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11.
The collisional velocity dependence of the cross sections for fragmentation of mass-selected (CO2) n + (n+2...7) clusters in collisions with Ar atoms is presented. Interesting structure can be observed in the cross sections which indicate that the collision occurs between the Ar atom and one CO2 molecule within the cluster. The results may be explained by assuming that the collision leads to either vibrational excitation of a loosely bound CO2 monomer which then leaves the cluster or excitation of the entire cluster to a dissociative state.  相似文献   
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The pressure dependence of the reorientational correlation function for chloroform has been measured by analysis of the Raman 3019 cm? 1 A1 CH stretching lineshape at 1, 1000, and 2000 bar and 23°C. These reorientational correlation functions were obtained using the method of spectral Fourier deconvolution introduced by Bratos. The results are compared to the correlation times obtained from the NMR deuteron T1 relaxation times for CDCl3 and those calculated from high pressure viscosity measurements.  相似文献   
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We calculate the cross section for hadroproduction of a pair of heavy quarks in a (3)S(1) color-singlet state at next-to-leading order in QCD. This corresponds to the leading contribution in the nonrelativistic QCD expansion for J/psi and Upsilon production. The higher-order corrections have a large impact on the p(T) distributions, enhancing the production at high p(T) at both the Fermilab Tevatron and the CERN Large Hadron Collider. The total decay rate of a (3)S(1) into hadrons at next-to-leading order is also computed, confirming for the first time the result obtained by Mackenzie and Lepage in 1981.  相似文献   
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The high-temperature cubic phase of non-stoichiometric strontium ferrite SrFeOx (2.5≤x≤3.0) has been studied by in situ neutron powder diffraction in air over the temperature range 300-1273 K. The composition of SrFeOx changes within the range 2.56≤x≤2.81 from 1273 to 673 K, respectively.Rietveld refinements of the diffraction patterns show that the high-temperature cubic phase of SrFeOx is consistent with a face-centred Fm3c structure. This structure leads to agreement with previous density measurements. This cell allows the high-temperature structure of SrFeOx to be described in terms of a solid solution of the composition end members. Cubic SrFeOx at high temperature is found to closely obey Vegard's law. The density of cubic SrFeOx is also found to exhibit a linear relationship with composition.  相似文献   
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By measurement of the proton relaxation times T 1 and T 2 of CH3OD containing Co++ ions in dilute solution and the dependence of the observed decay time (T 2 ?) on t ep the separation between pulses in a Carr-Purcell sequence the coordination number is shown to be six. Since this result has previously been obtained by an independent method, the use of the dependence of T 2 ? on t ep to determine coordination numbers is justified for solutions of paramagnetic ions. The validity of analytical expressions derived previously has been checked by numerical methods, and the analytical expression is shown to be valid even in the presence of H 0 and H 1 inhomogeneity and inaccurate pulses of finite duration, provided that the Meiboom-Gill method is used. In an Appendix insight derived from the results of the numerical solutions is used to give a brief derivation of the dependence of T 2 ? on H 0, exchange rate and t ep.  相似文献   
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