高效毛细管电泳法手性分离D-氨基酸取代胸腺五肽类似物的研究

采用高效毛细管电泳法分离两对D-氨基酸取代的胸腺五肽类似物。对影响分离的缓冲液pH值、电泳温度、电泳电压等进行了系统的研究。用含20mmol/L2,6-二甲基-β-环糊精(DM-β-CD),40mmol/L磷酸盐缓冲液(Ⅰ:pH6.03;Ⅱ:pH5.05)作运行缓冲液,柱温15℃,电压20kV,使样品获得基线分离,取得了满意的分离结果。结果显示,两组样品的D-氨基酸取代物均比L-氨基酸取代物出峰早,提示D-氨基酸取代物的电泳移动速度较快,与DM-β-CD的结合稳定性较L-氨基酸取代物弱。     

三环无源谐振腔在光纤激光器中的选频特性

利用琼斯矩阵对一种三环嵌套的无源谐振腔的选频特性进行了分析,并根据无源谐振腔选频的原理,设计了一种基于三环嵌套无源谐振腔的掺铒光纤激光器.实验结果表明:三环嵌套的无源谐振腔具有良好的选频特性,当泵浦功率为159 mW时,得到了稳定的单纵模激光信号输出;输出功率的最大波动为0.04 dB,输出中心波长最大漂移为0.016...     

Visible photoluminescence of nanometer-sized SiGe/Si heterostructure fabricated by ion implantation

An innovative fabrication technique for the nanometer-sized SiGe/Si heterostructure was developed in this study. Ge was induced in Si substrate by two-step ion implantation. The spherical SiGe nanoclusters are self-assembled in the Si substrate by subsequent rapid thermal annealing at 1,100 °C. The diameter of the spherical SiGe nanoclusters is 5–7 nm. Visible photoluminescence from this nanometer-sized SiGe/Si heterostructure at room temperature was investigated. We found three peak energies of visible luminescence spectra at 1.97, 2.13, and 2.16 eV, respectively. The luminescence intensity depends on the number of the nanoclusters and will be decreased because of the micro-defects around the heterostructure, which is discussed in detail.     

On the harmonic oscillator on the Lobachevsky plane

We introduce the harmonic oscillator on the Lobachevsky plane with the aid of the potential V (ϱ) = (a ² ω ²/4) sinh(ϱ/a)², where a is the curvature radius and ϱ is the geodesic distance from a chosen center. Thus, the potential is rotationally symmetric and unbounded, as in the Euclidean case. The eigenvalue equation leads to the differential equation of spheroidal functions. We provide a basic numerical analysis of eigenvalues and eigenfunctions provided that the value of the angular momentum, m, is equal to 0. Dedicated to the memory of V. A. Geyler     

Growth,spectroscopic and laser properties of Yb<Superscript>3<Emphasis Type="Bold">+</Emphasis></Superscript>-doped GdAl<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>4</Subscript> crystal: a candidate for infrared laser crystal

Yb³⁺:GdAl₃(BO₃)₄ (hereafter Yb³⁺:GAB) crystals with large sizes and good optical quality have been grown by the top-seed solution growth (TSSG) method. The polarized absorption and emission spectra have been investigated at room temperature. For the σ-polarization, the intensities of both absorption and emission spectra are stronger than those for the π-polarization, the σ-absorption cross section of Yb³⁺ in GAB being 3.43×10^-20 cm² at 977 nm, and the σ-emission cross section being 0.98×10^-20 cm² at 1045 nm. The fluorescence lifetime of the ² F _5/2→² F _7/2 transition was measured to be 800 μs in the 5% doped sample used for our laser experiments, 993 μs in a 10% doped sample and 569 μs in a 0.5% doped sample. The laser parameters were estimated as: β_min=0.022, I_sat=10.4 kW/cm² and I_min=0.23 kW/cm². About 0.4 W laseroutput at the wavelength of 1043 nm was achieved when the Yb³⁺:GAB crystal was pumped by a 974 nm laser diode, with 27.4% slope efficiency. PACS 42.55.-f; 42.70.Hj; 78.20.-e; 81.10.Dn     

A tunable multi-wavelength Brillouin–erbium fiber laser with fourfold Brillouin frequency spacing

We have experimentally demonstrated a tunable multi-wavelength Brillouin–erbium fiber laser with over 40 GHz spacing utilizing two cascaded double Brillouin-frequency-spacing cavities. In this laser configuration, two segments of 25 km-long single-mode fibers are used as Brillouin gain medium in each ring cavity, and a segment of 8 m-long erbium-doped fiber with 980 nm pump is employed to amplify Brillouin pump (BP). At BP wavelength of 1550 nm, BP power of 8.3 dBm (6.8 mW) and the maximum 980 nm pump power of 27.78 dBm (600 mW), seven output channels with fourfold Brillouin-frequency spacing, and the tuning range of 15 nm from 1545 to 1560 nm are achieved. The proposed multi-wavelength Brillouin–erbium fiber laser has wide applications, such as in microwave signal generation and optical communications.     

