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排序方式: 共有263条查询结果,搜索用时 15 毫秒
51.
In this paper dry reforming of methane (DRM) was carried out over nanocrystalline MgAl2O4-supported Ni catalysts with various Ni loadings. Nanocrystalline MgAl2O4 spinel with high specific surface area was synthesized by a co-precipitation method with the addition of pluronic P123 triblock copolymer as surfactant, and employed as catalyst support. The prepared samples were characterized by X-ray diffraction (XRD), N2 adsorption, H2 chemisorption, temperature-programmed reduction (TPR), temperature-programmed oxidation (TPO), temperature- programmed desorption (TPD) and transmission and scanning electron microscopies (TEM, SEM) techniques. The obtained results showed that the catalyst support has a nanocrystalline structure (crystal size: about 5 nm) with a high specific surface area (175 m2 g-1) and a mesoporous structure. Increasing in nickel content decreased the specific surface area and nickel dispersion. The prepared catalysts showed high catalytic activity and stability during the reaction. SEM analysis revealed that whisker type carbon deposited over the spent catalysts and increasing in nickel loading increased the amount of deposited carbon. The nickel catalyst with 7 wt% of nickel showed the highest catalytic activity. 相似文献
52.
Farhangi MM Graham PJ Choudhury NR Dolatabadi A 《Langmuir : the ACS journal of surfaces and colloids》2012,28(2):1290-1303
Coalescence of a falling droplet with a stationary sessile droplet on a superhydrophobic surface is investigated by a combined experimental and numerical study. In the experiments, the droplet diameter, the impact velocity, and the distance between the impacting droplets were controlled. The evolution of surface shape during the coalescence of two droplets on the superhydrophobic surface is captured using high speed imaging and compared with numerical results. A two-phase volume of fluid (VOF) method is used to determine the dynamics of droplet coalescence, shape evaluation, and contact line movement. The spread length of two coalesced droplets along their original center is also predicted by the model and compared well with the experimental results. The effect of different parameters such as impact velocity, center to center distance, and droplet size on contact time and restitution coefficient are studied and compared to the experimental results. Finally, the wetting and the self-cleaning properties of superhydrophobic surfaces have been investigated. It has been found that impinging water drops with very small amount of kinetic impact energy were able to thoroughly clean these surfaces. 相似文献
53.
The flow of non-Newtonian fluids through two-dimensional porous media is analyzed at the pore scale using the smoothed particle
hydrodynamics (SPH) method. A fully explicit projection method is used to simulate incompressible flow. This study focuses
on a shear-thinning power-law model (n < 1), though the method is sufficiently general to include other stress-shear rate relationships. The capabilities of the
proposed method are demonstrated by analyzing a Poiseuille problem at low Reynolds numbers. Two test cases are also solved
to evaluate validity of Darcy’s law for power-law fluids and to investigate the effect of anisotropy at the pore scale. Results
show that the proposed algorithm can accurately simulate non-Newtonian fluid flows in porous media. 相似文献
54.
We have experimentally and analytically studied transport of a passive scalar in the wake of a thin flat plate located at
the centerline of a planar contraction with flat walls. The constant Launder parameter in the contraction, K = 6.25 ×10 − 6, was twice the value required for a turbulent boundary layer to relaminarize. In addition to the mixing analysis inside the
contraction, layer mixing is also investigated downstream, where the flow continues inside a constant cross-section channel.
In order to generate the passive scalar, the airflow above the plate was heated and the temperature stratification in the
wake was traced by measuring the temperature field using constant current anemometry. Using different plate lengths, we found
that the degree of mixing, obtained at a given position in the straight channel, is a function of the distance from the plate
trailing edge to the contraction outlet. For a plate which does not protrude into the straight channel, we demonstrate the
existence of an optimal trailing edge-contraction outlet distance that results in the lowest possible degree of mixing at
a given downstream position in the straight channel. This finding is also supported by a semi-empirical relationship based
on our developed self-similar solution for mixing layers in planar contractions. 相似文献
55.
