Enzyme‐Compatible Dynamic Nanoreactors from Electrostatically Bridged Like‐Charged Surfactants and Polyelectrolytes

Reported is an unanticipated mechanism of attractive electrostatic interactions of fully neutralized polyacrylic acid (PAA) with like‐charged surfactants. Amphiphilic polymer‐surfactant complexes with high interfacial activity and a solubilization capacity exceeding that of conventional micelles are formed by bridging with Ca²⁺ ions. Incorporation of a protease into such dynamic nanoreactors results in a synergistically enhanced cleaning performance because of the improved solubilization of poorly water‐soluble immobilized proteins. Competitive interfacial and intermolecular interactions on different time‐ and length‐scales have been resolved using colorimetric analysis, dynamic tensiometry, light scattering, and molecular dynamic simulations. The discovered bridging association mechanism suggests reengineering of surfactant/polymer/enzyme formulations of modern detergents and opens new opportunities in advancing labile delivery systems.     

The S.M.A.R.T. (small mass,affordable, rapid,transfer-less) digestion method for heavy metal determinations

The S.M.A.R.T. (small mass, affordable, rapid, transfer-less) digestion method was developed to determine heavy metal concentrations in small sample masses. The S.M.A.R.T. digestion method is a hot water bath digestion where sample digestion and dilution are performed in the original sample tube. This method is faster than the typical methods used and reduces potential sources of error. Masses as small as 0.01 g have been digested and analysed using this method. The preparation and digestion time is reduced from 10 h to less than 4 h. Acid volumes are reduced from millilitres to microlitres and the only disposable supplies needed are sample tubes and pipette tips. Method accuracy was determined by digesting seven replicates of two standard reference materials using the S.M.A.R.T. method and analysing samples by inductively coupled plasma mass spectrometry. The S.M.A.R.T. digestion method was found to provide excellent recoveries for Al (76 ± 2.7%), Mn (99 ± 11%), Co (92 ± 17%), Ni (93 ± 28%), Cu (109 ± 33%), Zn (97 ± 7.1%), As (108 ± 20%), Sr (90 ± 12%), Mo (84 ± 23%), Ag (91 ± 1.8%), Cd (95 ± 6.2%), Sn (139 ± 52%) and Pb (95 ± 22%). This study has successfully developed an efficient and reproducible digestion method for heavy metal determination in limited biomass samples.     

Strategic analysis of the dairy transportation problem

The dairy transportation problem (DTP) consists of determining the best routes to be performed for collecting milk from farms and delivering it to processing plants. We study the particular case of the province of Quebec, where the Fédération des producteurs de lait du Québec is responsible for negotiating the transportation costs on behalf of producers. Several issues are highlighted in the actual process of designing contracts such as using historical data. We propose an approach based on scenario analysis that consists of revising both the steps and the information used to construct the routes. We develop a generalized tabu search algorithm that integrates the different characteristics of the DTP.     

Dynamic finite deformation viscoelasticity and energy-consistent time integration

In the present work we deal with the conserving integration of viscoelastic bodies undergoing finite deformations. Isotropic viscoelastic materials can be described by using a symmetric viscous internal variable for measuring the inelastic strains, and the right Cauchy-Green tensor as measure of the total strain (see Reese & Govindjee [1]). Then, by using the unsymmetric product tensor , the purely elastic strains enter the isotropic free energy function. Alternatively, the i application of the symmetric right stretch tensor as internal variable allows to define a symmetric elastic strain tensor which enters the free energy (see also Miehe [2]). These two different approaches lead to different evolution equations for the viscous internal variable. In this lecture, both evolution equations are discretised by an ordinary midpoint rule at each Gauss point of a standard nonlinear displacement-based finite element in space. For discretising the semidiscrete Hamilton's equations of motion in time, we use numerical time integrators which preserve the fundamental conservation laws of the underlying system. In particular, we make use of a modified midpoint rule according to the discrete gradient method, proposed in Gonzalez [3]. Numerical examples demonstrate the difference between both formulations. (© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

A review on initiatives for the management of daily medical emergencies prior to the arrival of emergency medical services

Central European Journal of Operations Research - Emergency services worldwide face increasing cost pressure that potentially limits their existing resources. In many countries, emergency services...     

Distributing the Encryption and Decryption of a Block Cipher

In threshold cryptography, the goal is to distribute the computation of basic cryptographic primitives across a number of nodes in order to relax trust assumptions on individual nodes, as well as to introduce a level of fault-tolerance against node compromise. Most threshold cryptography has previously looked at the distribution of public key primitives, particularly threshold signatures and threshold decryption mechanisms. In this paper, we look at the application of threshold cryptography to symmetric primitives, and in particular the encryption or decryption of a symmetric key block cipher. We comment on some previous work in this area and then propose a model for shared encryption / decryption of a block cipher. We will present several approaches to enable such systems and will compare them.AMS classification: 94A60, 94A62, 68P25     

The Ups and Downs of Percent (and Some Interesting Connections)

Percent is a standardized ratio comparison that is often used to describe relative amounts of increase and decrease. In this paper, the nonsymmetric relationship between percent of increase and percent of decrease is explored in several ways. Beginning with a simple graphical representation of the relationship, the functional relationship is developed, with relative decrease expressed as a function of relative increase. Once expressed in the form f(x) = 100x/(100 + x), an immediate connection is made to two other topics commonly found within the study of rates—the work problem and the harmonic mean. Finally, successive percents of increase or decrease are shown to be everyday applications of the geometric mean. This deeper look at a common mathematical concept has uncovered rich structural relationships between topics that are often isolated in the curriculum.