Effect of surface nanocrystallization induced by fast multiple rotation rolling on hardness and corrosion behavior of 316L stainless steel

A nanostructured layer was fabricated by using fast multiple rotation rolling (FMRR) on the surface of 316L stainless steel. The microstructure in the surface was characterized by transmission electron microscopy and X-ray diffraction. The effects of FMRR on the microhardness, surface roughness and corrosion behavior of the stainless steel were investigated by microhardness measurements, surface roughness measurements, potentiodynamic polarization curves and pitting corrosion tests. The surface morphologies of pitting corrosion specimens were characterized by scanning electron microscopy. The results show that FMRR can cause surface nanocrystallization with the grain size ranges from 6 to 24 nm in the top surface layer of the sample. The microhardness of FMRR specimen in the top surface layer remarkably increases from 190 to 530 HV. However, the surface roughness slightly rises after FMRR treatment. The potentiodynamic polarization curves and pitting corrosion tests indicated that the FMRR treated 316L stainless steel with a surface nanocrystallized layer reduced the corrosion resistance in a 3.5% NaCl solution and enhanced the pitting corrosion rate in a FeCl₃ solution. Possible reasons leading to the decrease in corrosion resistance were discussed.     

Radiation-induced changes in electrical conductivity and structure of BaPbO3 after γ-irradiation

Several barium plumbate (BaPbO₃) solid samples, made from PbO and BaCO₃ powder by chemistry liquid-phase coprecipitation, were investigated before and after γ-irradiation. The solid samples were irradiated by a ⁶⁰Co γ-irradiation source whose dose rate is about 0.7?kGy per hour. The irradiation times were 0, 72, 144, 216, 288 and 360?h. Then, the four-probe method, X-ray diffraction (XRD), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) were used to indicate the changes in electrical conductivity and microstructure of BaPbO₃ after γ-irradiation. The XRD results indicated that the content of PbO was reduced as the irradiation dose was increased and eventually vanished from the surface of samples. However, there was no new obvious substance phase found from the XRD atlas. It seems that the PbO transformed into nearly amorphous Pb₅O₈. The conjecture could be proved by the results of annealing experiment and SEM. The XPS results seem to show that the microstructure of BaPbO₃ was slightly changed.     

Slow electron acoustic double layer (SEADL) structures in bi-ion plasma with trapped electrons

The properties of ion acoustic double layer (IADL) structures in bi-ion plasma with electron trapping are investigated by using the quasi-potential analysis. The κ-distributed trapped electrons number density expression is truncated to some finite order of the electrostatic potential. By utilizing the reductive perturbation method, a modified Schamel equation which describes the evolution of the slow electron acoustic double layer (SEADL) with the modified speed due to the presence of bi-ion species is investigated. The Sagdeev-like potential has been derived which accounts for the effect of the electron trapping and superthermality in a bi-ion plasma. It is found that the superthermality index, the trapping efficiency of electrons, and ion to electron temperature ratio are the inhibiting parameters for the amplitude of the slow electron acoustic double layers (SEADLs). However, the enhanced population of the cold ions is found to play a supportive role for the low frequency DLs in bi-ion plasmas. The illustrations have been presented with the help of the bi-ion plasma parameters in the Earth's ionosphere F-region.     

Ar?NO团簇的同步辐射光电离研究

利用国家同步辐射实验室合肥光源的真空紫外同步辐射，使NO分子和Ar原子混合物的超声分子束发生光电离，测量了Ar，NO和异类团簇Ar·NO的光电离效率谱. 在谱中，在与Ar原子的共振线对应的能量区域(11.5—12.0 eV)观察到一个强的类共振结构. 这个结果表明，在异类团簇Ar·NO的内部，稀有气体Ar原子的激发能转移到与它接触的分子NO上，使分子NO发生电离. 关键词： Ar·NO团簇 同步辐射 光电离 能量转移     

纳米隧道结的量子电容现象

利用STM针尖和二维Au纳米团簇构造的双隧道结，通过对单电子隧穿谱的测量，研究了纳米隧道结的电容随隧道结宽度的变化，发现电容随结宽度的变化偏离了经典电容的行为，为纳米隧道结的量子电容效应提供了实验证据。     

26Al的加速器质谱测量及其应用

26Al是一个在多个学科都非常有意义的放射性核素。主要介绍了国内外在利用加速器质谱技术测量26Al时所开展的各种测量方法、各自的优缺点和测量灵敏度，并介绍了目前利用^26Al在地球科学、生物医学、核物理以及天体物理等诸多方面的应用研究工作。     

相对论平均场理论中的有效超子-核子相互作用

利用相对论平均场理论,结合单超核的实验数据,研究了核介质中的Λ超子–核子有效相互作用.通过符合13ΛC超核中Λ超子1s轨道的结合能实验值,给出了5组Λ超子–核子有效相互作用参数.利用这些参数组对质量数从9到2?0?8的单Λ超核和核物质中最低Λ态的束缚能进行了系统计算,得到的结果与实验值相符.     

尾式铁(Ⅲ)卟啉的合成及其光谱性质研究

合成了不同侧链长度的苯并咪唑基尾式卟啉及其Fe（Ⅲ）配合物。化合物经质谱、^1HMR、UVVisible、IR等表征，表明苯并咪唑基与卟啉环通过醚氧键和醚硫键相连。光谱学研究表明侧链较短不利于尾端基团的配位，长度对尾端基团的配位起着重要作用。     

C1催化剂MoS2/K2CO3/TiO2的制备

根据“盐类及氧化物等在高比表面载体上有自发分散倾向”的原理，制备了一种新型的用于由合成气（H2／CO）合成甲醇的催化剂MoS2/K2CO3/TiO2(DSA),该催化剂具有较好的耐硫性和对甲醇有较高的选择性。     

广义Hénon映射的滑模变结构控制同步

基于可线性化的非线性离散变结构跟踪控制方法实现了广义Hénon映射混沌系统的同步.广义Hénon映射的混沌吸引子比Hénon映射的混沌吸引子要复杂得多,对于保密通信来说,这种复杂性正是所期望的.提出的同步方法允许参数有适当的失配程度,这对工程实现是非常有利的,理论分析和仿真结果证实了该方法的有效性 关键词： 广义Hénon映射 混沌 同步 变结构控制