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131.
Multilayer thin film coatings were prepared on silicon substrates. Poly(vinyl alcohol) was adsorbed from aqueous solution to propyldimethylsilyl-modified silicon wafers. This thin semicrystalline coating was chemically modified using acid chlorides to form thicker, hydrophobic coatings. The products of the modification reactions allowed adsorption of a subsequent layer of poly(vinyl alcohol) that could subsequently be hydrophobized. This two-step process (adsorption/chemical modification) allows layer-by-layer deposition to prepare coatings with thickness, chemical structure, and wettability control. 相似文献
132.
Effects of exchanged surfactant cations on the pore structure and adsorption characteristics of montmorillonite 总被引:17,自引:0,他引:17
Wang CC Juang LC Lee CK Hsu TC Lee JF Chao HP 《Journal of colloid and interface science》2004,280(1):27-35
Ca-montmorillonite (Ca-Mont) was exchanged with two quaternary amines, tetramethylammonium (TMA) chloride and hexadecyltrimethylammonium (HDTMA) bromide, to study the surfactant ion exchange effect on the pore structure, surface characteristics, and adsorption properties of montmorillonite. The revolution of both the surface area and pore structure of montmorillonite was characterized based on classical and fractal analyses of the nitrogen isotherms as well as the XRD patterns. The change of surface characteristics was identified from FTIR patterns and zeta-potential plots. The adsorption isotherms of acid dye, Amido Naphthol Red G (AR1), were then measured to identify the effects of the ion-exchange process on the adsorption properties of montmorillonite. It was found that the exchange processes might induce an increase or decrease in the surface area, pore size, pore volume, and surface fractal dimension D of montmorillonite, depending on the size, the molecular arrangement, and the degree of hydration of the exchanged ion in the clay. On the other hand, it was also found that the hydrophobic bonding by conglomeration of large C(16) alkyl groups associated with HDTMA could cause positive charge development on the surface of montmorillonite, which was not observed for TMA-modified montmorillonite (TMM). The effects of the alteration of the surface characteristics of montmorillonites on their adsorption selectivity for acid dye were discussed. 相似文献
133.
Electrophoresis of a sphere at an arbitrary position in a spherical cavity filled with Carreau fluid
Boundary effects on the electrophoretic behavior of a charged entity are of both fundamental and practical significance. Here, they are examined by considering the case where a sphere is at an arbitrary position in a spherical cavity under conditions of low surface potential and weak applied electrical field. Previous analyses are extended to the case of a non-Newtonian fluid, and a Carreau model is adopted for this purpose. The effects of key parameters such as the thickness of a double layer, the relative sizes of particle and cavity, the position of a particle, and the nature of a fluid on the electrophoretic mobility of a particle are discussed. Several interesting phenomena are observed. For example, if the applied electric field points toward north, the mobility of a particle has a local maximum when it is at the center of a cavity. However, if a particle is sufficiently close to the north pole of a cavity, its mobility exhibits a local minimum as its position varies. This does not occur when the particle is close to the south pole of the cavity; instead, it may move in the direction opposite to that of the applied electric field. For a Newtonian fluid, if a particle is close to the north pole of a cavity, its upward movement yields a clockwise (counterclockwise) vortex near the north pole of the cavity and a counterclockwise (clockwise) vortex near the south pole of the cavity on its right (left)-hand side. The latter is not observed for a Carreau fluid. 相似文献
134.
Determination of Pd,Rh, Pt,Au in road dust by electrothermal vaporization inductively coupled plasma mass spectrometry with slurry sampling 总被引:1,自引:0,他引:1
Inductively coupled plasma mass spectrometry coupled with ultrasonic slurry sampling electrothermal vaporization (USS-ETV-ICP-MS) has been applied to determine Pd, Rh, Pt and Au in 0.5% m/v slurries of several road dust samples. 2% m/v ammonium pyrrolidine dithiocarbamate (APDC) was used as the modifier to enhance the ion count. The influence of instrument operating conditions, slurry preparation and interferences on the ion count was reported. This method has been applied to the determination of Pd, Rh, Pt and Au in BCR 723 Road Dust and NIST SRM 2709 San Joaquin Soil reference materials and two road dust samples collected locally. The analysis results of the standard reference materials agreed with the certified values. Precision between sample replicates was better than 10% for all the determinations. The method detection limits estimated from standard addition curves were 0.9, 0.4, 0.6 and 0.4 ng g−1 for Pd, Rh, Pt and Au, respectively, in original dust samples. 相似文献
135.
