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31.
Hormoz Eslami Soleyman Hosseinzadeh Younes Saadat Faramarz Afshar-Taromi Mehdi Rimaz 《Colloid and polymer science》2012,290(14):1463-1469
In this work, the preparation of micron-sized polymer particles with nonspherical shapes via seeded dispersion polymerization of 2-ethylhexyl methacrylate (EHMA) with polystyrene (PS) seed particles in the presence of decane droplets and evaporation of decane after the polymerization under various polymerization conditions was discussed. The effect of monomer and decane content and polarity of the medium on the shape of the obtained particles was investigated. The experimental results showed that decreasing the amount of monomer and hydrocarbon volume of PEHMA/hydrocarbon domains, the particles decreased but they grew symmetrically, resulting in symmetric shapes. Furthermore, it was suggested that because of changing the solubility of the oligoradicals and hydrocarbon in the medium, the shape of the particles changed with changing the polarity of the medium. With decreasing the polarity of the medium, solubility of the oligoradicals in the medium increases and bigger polymer domains form on the surface of PS particles which can absorb higher amounts of decane. All of these can contribute to an increase in volume reduction after extraction of PEHMA/decane, resulting in various particle shapes. Further decreasing in polarity of the medium leads to an increase in the solubility of decane in the medium and decreasing the absorbed amount of decane by PS particles and PEHMA domains, resulting in lower volume reduction after evaporation of decane. 相似文献
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2‐hydroxyethylammonium formate ionic liquid grafted magnetic nanoparticle as a novel heterogeneous catalyst for the synthesis of substituted imidazoles 下载免费PDF全文
Catalytic one‐pot condensation of benzil, aldehyde and ammonium acetate have been successfully carried out using 2‐hydroxyethylammonium formate (HEAF) grafted on a magnetic nanoparticles as a new heterogeneous catalyst. The as‐prepared catalyst was characterized by FT‐IR, TEM, FESEM, VSM, TGA and XRD. This catalyst indicated significant advantages, such as excellent yields, shorter reaction time, reusability of the catalyst and easy workup process. 相似文献
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The MHD Falkner–Skan equation arises in the study of laminar boundary layers exhibiting similarity on the semi‐infinite domain. The proposed approach is equipped by the orthogonal Sinc functions that have perfect properties. This method solves the problem on the semi‐infinite domain without truncating it to a finite domain and transforming domain of the problem to a finite domain. In addition, the governing partial differential equations are transformed into a system of ordinary differential equations using similarity variables, and then they are solved numerically by the Sinc‐collocation method. It is shown that the Sinc‐collocation method converges to the solution at an exponential rate. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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The lattice‐Boltzmann method is being applied to a diversity of fluid flow and heat transfer problems nowadays. Because of its microscale nature, strict attention should be paid when introducing macroscopic inputs to the model. One of the challenging issues dealing with macroscale and microscale treatment is the implementation of boundary conditions. In this regard constant‐temperature boundaries are frequently used in energy transfer problems. Such boundaries are simply modeled in Navier–Stokes based solvers, but they are not so harnessed in lattice‐Boltzmann models. One of the problems is that the calculated tangential heat flux is not zero along such boundaries in most of the previous models. In the present paper, a model has been developed, which has the capability of controlling tangential heat flux along the constant‐temperature boundaries. It aims to set the heat flux nearly zero along the boundary in midplane grid schemes. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Abbas Ghasempour Ardakani Mehdi Hosseini Ali Reza Bahrampour Seyed Mohammad Mahdavi 《Optics Communications》2012,285(7):1900-1904
We propose that spectral intensity of superconductor based random lasers can be made tunable by changing temperature. The two fluid model and wavelength dependent dispersion formula have been employed to describe the optical response of the superconducting materials. Random laser characteristics have been calculated using the one dimensional FDTD method. Our simulation results reveal that the emission spectrum can be manipulated through the ambient temperature of the system. It is observed that transition from metal phase to pure superconducting phase leads to the enhancement of the laser emission. Furthermore, spatial distribution of the fields in one dimensional disordered media is very sensitive to the system temperature. 相似文献
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A theoretical investigation was performed to study cooperative effects in fluorine-centered halogen bond interactions. We investigated geometry, strength, and origin of the interactions in linear (FCN)2–7 and (FNC)2–7 clusters by means of MP2 and CCSD(T) methods. Our results strongly suggest that cooperative effects induced by fluorine-centered halogen bonds are significant in both linear FCN and FNC clusters. CCSD(T)/6-311++G** calculations reveal that for (FCN)2–7 clusters, the average halogen-bonding energy per monomer increases from ?0.76 kcal/mol in dimer to ?0.92 kcal/mol in heptamer. The results of electron density analysis suggest that the capacity of the linear FCN and FNC clusters to concentrate electrons at the F···N and F···C BCPs enhance considerably with cluster size. The results also indicate that the magnitude of cooperative effects is more important for FCN than for FNC clusters. According to energy decomposition analysis, attractive electrostatic and dispersion components make the major contribution to the F···N and F···C halogen bond interactions. An acceptable correlation is found between different energy terms and total interaction energies, revealing the main role of these interactions for stability of linear (FCN) n and (FNC) n clusters. 相似文献
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