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排序方式: 共有1379条查询结果,搜索用时 15 毫秒
91.
Dipl.‐Chem. Andreas Kraft B. Sc. Patrick Roth Dr. David Schmidt M. Sc. Johannes Stangl Prof. Dr. Klaus Müller‐Buschbaum Dr. Florian Beuerle 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(17):5982-5987
Hexakis‐substituted [60]fullerene adducts with icosahedral symmetry provide an unprecedented scaffold for the spatial arrangement of twelve functional groups with high geometric precision. This unique molecular symmetry identifies such polyfunctional organic building blocks as potential highly connective linkers for coordination polymer and metal–organic framework synthesis. Hereby, the linker exhibits a higher connectivity than the metal ions and with the main connectivity based on the ligand, this can create a new type of inversely cross‐linked framework. Two hexakis adducts bearing either twelve glycolic acid or 3‐hydroxypropionic acid side chains attached to its malonate units were incorporated as organic connectivity centers in the first fullerene‐containing three‐dimensional frameworks by coordination with Zn2+. 相似文献
92.
Rimer JD Roth DD Vlachos DG Lobo RF 《Langmuir : the ACS journal of surfaces and colloids》2007,23(5):2784-2791
We show that germania nanoparticle self-assembly in basic aqueous solutions occurs at a critical aggregation concentration (CAC) corresponding to a 1:1 GeO2/OH- molar ratio. A combination of pH, conductivity, and small-angle X-ray scattering (SAXS) measurements was used to monitor the effect of incremental additions of germanium (IV) ethoxide to basic solutions of sodium hydroxide or tetraalkylammonium cations. Plots of pH versus total germania concentration at varying alkalinities generated a phase diagram with three distinct regions. The diagram was analyzed with a thermodynamic model based on the chemical equilibria of germania speciation and dissociation. The model, which uses the GeO-H dissociation constant (pK = 7.1) as the single fitting parameter, quantitatively captures trends in the CAC and pH. SAXS patterns reveal that the germania nanoparticles have either a cubic or a spherical geometry of dimension approximately 1 nm that is independent of solution pH and cation. On the basis of these and other literature findings, we propose that the germania nanoparticle structure is that of the cubic octamer (double four-membered ring, Ge8O12(OH)8), which is common among condensed GeO2 materials and building units in [Ge,Si]-zeolites. Comparisons between germania and silica solutions show distinct differences in their phase behavior and nanoparticle structure. The results presented here, in combination with previous studies of siliceous solutions, provide a framework for ongoing studies of combined germania-silica phase behavior, which is part of an overarching effort to understand the influence of heteroatoms in the growth and structure direction of zeolites. 相似文献
93.
New copper(II) complexes of the hydrazone ligands H2salhyhb, H2salhyhp, and H2salhyhh, derived from salicylaldehyde and ω‐hydroxy carbonic acid hydrazides, have been synthesized and physically characterized. Two fundamental structures were found in solid state depending on the pH‐value of the reaction solution. Acidic conditions lead to the formation of the di‐μ‐phenoxo‐bridged dicationic complex dimers [{Cu(Hsalhyhb)}2]2+ ( 1a ), [{Cu(Hsalhyhp)}2]2+ ( 2a ), and [{Cu(Hsalhyhh)}2]2+ ( 3a ), isolated as perchlorate salts. The dimeric complexes show strong antiferromagnetic coupling with J = ?399 ( 1a ), ?410 ( 2a ), and ?311 cm?1 ( 3a ). Higher pH‐values resulted in the aggregation of neutral copper ligand fragments to the one‐dimensional coordination polymers [{Cu(salhyhb)}n] ( 1b ), [{Cu(salhyhp)}n] ( 2b ), and [{Cu(salhyhh)}n] ( 3b ). 3b has been examined by means of X‐ray crystallography and represents the first example of a structurally characterized neutral copper(II) N‐salicylidenehydrazide complex without additional ligands. The magnetic interactions in the polymers are also antiferromagnetic with J = ?125 ( 1b ), ?136 ( 2b ), and ?148 cm?1 ( 3b ), but strongly reduced compared to the corresponding dimeric complexes. The two basic structure types can be reversibly interconverted simply by pH‐control. 相似文献
94.