NO dissociation pathways on Rh(1 0 0), (1 1 0), and (1 1 1) surfaces: A comparative density functional theory study

The chemisorption and dissociation pathways of NO on the Rh(1 0 0), (1 1 0), and (1 1 1) surfaces are studied by the plane-wave density functional theory (DFT) with CASTEP program. In addition, the electronic and geometrical effects that affect the NO dissociation reactions have been investigated in detail. The calculation results are presented as following: The effective activation energies of the best NO dissociation pathways on the Rh(1 0 0), the Rh(1 1 0), and the Rh(1 1 1) are 0.63, 0.66 and 1.77 eV, respectively. The activity of the Rh planes for NO dissociation is in the order of Rh(1 0 0) ≈ Rh(1 1 0) > Rh(1 1 1). The low dissociation barrier for Rh(1 0 0) and Rh(1 1 0) is associated with the existence of a lying-down NO structure which acts as a precursor for dissociation. By Mulliken population analysis and structure analysis, both electronic and geometrical effects are found to affect the NO dissociation reactions, but the geometrical effect exceed the electronic. The energy decomposition scheme has been used to provide further insight into the NO dissociation reactions. Based on the calculations, the interaction energy between N and O in the transition state on the Rh(1 1 1) is found much larger than that on the Rh(1 0 0) and the Rh(1 1 0). The major differences of should originate from the variation of the bonding competition effect.     

Optical properties of Dy ions in sodium gadolinium tungstates crystal

Dy³⁺-doped NaGd(WO₄)₂ crystal with sizes of about Φ20×40 mm² was grown by the Czochralski technique along the (0 0 1) orientation. Polarized absorption spectra, fluorescence spectra, and fluorescence decay curve of Dy³⁺-doped NaGd(WO₄)₂ have been recorded at room temperature. Based on the Judd-Ofelt (J-O) theory, the intensity parameters from the measured line strengths were evaluated. The J-O parameters were used to predict radiative transition probabilities, radiative lifetimes and branching ratios for various excited levels of Dy³⁺-doped NaGd(WO₄)₂ crystal. The luminescent quantum efficiency of the ⁴F_9/2 level was determined to be approximately 63% for this material. The emission cross-section of the ⁴F_9/2→⁶H_13/2 transition was estimated by using the Füchtbauer-Ladengurg method.     

Stable multiwavelength and passively mode-locked Yb-doped fiber laser based on nonlinear polarization rotation

Based on the nonlinear polarization rotation (NPR) technique and a fiber Mach–Zehnder interferometer (MZI), a fiber laser which can work in two different modes has been demonstrated. In one mode, it works as a continuous wave (CW) multiwavelength laser, and stable dual-, triple- and tetra-wavelength lasing with the wavelength spacing of 1.1 nm are obtained. In the other mode, it works as a passively mode-locked fiber laser, and the generated pulses have a repetition rate of 10.6 MHz, an FWHM width of 800 ps and the largest energy of 1 nJ. The multi-functional property makes this fiber laser a very convenient, cost effective and multi-purpose laser source.     

牵引变流器网侧电流谐波抑制研究

作为电力机车牵引传动系统核心部件的牵引变流器是牵引供电网的主要谐波来源之一。牵引变流器采用的单相四象限整流器,输出含有二次脉动,且工作开关频率较低,导致变流器网侧电流谐波问题严重。目前单相四象限整流器的控制脉冲产生主要采用SPWM技术。与SPWM相比,SHEPWM（特定谐波消除PWM）可以针对性的消除特定的谐波,谐波含量更小,效率更高,但其无法消除调制波中本身就存在的谐波。针对SHEPWM调制策略进行了分析设计,同时对陷波滤波器技术、PR控制策略和LC回路在降低谐波含量中的作用进行深入分析。经过合理的方案选择,有效的降低了网侧电流谐波含量,并通过MATLAB仿真实验进行了分析验证。