Solubility and thermodynamic properties of acetaminophen in 1-hexyl-4-methylpyridinium bromide and water mixtures

The solubility data of acetaminophen in binary mixtures of 1-hexyl-4-methylpyridinium bromide and water were obtained over the temperature range from 293.15 to 313.15 K by using the gravimetric method under atmospheric pressure. Using the experimentally measured solubility values, the thermodynamic properties of dissolution, mixing and transfer processes were evaluated. The measured solubilities were correlated by the modified Wilson and the electrolyte non-random two liquid (E-NRTL) models.     

A new phosphorothioic triamide structure: P(S)[NHCH2C6H5]3

The structure of N,N′,N′′‐tribenzylphosphorothioic triamide, C₂₁H₂₄N₃PS, (I), and analysis of the bond‐angle sums at the N atoms for this compound, and for 74 structures with a P(S)[N]₃ skeleton and the N atom in a three‐coordinate geometry found in the Cambridge Structural Database [CSD; Groom & Allen (2014). Angew. Chem. Int. Ed. 53 , 662–671], are reported. For (I), the bond‐angle sum at one of the N atoms [359 (1)°] shows a nearly planar configuration, while the other two show a nonplanar geometry with bond‐angle sums of 342 (1) and 347 (1)°. The location of the atoms attached to the nonplanar N atoms suggests an anti orientation of the corresponding lone electron pairs (LEPs) on these N atoms with respect to the P=S group. For 74 structures with a P(S)[N]₃ skeleton and with the N atom in a three‐coordinate geometry, the bond‐angle sums at the N atoms were found to be in the range 293–360°. Among 307 such three‐coordinate N atoms, 39% (120 N atoms) have bond‐angle sums in the range 359–360°, in accordance with sp² hybridization, and 45% (138 N atoms) have bond‐angle sums in the range 352–359°, with hybridization close to sp². For the orientation of the LEP with respect to the P=S group, the anti orientation was found to be a general rule for N atoms, with the corresponding bond‐angle sums deviating by more than 8° from the planar value of 360°. In the title structure, the S atom takes part in intermolecular (N—H...)(N—H...)S hydrogen bonds, connecting the molecules into extended chains parallel to the b axis. The co‐operation of one N atom in an N—H...S hydrogen bond as an H‐atom donor, and in an N—H...N hydrogen bond as an acceptor, is a novel feature of the crystal structure.     

A High Sensitive TNT Sensor Based on Electrochemically Reduced Graphene Oxide‐Poly(amidoamine) Modified Electrode

In this paper, the electrochemically reduced graphene oxide‐poly(amidoamine) hybrid (ErGO‐PAMAM) have been used for fabrication of TNT electrochemical sensor. The prepared modified electrode is characterized with X‐ray photoelectron spectroscopy (XPS), fourier transform infrared spectroscopy (FT‐IR), electrochemical impedance spectroscopy (EIS), energy‐dispersive X‐ray (EDX) spectroscopy, scanning electron microscopy (SEM) and atomic force microscope (AFM). Based on obtained results, it is can be seen that the ErGO‐PAMAM/GCE has high response to TNT than the other graphene based modified electrodes. The resulting electrochemical sensor exhibited good response to TNT with linear range from 0.05 to 1.2 ppm with a low detection limit of 0.0015 ppm.     

Functionalization of polypropylene by grafting with itaconic acid

Grafting of polypropylene was carried out in both boiling xylene and decalin as solvent medium with itaconic acid (2-methylenesuccinic acid) as functional polar monomer using 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane (Lupersol 101) as radical initiator. It was found that the temperature influenced the percentage of monomer grafted onto polypropylene and that the amount of monomer incorporated was practically constant after 5 min. The results also show that the amount of monomer incorporated is proportional to the initial monomer concentration used in the grafting reaction, although for higher initiator concentrations a reduction in the percentage of grafting was found.     

Dynamic analysis of a novel wide-tunable microbeam resonator with a sliding free-of-charge electrode

In this paper, a MEMS-based resonator with a novel effective stiffness tunability is presented. The performance of the proposed resonator is based on the transversal vibration of the two porous cantilever microbeams with a rectangular microplate at the end of the structure. The microplate as a free-of-charge slider electrode is in contact with two other fixed substrate electrodes via the thin layer of dielectric material. Applying a constant DC voltage to the two fixed electrodes leads to the movement of free electrons in the slider and eventually to the formation of two series capacitors. As a result, the slider meets a nonlinear electrostatic force proportional to the square of the applied DC voltage. It will act as a nonlinear spring with a tunable stiffness during the oscillation of the resonator. The coupled nonlinear equations governing the longitudinal and transversal vibration of the resonator are extracted in the presence of the nonlinear voltage-sliding spring. Its steady-state solution is obtained based on a physically based learning method that makes it possible to obtain frequency response for the first harmony as well as for the higher harmonies and to predict primary and secondary resonances in different harmonies of the response. The effect of the applied tuning DC voltage, the geometrical parameters of the resonator, and the cantilever's porosity on the dynamic response of the resonator are investigated. It is shown that the tuning stiffness of this voltage-sliding spring provides a highly effective solution to realize an extreme tunable range. In the end, a modified tunable structure is introduced in which the folded beams are replaced with common ones. The modified resonator by making the nonlinear behavior of the resonator least can improve its performance significantly.

