Conical enclosures rely on the conical cavity and can be used as radiation concentrators. Two circular cross-section baffles were used to improve the heat transfer of this geometry. By changing the rigid fins to porous, it could improve the heat transfer. Al2O3/water nanofluid was also employed to enhance the heat transfer performance of the cavity. For this purpose, numerical analysis of three-dimensional natural convection heat transfer was performed in a conical cavity with two types of fins. The best combination of fins arrangement for the next step was selected using the differential evolutionary optimization method (D.E). In this case study, a new combination of laminar and turbulence methods was employed for the first time to increase the accuracy of the natural convection solution. This combination is based on the laminar solution by suppressing the perturbation parameter in the turbulence method which led to more accurate results. The analysis results showed that a conical cavity with optimized fin geometry can lead to a 23% increase in Nu. The best porosity for the inner fin was calculated 40% in the case of constant porosity. Ascending porosity along the fin, whose increase was more intense near the base and slower near the cone's tip, was the best variable porosity for the inner fin.
Research on Chemical Intermediates - We describe synthesis and characterization of a series of novel multifunctional methacrylate-based dental monomers. Triethanolamine was reacted with glycidyl... 相似文献
The purpose of this paper is computing the fundamental relations and automorphism groups of very thin Hv-groups. In this regards, we first investigate some basic properties of Hv-groups and then we show that any given group is isomorphic to the fundamental group of a nontrivial Hv-group. The main properties of very thin Hv-groups are also investigated and it is proved that every finite very thin Hv-group is proper. 相似文献
We study the shearing flow of granular materials between two horizontal flat plates where the top plate is moving with a constant speed. The constitutive relation used for the stress is based on the continuum model proposed by Rajagopal and Massoudi (DOE Report, DOE/PETC/TR-90/3, 1990). The material coefficients such as viscosity and normal stress coefficients are based on the model of Boyle and Massoudi (Int. J. Eng. Sci 28 (1990) 1261). The governing equations are non-dimensionalized and the resulting system of non-linear differential equations is solved numerically using finite difference technique. 相似文献
The compound N,N′,N′′‐tricyclohexylphosphorothioic triamide, C18H36N3PS or P(S)[NHC6H11]3, (I), crystallizes in the space group Pnma with the molecule lying across a mirror plane; one N atom lies on the mirror plane, whereas the bond‐angle sum at the other N atom has a deviation of some 8° from the ideal value of 360° for a planar configuration. The orientation of the atoms attached to this nonplanar N atom corresponds to an anti orientation of the corresponding lone electron pair (LEP) with respect to the P=S group. The P=S bond length of 1.9785 (6) Å is within the expected range for compounds with a P(S)[N]3 skeleton; however, it is in the region of the longest bond lengths found for analogous structures. This may be due to the involvement of the P=S group in N—H...S=P hydrogen bonds. In O,O′‐diethyl (2‐phenylhydrazin‐1‐yl)thiophosphonate, C10H17N2O2PS or P(S)[OC2H5]2[NHNHC6H5], (II), the bond‐angle sum at the N atom attached to the phenyl ring is 345.1°, whereas, for the N atom bonded to the P atom, a practically planar environment is observed, with a bond‐angle sum of 359.1°. A Cambridge Structural Database [CSD; Allen (2002). Acta Cryst. B 58 , 380–388] analysis shows a shift of the maximum population of P=S bond lengths in compounds with a P(S)[O]2[N] skeleton to the shorter bond lengths relative to compounds with a P(S)[N]3 skeleton. The influence of this difference on the collective tendencies of N...S distances in N—H...S hydrogen bonds for structures with P(S)[N]3 and P(S)[O]2[N] segments were studied through a CSD analysis. 相似文献
The competitive metal ion transport experiments of Co+2, Cd+2, Ag+, Pb+2, Ni+2, and Cu+2 were carried out by N-(2,6-dichlorobenzoyl)-N′,N″-bis(pyrrolidinyl)-phosphoric triamide as a carrier in organic membrane phase. 2,6-Cl2C6H3C(O)NHP(O)[NC4H8]2 has been synthesized and characterized by mass spectrometry IR spectroscopy and single crystal X-ray diffraction. The asymmetric unit of title phosphoric triamide contains one symmetrically independent molecule. The source phase contained equimolar concentrations of metal ions at pH 5 and the receiving phase being buffered at pH 3. The following solvents were examined as membrane: chloroform (CHCl3), nitrobenzene (NB), 1,2-dichloroethane (1,2-DCE), dichloromethane (DCM), dichloromethane/1,2-dichloroethane (DCM/1,2-DCE). The obtained results show that the selectivity and efficiency of transport for these heavy metal cations change with the nature of the ligand and also the organic solvents, which were used as liquid membrane in these experiments. A good selectivity was observed for Pb+2 cation by this ligand in all membrane systems. Moreover, the selectivity of metal cations in DCM is higher than other solvents. A non-linear relationship was found between the percent of transport of Pb+2 cation by this ligand and the compositions of DCM/1,2-DCE and binary solution by this ligand. The effect of several factors such as the nature of carboxylic acids (stearic, fumaric and maleic acid) as surfactant in the membrane phase and the time of transport on transport efficiency of Pb+2 cation were investigated. 相似文献
A nanocomposite of activated carbon and iron oxide was prepared and characterized by x-ray diffraction and scanning electron microscopy methods. The prepared magnetic nanocomposite can be separated easily from water by an external magnet. The prepared magnetic nanocomposite was used as adsorbent for removal of Bismarck Brown (B.B.) as a dye pollutant from water. The adsorption studies include both equilibrium and kinetic aspects, and the results were modeled with different equations. The obtained results indicate that the prepared magnetic nanocomposite of iron oxide and activated carbon is one of the best adsorbents for the removal of B.B. from aqueous solution. 相似文献