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101.
Nurcan Kurtoglu Mehmet Aslantaş Huseyin Zengin Ertan Şahin Mukerrem Kurtoglu 《Chemical Papers》2010,64(5):645-651
This study focuses on the preparation, single crystal X-ray diffraction, characterization, and optical properties of some
anthraquinone-based dyes. The anthraquinone-based antimicrobial dye N-{2-[(9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]-2-oxoethyl}-N,N-dimethylbutan-1-aminium chloride monohydrate (III) was obtained from 1-aminoanthraquinone (I) via 2-chloro-N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)acetamide (II) using known preparation and characterization methods. Single crystal X-ray diffraction analysis of III revealed a monoclinic system, space group P21/n, Z = 4. Photoluminescence properties of anthraquinone dyes I–III were also investigated. These dyes gave an intense emission (λmax = 341 nm) upon the irradiation by UV light and showed photoluminescence quantum yields of 73 %, 66 %, and 61 % with long
excited-state lifetimes of 6.87 ns, 6.14 ns, and 5.69 ns, respectively. These anthraquinone dyes are of interest as an organic
light emitting material for electroluminescent devices. 相似文献
102.
Mustafa Yıldız Hava Özay Hüseyin Ünver Nazan Ocak İskeleli D. Mehmet Zengin Tahsin Nuri Durlu 《Journal of chemical crystallography》2010,40(11):909-913
Abstract
Schiff base (E)-2-[(benzo[d]thiazol-2-ylimino)methyl]phenol (1) has been synthesized from the reaction of 2-hydroxy-benzaldehyde with 2-aminobenzothiazole. The 2-[(benzo[d]thiazol-2-ylamino)methyl]phenol (2) was prepared reduction of the Schiff base 1 with sodium borohydride. The compounds 1 and 2 have been characterized by elemental analysis, FT-IR, 1H-NMR, 13C-NMR and UV–visible spectroscopic techniques. The structure of the compound 2 has also been examined crystallographically. The compound 2 crystallizes in the monoclinic space group P2/c. The unit cell parameters were found as a = 10.017(1), b = 11.725(1), c = 10.341(1) ?, V = 1208.1(1) ?3, D x = 1.409 g cm−3 and Z = 4. The crystal structure was solved by direct methods and refined by the full-matrix least squares method and found as R 1 = 0.0308 and wR 2 = 0.0818 for 2032 for the observed reflections [I > 2σ(I)]. 相似文献103.
In this study, channel waveguides fabricated in photopolymer films by direct-writing using a low-power CW laser, are used as phase objects in a simple plane-wave diffraction setup, and the refractive index modulation profiles of the waveguides are characterized using the recorded diffraction patterns. Index profiles are modeled by piece-wisely combining two Gaussian functions representing the central and the tail regions. Measured diffraction patterns are matched with patterns generated using the model. This simple model makes it possible to design various channel waveguides embedded into polymer substrates. The proposed model is tested on three distinctive waveguide profiles written on the same Acrylamide/Polyvinyl Alcohol based photopolymer with different exposures. 相似文献
104.
In this work, we performed density functional calculations to examine the molecular adsorption states of thiophene on β-SiC(0 0 1)-2×1 surface. A number of possible adsorption geometries are considered into two groups as the polymeric thiophene chain and the individual molecules covalently bonded onto the surface. The results show that the polymeric chain on the surface is the less stable adsorption case and individual arch like adsorption case structure is more stable than others. In all adsorption cases, the adsorbed SiC surfaces are characterized as different semiconductors. 相似文献
105.
Mehmet Ozger 《Physica A》2011,390(6):981-989
Fluctuations in the significant wave height can be quantified by using scaling statistics. In this paper, the scaling properties of the significant wave height were explored by using a large data set of hourly series from 25 monitoring stations located off the west coast of the US. Detrended fluctuation analysis (DFA) was used to investigate the scaling properties of the series. DFA is a robust technique that can be used to detect long-range correlations in nonstationary time series. The significant wave height data was analyzed by using scales from hourly to monthly. It was found that a common scaling behavior can be observed for all stations. A breakpoint in the scaling region around 4-5 days was apparent. Spectral analysis confirms this result. This breakpoint divided the scaling region into two distinct parts. The first part was for finer scales (up to 4 days) which exhibited Brown noise characteristics, while the second one showed 1/f noise behavior at coarser scales (5 days to 1 month). The first order and the second order DFA (DFA1 and DFA2) were used to check the effect of seasonality. It was found that there were no differences between DFA1 and DFA2 results, indicating that there is no effect of trends in the wave height time series. The resulting scaling coefficients range from 0.696 to 0.890 indicating that the wave height exhibits long-term persistence. There were no coherent spatial variations in the scaling coefficients. 相似文献
106.
Erdoğan Şen Serkan Araci Mehmet Acikgoz 《Mathematical Methods in the Applied Sciences》2014,37(17):2619-2625
In this work, we study the asymptotic properties of a new Sturm–Liouville problem with retarded argument. Contrary to previous works, differential equation includes eigenparameter as a quadratic function. In the considered problem arise new difficulties. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
107.
In this paper, we model and solve profit maximization problem of a telecommunications Bandwidth Broker (BB) under uncertain market and network infrastructure conditions. The BB may lease network capacity from a set of Backbone Providers (BPs) or from other BBs in order to gain profit by leasing already purchased capacity to end-users. BB’s problem becomes harder to deal with when bandwidth requests of end-users, profit and cost margins are not known in advance. The novelty of the proposed work is the development of a mechanism via combining fuzzy and stochastic programming methodologies for solving complex BP selection and bandwidth demand allocation problem in communication networks, based on the fact that information needed for making these decisions is not available prior to leasing capacity. In addition, suggested model aims to maximize BB’s decision maker’s satisfaction ratio rather than just profit. As a solution strategy, the resulting fuzzy stochastic programming model is transformed into deterministic crisp equivalent form and then solved to optimality. Finally, the numerical experiments show that on the average, proposed approach provides 14.30% more profit and 69.50% more satisfaction ratio compared to deterministic approaches in which randomness and vagueness in the market and infrastructure are ignored. 相似文献
108.
Mustafa Gülsu Mehmet Sezer 《Numerical Methods for Partial Differential Equations》2011,27(6):1628-1638
A numerical method based on the Taylor polynomials is introduced in this article for the approximate solution of the pantograph equations with constant and variable coefficients. Some numerical examples, which consist of the initial conditions, are given to show the properties of the method. © 2010 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 27:1628–1638, 2011 相似文献
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