Fong-Fu Hsu Irfan J. Lodhi John Turk Clay F. Semenkovich 《Journal of the American Society for Mass Spectrometry》2014,25(8):1412-1420
We describe a linear ion-trap (LIT) multiple-stage (MSn) mass spectrometric approach towards differentiation of alkylacyl, alk-1-enylacyl- and diacyl-glycerophoscholines (PCs) as the [M – 15]– ions desorbed by electrospray ionization (ESI) in the negative-ion mode. The MS4 mass spectra of the [M – 15 – R2′CH = CO]– ions originated from the three PC subfamilies are readily distinguishable, resulting in unambiguous distinction of the lipid classes. This method is applied to two alkyl ether rich PC mixtures isolated from murine bone marrow neutrophils and kidney, respectively, to explore its utility in the characterization of complex PC mixture of biological origin, resulting in the realization of the detailed structures of the PC species, including various classes and many minor isobaric isomers. Graphical abstract
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136.
Selective Transfer Hydrogenation and Hydrogenation of Ketones Using a Defined Monofunctional (P^N(Bn)^N(Bn)^P)–RuII Complex 下载免费PDF全文
Shih‐Fan Hsu Prof. Dr. Bernd Plietker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(15):4242-4245
A defined (P^N^N^P)–Ru complex possessing tertiary amines within the ligand backbone proved to be highly active both in transfer hydrogenations and hydrogenations of a variety of ketones. As compared to the existing catalytic systems, no bifunctional activation of H2 or of the substrate by the metal center and a secondary amine within the ligand backbone is required to obtain high activities at catalyst loadings of down to 10 ppm. 相似文献
137.
Ling-Yang Hsu Qiumin Liang Zhiheng Wang Hsin-Hung Kuo Wun-Shan Tai Shi-Jian Su Xiuwen Zhou Yi Yuan Yun Chi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(67):15375-15386
Iridium complexes bearing chelating cyclometalates are popular choices as dopant emitters in the fabrication of organic light-emitting diodes (OLEDs). In this contribution, we report a series of blue-emitting, bis-tridentate IrIII complexes bearing chelates with two fused five-six-membered metallacycles, which are in sharp contrast to the traditional designs of tridentate chelates that form the alternative, fused five-five metallacycles. Five IrIII complexes, Px-21 – 23 , Cz-4 , and Cz-5 , have been synthesized that contain a coordinated dicarbene pincer chelate incorporating a methylene spacer and a dianionic chromophoric chelate possessing either a phenoxy or carbazolyl appendage to tune the coordination arrangement. All these tridentate chelates afford peripheral ligand–metal–ligand bite angles of 166–170°, which are larger than the typical bite angle of 153–155° observed for their five-five-coordinated tridentate counterparts, thereby leading to reduced geometrical distortion in the octahedral frameworks. Photophysical measurements and TD-DFT studies verified the inherent transition characteristics that give rise to high emission efficiency, and photodegradation experiments confirmed the improved stability in comparison with the benchmark fac-[Ir(ppy)3] in degassed toluene at room temperature. Phosphorescent OLED devices were also fabricated, among which the carbazolyl-functionalized emitter Cz-5 exhibited the best performance among all the studied bis-tridentate phosphors, showing a maximum external quantum efficiency (EQEmax) of 18.7 % and CIEx,y coordinates of (0.145, 0.218), with a slightly reduced EQE of 13.7 % at 100 cd m−2 due to efficiency roll-off. 相似文献
138.