     

Thermolysis of disubstituted 1,2-dioxetanes: Activation parameters and chemiexcitation yields

trans-3-Methyl-4-(p-anisyl)-1,2-dioxetane 1, trans-3-methyl-4-(o-anisyl)-1,2-dioxetane 2 , 3-methyl-3-benzyl-1,2-dioxetane 3 , and 3-methyl-3-p-methoxybenzyl-1,2-dioxetane 4 were synthesized in low yield by the β-bromo hydroperoxide method. The activation parameters were determined by the chemiluminescence method (for 1 ΔG≠ = 22.8 ± 0.3 kcal/mol, Δ≠ = 22.2, ΔS≠ = −1.7 e.u., k₆₀ = 7.6 × 10⁻³s⁻¹; for 2 ΔG≠ + 23.6 ± 0.3 kcal/mol, ΔH≠ = 22.8, ΔS≠ = −2.2 e.u., k₆₀ = 2.5 × 10⁻³S⁻¹; for 3 ΔG≠ = 24.0 ± 0.4 kcal/mol, ΔH≠ = 23.1, ΔS≠ = −2.7 e.u., k₆₀ = 1.2 × 10⁻³S⁻¹; for 4 ΔG≠ = 24.0 ± 0.2 kcal/mol, ΔH≠, = 23.2, ΔS≠, = −2.4 e.u., k₆₀ = 1.2 × 10⁻³s⁻¹). Thermolysis of 1–4 produced excited carbonyl fragments (direct production of high yields of triplets relative to excited singlets) [chemiexcitation yields ϕ^T, ϕ^S, respectively: for 1 0.02, 0.0001; for 2 0.02, 0.0001; for 3 0.03, 0.0002; for 4 0.02, 0.0001]. The effect of paramethoxyaryl substitution was consistent with electronic effects. The ortho substitution in 2 resulted in an increase in stability of the dioxetane, opposite that observed for an electronic effect. The results are discussed in relation to a diradical-like mechanism.     

On propagation of convergence

We discuss some classical theorems and some recent results in the field of complex approximation from the viewpoint of propagation of convergence. We also prove a theorem on propagation of convergence in C².     

Construction of amperometric biosensor modified with conducting polymer/carbon dots for the analysis of catechol

Phenolic compounds used in food industries and pesticide industry, are environmentally toxic and pollute the rivers and ground water. For that reason, detection of phenolic compounds such as catechol by using simple, efficient and cost-effective devices have been becoming increasingly popular. In this study, a suitable and a novel matrix was composed using a novel conjugated polymer, namely poly[1-(5-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiophen-2-yl)furan-2-yl)-5-(2-ethylhexyl)-3-(furan-2-yl)-4H thieno[3,4-c]pyrrole-4,6(5H)-dione] (PFTBDT) and carbon dots (CDs) to detect catechol. PFTBDT and CDs were synthesized and the optoelectronic properties of PFTBDT were investigated via electrochemical and spectroelectrochemical studies. Laccase enzyme was immobilized onto the constructed film matrix on the graphite electrode. The proposed biosensor was found to have a low detection limit (1.23 μM) and a high sensitivity (737.44 μA/mM.cm⁻²) with a linear range of 1.25–175 μM. Finally, the applicability of the proposed enzymatic biosensor was evaluated in a tap water sample and a satisfactory recovery (96–104%) was obtained for catechol determination.     

Investigation of energy performance in a U-shaped evacuated solar tube collector using oxide added nanoparticles through the emitter,absorber and transmittal environments via discrete ordinates radiation method

Journal of Thermal Analysis and Calorimetry - This work is a three-dimensional numerical study of a U-shaped evacuated tube solar collector employing different types of oxide nanofluids including...     

Separation/Competitive Transport of Heavy Metal Ions across the Bulk Liquid Membranes with N,N',N'-Tris(4-methylphenyl)phosphoric Triamide As Carrier

Russian Journal of Physical Chemistry A - The competitive bulk liquid membrane transport of seven metal ion by N,N',N''-tris(4-methylphen-yl)phosphoric triamide carrier was studied...