Ein verbessertes Verfahren zum schnellen und sicheren Nachweis von Cholerabacillen

Ohne Zusammenfassung     

The influence of vinyl activating groups on β‐allyl sulfone‐based chain transfer agents for tough methacrylate networks

In radical polymerization of monofunctional monomers, addition fragmentation chain transfer (AFCT) agents are well known to regulate polymerization and yield polymers with lower molecular weights and narrower molecular weight distributions. Papers concerning bulk photopolymerization of monomer mixtures with AFCT agents are rarely found in literature. In this article, AFCT reagents based on β‐allyl sulfones with different vinyl activating groups were synthesized and compared. The compounds were tested in mono‐ and difunctional monomer systems providing information about the influence on photoreactivity, molecular weight, as well as thermal and mechanical properties of the resultant polymers. Where more potent activating groups (‐Ph, ‐CN) markedly influenced polymerization at lower concentrations, the AFCT reagent with an ester activating group reacted at a similar rate to the methacrylate monomer (C_T ≈ 1) and provided the best overall performance. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1417‐1427     

A Mössbauer study of an impactite from the Monturaqui crater

The iron mineralogy of samples of the Monturaqui impactite has been studied by Mössbauer spectroscopy. Magnetite, maghemite, goethite and a ferrous glass phase were identified. In a magnetic separate a bcc-structured iron-nickel alloy was identified in addition to the oxide phases. The oxides have formed by weathering of iron-nickel alloys.     

Reconstruction behaviour of fcc(110) transition metal surfaces and their vicinals

The fcc(110) surfaces are well known for their strong tendency to missing-row (MR) type reconstructions either in the clean state (Au, Pt) or driven by adsorbates (Ni, Cu, Pd, Ag). The present knowledge on the different reconstruction behaviour of flat (110) surfaces is reviewed. The survey focuses on recent scanning tunneling microscopy (STM) studies, which for the first time also elucidate the dynamics of the reconstruction process for the various systems. An overview of our recent STM and low energy electron diffraction studies on vicinal Au(110) and Ni(110) surfaces is given, aiming for a deeper understanding of the influence of steps on reconstruction behaviour of fcc(110) surfaces on the one hand, and on the stability of reconstructing vicinal surfaces on the other. Finally, we report on the reconstruction behaviour of Ir(110), which stabilizes in the clean state by formation of mesoscopic (331) facets and dereconstructs to the (1×1) phase upon oxygen adsorption at 700–900 K.     

On the difficulties and remedies in enforcing the div = 0 condition in the finite element analysis of thermal plumes with strongly temperature-dependent viscosity

A finite element (FE) analysis of experimentally observed creeping thermal plumes in a medium whose viscosity is strongly temperature-dependent is performed. Such plumes are considered to play an important role in numerous geological processes and numerical modelling is often the only option to study their physics. Initial simulations by means of the general-purpose Galerkin finite element package NACHOS-II demonstrated serious deficiencies of the method in modelling plumes with large viscosity contrasts, in spite of several options for the solution (mixed or penalty formulation) and the elements (continuous or discontinous pressure). In agreement with observations from FE simulations of isothermal Stokes flow in other studies, we have isolated the violation of the div = 0 or incompressibility constraint as the major culprit in the failure of the FE method. It is demonstrated that the a posteriori computed discrete divergence (DDIV) can be used as a diagnostic tool to evaluate the reliability of the FE solution and to rank the solution and element options provided in the NACHOS code. On the basis of these considerations, the combination of the mixed method with a Q₂-P₁ (discontinuous pressure) element turns out to be the most suitable for the present plume problem but is still unable to sufficiently enforce the div = 0 condition. With a goal to remedy this detrimental behaviour, several FE modifications and new approaches have been taken. These include: (i) use of a new scaling option for the governing equations which has the effect of equilbrating the stiffness matrices and thus improving their condition; (ii) implementation of several iterative solution techniques such as the iterated penalty and the Uzawa algorithm for the augmented Langrangian to better accommodate the dual role of the pressure; (iii) use of a multistep Newton method to better handle the high non-linearity of the coupled flow/transport problem. Although each of these options (or a combination of them) is able to improve on the quality of FE solution, the most startling amelioration has been gained with option (iii). Use of the latter resulted in very satisfactory modelling of the experimentally observed plumes.