Parametric Excitation of Electron-Acoustic Mode in a Plasma of Two-Temperature Electrons

Using hydrodynamical model of the two-electron-temperatere plasma, the analytical investigation of parametric instability of electron-acoustic wave has been made. It is found that the growth rate decreases with increasing concentration ratio of the hot to the total electrons n_h0/n₀. The growth rate is found to be more for      

Thermodynamics of binary mixtures of non-electrolytes containing a salt

Molar excess volume V ^E and enthalpy H ^E data have been measured at 25°C for pyridine A saturated with anhydrous cupric chloride (S) [A(S)]+ B [where B is aniline or o-toluidine (OT) or formamide (FD) or N, N-dimethylformamide (NND)] mixtures on the assumption that while the standard state of B is that of pure components B, the standard state of A(S) is that of A saturated with the salt S. The excess volume or enthalpy data for an equimolar mixture at a given temperature have been utilized to evaluate the interactional parameter X₁₂ of the Sanchez and Lacombe theory of fluid mixtures at that temperature, and the same has been combined with V ^E (x _A ) data for a good prediction not only of the coresponding H ^E (x _A ) data for the mixture but also the extent of unlike interactions between the A(S) and B components of these A(S)+B mixtures.     

Synthesis and characterization of zeolite Linde Type W and its metal oxide composite Ag-O-LTW used for the decontamination of chemical warfare agent simulant

Abstract

In this study, we have evaluated the performance of novel adsorbent zeolite Linde Type W and modified LTW with AgO metal oxide composite for the decontamination of chemical warfare agent simulant 2-chloroethylphenylsulphide (CEPS). Zeolites are nanoporous aluminosilicate minerals composed of silicon, aluminum and oxygen framework with cations and water molecules within the pores. The synthesized zeolite LTW and its composites Ag-O-LTW was characterized by XRD, FTIR, SEM-EDS and BET analytical techniques. The decontamination study of CWA simulant, CEPS was monitored by using GC-FID technique. The nanocrystalline zeolite LTW and Ag-O-LTW composites were found powerful adsorbents and showed great decontamination potential toward CWA simulant CEPS. The Ag-O-LTW showed better results (～98 % decontamination in 7?hours) than LTW zeolite.     

Pressure-induced structural phase transition and elastic properties of rare earth Pr chalcogenides and pnictides

Pressure-induced structural aspects and elastic properties of NaCl-type (B1) to CsCl-type (B2) structure in praseodymium chalcogenides and pnictides are presented. Ground-state properties are numerically computed by considering long-range Coulomb interactions, Hafemeister and Flygare type short-range overlap repulsion, and van der Waals interaction in the interionic potential. From the elastic constants, Poisson's ratio ν, the ratio R_G/B of G (shear modulus) over B (bulk modulus), anisotropy parameter, shear and Young's moduli, Lamé's constant, Kleinman parameter, elastic wave velocity and thermodynamical property such as Debye temperature are calculated. Poisson's ratio ν and the ratio R_G/B indicate that PrX and PrY are brittle in B1 phase and ductile in B2 phase. To our knowledge, this is the first quantitative theoretical prediction of the ductile (brittle) nature of praseodymium chalcogenides and pnictides and still awaits experimental confirmation.     

Distribution regimes of intense laser beam in a self-consistent plasma channel

In the present work, we investigate the distributed regimes of an intense laser beam in a self-consistent plasma channel. As the intensity of the laser beam increases, the relativistic mass effect as well as the ponderomotive expulsion of electrons modifies the dielectric function of the medium due to which the medium exhibits nonlinearity. Based on Wentzel–Kramers–Brillouin and paraxial ray theory, the steady-state solution of an intense, Gaussian electromagnetic beam is studied. A differential equation of the beamwidth parameter with the distance of propagation is derived, including the effects of relativistic self-focusing (SF) and ponderomotive self-channeling. The nature of propagation and radial dynamics of the beam in plasma depend on the power, width of the beam, and Ω _p, the ratio of plasma to wave frequency. For a given value of Ω _p (<1), the distribution regimes have been obtained in beampower–beamwidth plane, characterizing the regimes of propagation as steady divergence, oscillatory divergence, and SF. The related focusing parameters are optimized introducing plasma density ramp function, and spot size of the laser beam is analyzed for inhomogeneous plasma. This results in overcoming the diffraction and guiding the laser beam over long distance. Numerical computations are performed for typical parameters of relativistic laser–plasma interaction studies.     

Polyfluorophenylaminosilane–Titanium (IV) Chloride Adducts

Si(NHC₆H_5-nF_n)₄.xTiCl₄ [n = 2–5; x = 3,4] are obtained from the disproportionation reactions between (CF₃CH₂O)₃SiNHC₆H_5-nF_n (n = 2–5) and TiCl₄ in petroleum ether (40–60°C) at 0°–10°C. These complexes are characterized by elemental analyses and IR, ¹H, and ¹⁹F NMR spectroscopy. Unlike the reported⁵ complex Si(NHC₆H₄F-o)₄.3TiCl₄, these are non-ionic in nature. All complexes give double adducts with CH₃NO₂ and CH₃CN within 24 h.     

Effect of temperature on AC conductivity of poly(butyl methacrylate)/cerium dioxide nanocomposites and applicability of different conductivity modeling studies

In this research, the effect of cerium dioxide (CeO₂) nanoparticles on electrical properties of poly(butyl methacrylate) (PBMA) has been investigated. Polymer nanocomposites reinforced with variable contents of CeO₂ nanoparticles (3, 5, 7 and 10 wt%) were fabricated by an in situ polymerization method. The formation of nanocomposites was analyzed by FTIR, XRD, SEM and TEM analysis. Also, the AC and DC conductivities of CeO₂ nanoparticles-reinforced PBMA were systematically studied with respect to different loadings of CeO₂ fillers. The FTIR, XRD and morphological studies revealed that the nanoparticles were well inserted and uniformly dispersed into the macromolecular chain of PBMA. The AC conductivity of PBMA/CeO₂ composite increases not only with the loading of nanoparticles but also with the temperature of the system. The activation energy determined from AC electrical conductivity was found to decrease with the frequency and temperature. DC conductivity of the nanocomposites was increased with the insertion of nanoparticles into PBMA. The DC conductivity of all the composites was greater than pure PBMA. The applicability of different theoretical models such as Scarisbrick, Bueche and McCullough equations was compared with the experimentally determined DC conductivity of PBMA/CeO₂ nanocomposites. These models fail to explain the conductivity of polymer composite in the entire loading of fillers. Hence, a new theoretical model is proposed in this study and it shows good agreement with the experimentally observed conductivity values.

     

(4aR,8aS,9aR,10aS)‐8a,9a‐Difluoro‐1,4,4a,5,8,8a,9,9a,10,10a‐decahydroanthracene‐4a,10a‐diol hemihydrate

The title compound, C₁₄H₁₈F₂O₂·0.5H₂O, a hemihydrate of a C_s‐symmetric unsaturated difluorodiol, crystallizes in the centrosymmetric space group P2/m (Z = 4). The asymmetric unit contains two crystallographically independent difluorodiol half‐molecules, occupying the mirror planes at (x, 0, z) and (x, , z), and half a molecule of water, lying on the twofold axis at (0, y, 0). Four difluorodiol molecules self‐assemble around each solvent water molecule via O—H...O hydrogen bonds in a near tetrahedral symmetry to generate a cylindrical column‐like architecture.