包含不同数目发光单元的阵列最高温度差异仅约0.5 ℃,有利于多发光单元高填充因子器件高功率输出。     

An Efficient Scheme for Entanglement Concentration of Arbitrary Four-Photon States

The maximally entanglement will become less-entangled state because of the effects of decoherence. However, maximally entangled states are usually important for most of the quantum information processing protocols. So we propose a practical entanglement concentration protocol of an arbitrary four-photon less-entangled state assisted with single photons, which greatly reduces the difficulty of the experimental realization. In our scheme, we only employ three steps, a four-photon cluster state can be acquired with a certain probability by three affiliated photons. The protocol adopts the linear optical elements and weak cross-Kerr media, which make the scheme more simple and feasible in the experiment.     

Ultracold two-component fermionic gases with a magnetic field gradient near a feshbach resonance

We study theoretically the ultracold two-component fermionic gases when a gradient magnetic field is used to tune the scattering length between atoms. For 6Li at the narrow resonance B0=543.25 G, it is shown that the gases would be in a coexistence of the regimes of BCS, Bose-Einstein condensation (BEC), and unitarity limit with the present experimental technique. In the case of thermal and chemical equilibrium, we investigate the density distribution of the gases and show that a double peak of the density distribution can give us a clear evidence for the coexistence of BCS, BEC, and unitarity limit.