The excitation energy in the multiphoton ionization spectrum of the trans-1-naphthol/N(2) cluster shows only a small red shift with respect to isolated naphthol, indicating a van der Waals pi-bound structure rather than a hydrogen-bonded one. To confirm this interpretation, high-level electronic structure calculations were performed for several pi- and hydrogen-bonded isomers of this cluster. The calculations were carried out at the second order M?ller-Plesset (MP2) level of perturbation theory with the family of correlation consistent basis sets up to quintuple-zeta quality including corrections for the basis set superposition error and extrapolation to the MP2 complete basis set (CBS) limit. We report the optimal geometries, vibrational frequencies, and binding energies (D(e)), also corrected for harmonic zero-point energies (D(0)), for three energetically low-lying isomers. In all calculations the lowest energy structure was found to be an isomer with the N(2) molecule bound to the pi-system of the naphthol ring carrying the OH group. In the CBS limit its dissociation energy was computed to be D(0) = 2.67 kcal/mol (934 cm(-1)) as compared to D(0) = 1.28 kcal/mol (448 cm(-1)) for the H-bound structure. The electronic structure calculations therefore confirm the assignment of the experimental electronic spectrum corresponding to a van der Waals pi-bound structure. The energetic stabilization of the pi-bound isomer with respect to the hydrogen-bonded one is rather unexpected when compared with previous findings in related systems, in particular phenol/N(2). 相似文献
95.
Zellner M Winkler W Hayden H Diestinger M Eliasen M Gesslbauer B Miller I Chang M Kungl A Roth E Oehler R 《Electrophoresis》2005,26(12):2481-2489
For the preparation of proteins for proteome analysis, precipitation is frequently used to concentrate proteins and to remove interfering compounds. Various methods for protein precipitation are applied, which rely on different chemical principles. This study compares the changes in the protein composition of human blood platelet extracts after precipitation with ethanol (EtOH) or trichloroacetic acid (TCA). Both methods yielded the same amount of proteins from the platelet preparations. However, the EtOH-precipitated samples had to be dialyzed because of the considerable salt content. To characterize single platelet proteins, samples were analyzed by two-dimensional fluorescence differential gel electrophoresis. More than 90% of all the spots were equally present in the EtOH- and TCA-precipitated samples. However, both precipitation methods showed a smaller correlation with nonprecipitated samples (EtOH 74.9%, TCA 79.2%). Several proteins were either reduced or relatively enriched in the precipitated samples. The proteins varied randomly in molecular weight and isoelectric point. This study shows that protein precipitation leads to specific changes in the protein composition of proteomics samples. This depends more on the specific structure of the protein than on the precipitating agent used in the experiment. 相似文献
96.
97.
Using density functional theory we calculate the density profiles of a binary solvent adsorbed around a pair of big solute particles. All species interact via repulsive Gaussian potentials. The solvent exhibits fluid-fluid phase separation, and for thermodynamic states near to coexistence the big particles can be surrounded by a thick adsorbed "wetting" film of the coexisting solvent phase. On reducing the separation between the two big particles we find there can be a "bridging" transition as the wetting films join to form a fluid bridge. The effective (solvent mediated) potential between the two big particles becomes long ranged and strongly attractive in the bridged configuration. Within our mean-field treatment the bridging transition results in a discontinuity in the solvent mediated force. We demonstrate that accounting for the phenomenon of bridging requires the presence of a nonzero bridge function in the correlations between the solute particles when our model fluid is described within a full mixture theory based upon the Ornstein-Zernike equations. 相似文献
98.
Zwitterionic Cellulose Carbamate with Regioselective Substitution Pattern: A Coating Material Possessing Antimicrobial Activity 下载免费PDF全文
Thomas Elschner Claudia Lüdecke Diana Kalden Martin Roth Bettina Löffler Klaus D. Jandt Thomas Heinze 《Macromolecular bioscience》2016,16(4):522-534
A polyzwitterion is synthesized by regioselective functionalization of cellulose possessing a uniform charge distribution. The positively charged ammonium group is present at position 6, while the negative charge of carboxylate is located at positions 2 and 3 of the repeating unit. The molecular structure of the biopolymer derivative is proved by NMR spectroscopy. This cellulose‐based zwitterion is applied to several support materials by spin‐coating and characterized by means of atomic force microscope, contact angle measurements, ellipsometry, and X‐ray photoelectron spectroscopy. The coatings possess antimicrobial activity depending on the support materials (glass, titanium, tissue culture poly(styrene)) as revealed by confocal laser scanning microscopy and live/dead staining.
99.
100.
A five-step model for a quality assurance system is developed for an internal quality control check. It includes the quality
control of the decomposition method and the detection method as steps belonging together. The Wickbold combustion technique
as decomposition method in combination with atomic absorption spectrometry was chosen. The vaporization of the elements mercury,
arsenic, lead, antimony and selenium is based on combustion in an oxyhydrogen flame. To check the efficiency of the analytical
system, the uncertainty of results was calculated on the basis of the "Guide to the Expression of Uncertainty in Measurement".
Received: 13 January 1997 · Accepted: 29 March 1997 相似文献