Ilknur Babahan Ali Özmen Mehran Aksel Mehmet Dincer Bilgin Rukiye Gumusada Muhammet Emin Gunay Fatih Eyduran 《应用有机金属化学》2020,34(7):e5632
In this study, a novel bidentate ligand containing oxime, hydrazone, and indole moieties and its BF2+-bridged transition metal complexes [Ni(II), Cu(II), and Co(II)] were synthesized and their cytotoxic activities against prostate and breast cancer cells were investigated. The vic-dioxime ligand bearing indole–hydrazone side groups was synthesized by reacting antiglyoximehydrazine (GH2) with 3-methoxy indole. The ligand forms mononuclear complexes with a metal-to-ligand ratio of 1:2 with M = Co(II)(H2O)2, Ni(II), and Cu(II). These metal complexes were then reacted with BF3(C2H5)2O to obtain BF2+-bridged transition metal complexes. The Co(II) complex of the ligand is proposed to be octahedral with water molecules as axial ligands, whereas the Ni(II) and Cu(II) complexes are proposed to be square planar. Spectral studies showed that the ligand bonded to the metal ion in a neutral bidentate fashion through the azomethine nitrogen atom and the imine oxime group. Structural assignments are supported by a combination of 1H nuclear magnetic resonance (NMR), 13C NMR, Fourier-transform infrared, LC/MS, elemental analyses, and magnetic susceptibility testing. For determining the cytotoxic effects of the novel anticancer products, cancer cells were cultured. The antiproliferative effects were determined using the MCF-7 breast cancer and PC-3 prostate cancer cell lines. The antiproliferative effects of the products were analyzed and their apoptotic or necrotic effects were determined with the Hoechst/propidium iodide double staining method in both cancer cell lines. Paclitaxel was used as the positive control (1 μm ). The results indicated that the newly synthesized compounds are effective on both cell lines between concentrations of 5 and 40 μm and show their effects by apoptotic mechanisms. Besides, these products were found to be more effective on the MCF-7 cell line. The cytotoxic efficiency of the newly synthesized products was more than that of paclitaxel (depending on concentration), which is a chemotherapeutic agent used in cancer therapy. 相似文献
56.
A phosphovanadomolybdate hybridized with an anchored dicationic ionic liquid on Al‐MCM‐41 was prepared through the anion exchange and characterized by 1H and 13C NMR, FTIR, UV–Vis, XRD, XPS, TGA, TEM, FESEM, ICP‐OES and BET techniques. The obtained data demonstrated that the composite is a porous material with the high surface area and also having a large pore volume which are 405 m2 g?1 and 0.616 cm3 g?1 respectively. The prepared composite has shown an acceptable catalytic activity for converting benzene selectively to phenol with hydrogen peroxide as eco‐friendly oxidant. Under the optimized reaction conditions, the hybrid catalyst resulted in phenol yield of 14.8% with 100% selectivity and a TOF value of 20.0 h?1. The catalyst also revealed a desired recovery and reusability. The efficient performance of the composite is related to the textural and polyoxometalate properties. 相似文献
57.
Rezaei Shokoofe Rahpeima Soraya Esmaili Javad Javanbakht Vahid 《Russian Journal of Applied Chemistry》2021,94(4):533-548
Russian Journal of Applied Chemistry - Magnetic nanoparticles and clay minerals combine to form a class of advanced nanocomposites that would possess exceptional adsorption, magnetism, and... 相似文献
58.
59.
Omid Sadeghi Mehran Amiri Dr. Eric W. Reinheimer Prof. Dr. May Nyman 《Angewandte Chemie (International ed. in English)》2018,57(21):6247-6250
Metal oxo clusters and metal oxides assemble and precipitate from water in processes that depend on pH, temperature, and concentration. Other parameters that influence the structure, composition, and nuclearity of “molecular” and bulk metal oxides are poorly understood, and have thus not been exploited. Herein, we show that Bi3+ drives the formation of aqueous Fe3+ clusters, usurping the role of pH. We isolated and structurally characterized a Bi/Fe cluster, Fe3BiO2(CCl3COO)8(THF)(H2O)2, and demonstrated its conversion into an iron Keggin ion capped by six Bi3+ irons ( Bi6Fe13 ). The reaction pathway was documented by X‐ray scattering and mass spectrometry. Opposing the expected trend, increased cluster nuclearity required a pH decrease instead of a pH increase. We attribute this anomalous behavior of Bi/Fe(aq) solutions to Bi3+, which drives hydrolysis and condensation. Likewise, Bi3+ stabilizes metal oxo clusters and metal oxides in strongly acidic conditions, which is important in applications such as water oxidation for energy storage. 相似文献
60.