Hybrid composites of monodisperse pi-conjugated rodlike organic compounds and semiconductor quantum particles

Composite materials of quantum particles (Q-particles) arranged in layers within crystalline powders of pi-conjugated, rodlike dicarboxylic acids are reported. The synthesis of the composites, either as three-dimensional crystals or as thin films at the air-water interface, comprises a two-step process: 1) The preparation of the Cd salts 6 (Cd), 8 (Cd) or Pb salts 6 (Pb), 8 (Pb) of the oligo(p-phenyleneethynylene)dicarboxylic acids 6 (H), 8 (H), in which the metal ions are arranged in ribbons and are separated by the long axis of the organic molecules, as demonstrated by X-ray powder diffraction analysis of the solids and grazing incidence X-ray diffraction analysis of the films on water. 2) Topotactic solid/gas reaction of these salts with H(2)S to convert the metal ions into Q-particles of CdS or PbS embedded in the organic matrix that consists of the acids 6 (H) and 8 (H). These hybrid materials have been characterized by X-ray photoelectron spectroscopy and transmission electron microscopy.     

Probing the Kondo density of states in a three-terminal quantum ring

We have measured the Kondo effect in a quantum ring connected to three terminals. In this configuration nonlinear transport measurements allow us to check which lead contributes to the Kondo density of states (DOS) and which does not. The ring geometry allows a fine-tuning of the coupling to each lead through the Aharonov-Bohm effect via application of a magnetic field. When the ring is connected to two strongly and one weakly coupled leads, conductance through the weakly coupled lead provides a direct measurement of the DOS in the Kondo regime. By applying a bias between the two strongly coupled leads, we demonstrate directly the splitting of the out-of-equilibrium Kondo DOS.     

The Contribution of Pyroelectricity of AgI Crystals to Ice Nucleation

The pyroelectricity of AgI crystals strongly affects the icing temperature of super‐cooled water, as disentangled from that of epitaxy. This deduction was achieved by the design of polar crystalline ceramic pellets of AgI, with experimentally determined sense of polarity. These pellets are suitable for measuring both their pyroelectric properties as well as the icing temperature of super‐cooled water, separately on each of the expressed Ag⁺ and I^? hemihedral surfaces. The positive pyroelectric charge at the silver‐enriched side elevates the icing temperature, whereas the negative charge at the iodide side decreases that temperature. Moreover, the effect of pyroelectric charge remains dominant despite the presence of contaminants on both the silver and the iodide‐enriched surfaces. Consequently an electrochemical process for ice nucleation is suggested, which might be of relevance for understanding the role played by electric charges in heterogeneous icing processes in general.