Jen-Yi Hsu Jing-Fang Hsu Yet-Ran Chen Chia-Lang Shih Yi-Sheng Hsu Yi-Jen Chen Shu-Han Tsai Pao-Chi Liao 《Analytica chimica acta》2016
Human biomonitoring is the assessment of actual internal contamination of chemicals by measuring exposure markers, chemicals or their metabolites, in human urine, blood, serum, and other body fluids. However, the metabolism of chemicals within an organism is extremely complex. Therefore, the identification of metabolites is often difficult and laborious. Several untargeted metabolomics methods have been developed to perform objective searching/filtering of accurate-mass-based LC-MS data to facilitate metabolite identification. In this study, three metabolomics data processing approaches were used for chemical exposure marker discovery in urine with an LTQ-Orbitrap high-resolution mass spectrometry (HRMS) dataset; di-isononyl phthalate (DINP) was used as an example. The data processing techniques included the SMAIT, mass defect filtering (MDF), and XCMS Online. Sixteen, 83, and 139 probable DINP metabolite signals were obtained using the SMAIT, MDF, and XCMS procedures, respectively. Fourteen probable metabolite signals mined simultaneously by the three metabolomics approaches were confirmed as DINP metabolites by structural information provided by LC-MS/MS. Among them, 13 probable metabolite signals were validated as exposure-related markers in a rat model. Six (m/z 319.155, 361.127, 373.126, 389.157, 437.112 and 443.130) of the 13 exposure-related DINP metabolite signals have not previously been reported in the literature. Our data indicate that SMAIT provided an efficient method to discover effectively and systematically urinary exposure markers of toxicant. The DINP metabolism information can provide valuable information for further investigations of DINP toxicity, toxicokinetics, exposure assessment, and human health effects. 相似文献
139.
The energy transfer between Kr atoms and highly vibrationally excited, rotationally cold phenanthrene and diphenylacetylene in the triplet state was investigated using crossed-beam/time-of-flight mass spectrometer/time-sliced velocity map ion imaging techniques. Compared to the energy transfer between naphthalene and Kr, energy transfer between phenanthrene and Kr shows a larger cross-section for vibrational to translational (V → T) energy transfer, a smaller cross-section for translational to vibrational and rotational (T → VR) energy transfer, and more energy transferred from vibration to translation. These differences are further enlarged in the comparison between naphthalene and diphenylacetylene. In addition, less complex formation and significant increases in the large V → T energy transfer probabilities, termed supercollisions in diphenylacetylene and Kr collisions were observed. The differences in the energy transfer between these highly vibrationally excited molecules are attributed to the low-frequency vibrational modes, especially those vibrations with rotation-like wide-angle motions. 相似文献
140.
Biosynthesis of Streptolidine Involved Two Unexpected Intermediates Produced by a Dihydroxylase and a Cyclase through Unusual Mechanisms 下载免费PDF全文
Dr. Chin‐Yuan Chang Syue‐Yi Lyu Dr. Yu‐Chen Liu Ning‐Shian Hsu Dr. Chih‐Chung Wu Dr. Cheng‐Fong Tang Kuan‐Hung Lin Dr. Jin‐Yuan Ho Dr. Chang‐Jer Wu Dr. Ming‐Daw Tsai Dr. Tsung‐Lin Li 《Angewandte Chemie (International ed. in English)》2014,53(7):1943-1948
Streptothricin‐F (STT‐F), one of the early‐discovered antibiotics, consists of three components, a β‐lysine homopolymer, an aminosugar D ‐gulosamine, and an unusual bicyclic streptolidine. The biosynthesis of streptolidine is a long‐lasting but unresolved puzzle. Herein, a combination of genetic/biochemical/structural approaches was used to unravel this problem. The STT gene cluster was first sequenced from a Streptomyces variant BCRC 12163, wherein two gene products OrfP and OrfR were characterized in vitro to be a dihydroxylase and a cyclase, respectively. Thirteen high‐resolution crystal structures for both enzymes in different reaction intermediate states were snapshotted to help elucidate their catalytic mechanisms. OrfP catalyzes an FeII‐dependent double hydroxylation reaction converting L ‐Arg into (3R,4R)‐(OH)2‐L ‐Arg via (3S)‐OH‐L ‐Arg, while OrfR catalyzes an unusual PLP‐dependent elimination/addition reaction cyclizing (3R,4R)‐(OH)2‐L ‐Arg to the six‐membered (4R)‐OH‐capreomycidine. The biosynthetic mystery finally comes to light as the latter product was incorporation into STT‐F by a feeding experiment. 相似文献