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81.
S. Succi M. Mendoza F. Mohseni I. Karlin 《The European physical journal. Special topics》2014,223(11):2177-2188
In this paper, we review recent progress in relativistic lattice kinetic theory and its applications to relativistic hydrodynamics. Two methods for constructing the discretised distribution function, moment matching and projection onto orthogonal polynomials, are described. Extensions to ultra-high velocities as well as improved dissipation models are discussed. We show that the existing models can successfully cover a wide range of velocities (from weak-relativistic to ultra-relativistic) and viscous regimes. Various applications, from quark-gluon plasma and relativistic Richtmyer-Meshkov instability to flows in curved manifolds are also explored. Finally, potential developments for general relativity are outlined along with future prospects for solving the full set of Einstein equations of general relativity. 相似文献
82.
Renata Monteiro-Maia Maria B Ortigão-de-Sampaio Rosa T Pinho Luiz RR Castello-Branco 《Journal of immune based therapies and vaccines》2006,4(1):1-6
We hypothesize that the energy strategy of a cell is a key factor for determining how, or if, the immune system interacts
with that cell. Cells have a limited number of metabolic states, in part, depending on the type of fuels the cell consumes.
Cellular fuels include glucose (carbohydrates), lipids (fats), and proteins. We propose that the cell's ability to switch
to, and efficiently use, fat for fuel confers immune privilege. Additionally, because uncoupling proteins are involved in
the fat burning process and reportedly in protection from free radicals, we hypothesize that uncoupling proteins play an important
role in immune privilege. Thus, changes in metabolism (caused by oxidative stresses, fuel availability, age, hormones, radiation,
or drugs) will dictate and initiate changes in immune recognition and in the nature of the immune response. This has profound
implications for controlling the symptoms of autoimmune diseases, for preventing graft rejection, and for targeting tumor
cells for destruction. 相似文献
83.
Microcrystals of orthorhombic nickel (II) oxalate dihydrate were synthesized through a precipitation reaction of aqueous solutions of nickel chloride and oxalic acid. Magnetic susceptibility exhibits a sharp peak at 3.3 K and a broad rounded maximum near 43 K. We associated the lower maximum with a metamagnetic transition that occurs when the magnetic field is about ≥3.5 T. The maximum at 43 K is typical of 1D antiferromagnets, whereas weak ferromagnetism behavior was observed in the range of 3.3–43 K. 相似文献
84.
Kashiwagi GA Mendoza VM de Lederkremer RM Gallo-Rodriguez C 《Organic & biomolecular chemistry》2012,10(31):6322-6332
The hexasaccharide β-D-Galp-(1→2)-[β-D-Galp-(1→3)]-β-D-Galp-(1→6)-[β-D-Galf(1→2)-β-D-Galf(1→4)]-D-GlcNAc (1) is the largest carbohydrate structure released as alditol by reductive β-elimination from mucins of some strains of T. cruzi. The terminal β-D-Galp units are sites of sialylation by trans-sialidase which transfers sialic acid from the host to the parasite. Hexasaccharide 1 was synthesized by a [3 + 3]-convergent strategy based on a nitrile assisted glycosylation, using the trichloroacetimidate method. The β-D-Galf-(1→2)-β-D-Galf-D-GlcNAc synthon was sequentially constructed from the reducing end to the non-reducing end employing benzyl α-D-galactofuranoside as starting material for the internal Galf unit. The choice of this novel precursor, obtained in one-reaction step from galactose, allowed the introduction of an orthogonal and participating levulinoyl group at O-2. Thus, the diastereoselective construction of the Galf-β(1→4)-GlcNAc linkage by the trichloroacetimidate method of glycosylation was achieved. The (1)H NMR spectrum of alditol 2 was identical to the product released by β-elimination from the parasite mucin. 相似文献
85.
Eduardo H. Montoya Pablo A. Mendoza Patricia S. Bedregal Oscar R. Baltuano Isaac M. Cohen 《Journal of Radioanalytical and Nuclear Chemistry》2012,291(1):175-178
A method that combines the use of non-destructive neutron activation analysis and high-resolution α spectrometry has been
developed for determination of the activities of 234U and 238U in geological samples of low uranium content. The 238U content is determined by k0-based neutron activation analysis, whereas the 234U/238U relationship is measured by α spectrometry after isolation and electrodeposition of the uranium extracted from a lixiviation
with 6 M HCl. The main advantage of the method is the simplicity of the chemical operations, including the fact that the steps
destined to assure similar chemical state for the tracer and the uranium species present in the sample are not necessary.
The method was applied to soil samples from sites of the North Peru Coast. Uranium concentration range 3–40 mg/kg and the
isotopic composition correspond to natural uranium, with about 10% uncertainty. 相似文献
86.
87.
Fernando Garibay Bonales Rigoberto Vera Mendoza 《Proceedings of the American Mathematical Society》1998,126(1):97-103
In a Banach space, Gelfand's formula is used to find the spectral radius of a continuous linear operator. In this paper, we show another way to find the spectral radius of a bounded linear operator in a complete topological linear space. We also show that Gelfand's formula holds in a more general setting if we generalize the definition of the norm for a bounded linear operator.
88.
Kerman Gmez Gabriel Gonzlez Manuel Martínez Carolina Mendoza Beatriz Sienra 《Polyhedron》2006,25(18):3509-3518
The use of classical Werner-type cis-[Co(Cl)2(tetraamine)]+ (tetraamine = cyclen or tren) complexes for their complexation study of biologically relevant ligands has been pursued. These chlorocomplexes are found to be in the chloroaqua/chlorohydroxo forms under the physiological conditions used, their chloride substitution reactivity being dominated by conjugate base pathways, specially when tetraamine = cyclen. Further studies with nucleotides indicate that the substitution processes on cis-[Co(H2O)2(tetraamine)]3+, up to neutral pH, correspond to a simple reaction producing final stable phosphato bound mononucleotide complexes. These complexes are found to be an equilibrium mixture between monodentate O-phosphato and chelate O-phosphato-N-nucleotide forms. No evidence has been found for hydrolytic cleavage of the phosphato-nucleoside bond, as found in other systems with activated phosphates or higher pH values. A full kinetic profile of the process is proposed for the systems in the 2–7 pH range which is the same for chloride, nucleoside and nucleotide substitutions. The results are indicative of an important degree of outer-sphere hydrogen bonding between the cobaltocomplex and the entering biologically relevant ligands, as expected for these processes. 相似文献
89.
M. T. Alonso O. Juanes J. de Mendoza J. C. Rodrí guez-Ubis 《Journal of organometallic chemistry》1992,430(3):335-347
Palladium(II) coordination complexes of nine 3- or 5-arylpyrazoles (phenyl, 2-bromophenyl, or 3-methoxyphenyl), as well as of 3,5-diphenylpyrazole, are reported. A cis-trans mixture of [PdL2Cl2] isomers is found in the case of 3-aryl-1-methylpyrazoles, the cis-isomers being transformed into trans by heating. Only trans isomers are isolated with the other ligands. Cyclopalladation of 3-ary]-1-methylpyrazoles can be performed with palladium(II) acetate, and the resultant μ-acetate bridged dimers can be transformed into μ-chloro bridged dimers or acetylacetonate monomers. The structures of the complexes have been characterized by 1H- and 13C-NMR spectroscopy. 相似文献
90.