全文获取类型
收费全文 | 8642篇 |
免费 | 217篇 |
国内免费 | 68篇 |
专业分类
化学 | 4935篇 |
晶体学 | 76篇 |
力学 | 333篇 |
综合类 | 16篇 |
数学 | 1352篇 |
物理学 | 2215篇 |
出版年
2022年 | 62篇 |
2021年 | 82篇 |
2020年 | 114篇 |
2019年 | 105篇 |
2018年 | 97篇 |
2017年 | 93篇 |
2016年 | 201篇 |
2015年 | 193篇 |
2014年 | 188篇 |
2013年 | 384篇 |
2012年 | 392篇 |
2011年 | 447篇 |
2010年 | 333篇 |
2009年 | 252篇 |
2008年 | 391篇 |
2007年 | 369篇 |
2006年 | 373篇 |
2005年 | 332篇 |
2004年 | 288篇 |
2003年 | 233篇 |
2002年 | 274篇 |
2001年 | 226篇 |
2000年 | 178篇 |
1999年 | 123篇 |
1998年 | 124篇 |
1997年 | 104篇 |
1996年 | 125篇 |
1995年 | 120篇 |
1994年 | 120篇 |
1993年 | 123篇 |
1992年 | 134篇 |
1991年 | 120篇 |
1990年 | 112篇 |
1989年 | 77篇 |
1988年 | 99篇 |
1987年 | 74篇 |
1986年 | 89篇 |
1985年 | 95篇 |
1984年 | 90篇 |
1983年 | 98篇 |
1982年 | 85篇 |
1981年 | 84篇 |
1980年 | 79篇 |
1979年 | 80篇 |
1978年 | 78篇 |
1977年 | 84篇 |
1976年 | 83篇 |
1975年 | 64篇 |
1974年 | 69篇 |
1973年 | 65篇 |
排序方式: 共有8927条查询结果,搜索用时 0 毫秒
191.
A. von Bohlen M. Brücher B. Holland R. Wagner R. Hergenröder 《Spectrochimica Acta Part B: Atomic Spectroscopy》2010
A systematic characterization of mono-disperse nanoparticles with nominal diameters of 25 nm, 46 nm, 73 nm, 100 nm, 115 nm, and 250 nm was performed using X-ray standing waves (XSW). The samples were prepared on Si-wafer pieces and analyzed at DELTA synchrotron facility at beamline BL8 under grazing incidence geometry of the primary radiation. Additionally, SEM-EDX inspections of single particles as well as population-density checks were conducted. Particles with smaller diameters were able be characterized by XSW while the larger ones were not completely covered by the interference field produced by the provided 15 keV monochromatic radiation of BL8. The results of the measurements were compared with those of numerical simulations. The extension of the interference field perpendicular to the Si-wafer reflector was determined to be 83 nm ± 4 nm. 相似文献
192.
193.
Ying Liu Chong‐an Di Dr. Chunyan Du Yunqi Liu Prof. Kun Lu Wenfeng Qiu Dr. Gui Yu Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(7):2231-2239
A series of fused thiophenes composed of fused α‐oligothiophene units as building blocks, end‐capped with either styrene or 1‐pentyl‐4‐vinylbenzene groups, has been synthesized through Stille coupling reactions. The compounds have been fully characterized by means of 1H NMR spectrometry, high‐resolution mass spectrometry, and elemental analysis. The molecules present a trans–trans configuration between their double bonds, which has been verified and confirmed by Fourier‐transform infrared spectroscopy and single‐crystal X‐ray diffraction analysis. The X‐ray crystal structures showed π–π overlap and sulfur–sulfur interactions between the adjacent molecules. The decomposition temperatures were all found to be above 300 °C, indicating that compounds of this series possess excellent thermal stability. The fact that no phase transition occurs at low temperature indicates that they should be well‐suited for application in devices. Moreover, they possess low HOMO energy levels, based on cyclic voltammetry measurements, and suitable energy gaps, as determined from their thin‐film UV/Vis spectra. Thin‐film X‐ray diffraction analysis and atomic force microscopy revealed high crystallinity on supporting substrates. In addition, as the substrate temperature has a significant influence on the morphology and the degree of crystallinity, the device performance could be optimized by varying the substrate temperature. These materials were found to exhibit optimal field‐effect performance, with a mobility of 0.17 cm2 V?1 s?1 and an on/off ratio of 105, at a substrate temperature of 70 °C. 相似文献
194.
A. Dobrak B. Verrecht H. Van den Dungen A. Buekenhoudt I.F.J. Vankelecom B. Van der Bruggen 《Journal of membrane science》2010
This paper describes solvent flux and rejection behavior of different hydrophilic TiO2 membranes and a hydrophobic ZrO2 membrane. Solvents and solutes used range from polar to non-polar. Additionally, the temperature effect on permeability and rejection of solutes through these membranes was examined. 相似文献
195.
Tobias G. Brevé Mike Filius Sven Weerdenburg Stefan J. van der Griend Tim P. Groeneveld Dr. Antonia G. Denkova Dr. Rienk Eelkema 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(10):e202103523
Stimuli-responsive soft materials enable controlled release of loaded drug molecules and biomolecules. Controlled release of potent chemotherapeutic or immunotherapeutic agents is crucial to reduce unwanted side effects. In an effort to develop controlled release strategies that can be triggered by using Cerenkov luminescence, we have developed polymer hydrogels that can release bovine serum albumin and immunoglobulin G by using light (254 nm–375 nm) as a trigger. We describe the synthesis and photochemical characterization of two light sensitive phenacyl bis-azide crosslinkers that are used to prepare transparent self-supporting hydrogel patches. One crosslinker was designed to optimize the overlap with the Cerenkov luminescence emission window, bearing an π-extended phenacyl core, resulting in a high quantum yield (14 %) of photocleavage when irradiated with 375 nm light. We used the extended phenacyl crosslinker for the preparation of protein-loaded dextran hydrogel patches, which showed efficient and selective dosed release of bovine serum albumin or immunoglobulin G after irradiation with 375 nm light. Cerenkov-triggered release is as yet inconclusive due to unexpected side-reactivity. Based on the high quantum yield, efficient release and large overlap with the Cerenkov window, we envision application of these photosensitive soft materials in radiation targeted drug release. 相似文献
196.
Veronika Šolínová Petr Tůma Maria Butnariu Václav Kašička Dušan Koval 《Electrophoresis》2022,43(20):1953-1962
We present a method for finely adjustable electroosmotic flow (EOF) velocity in cathodic direction for the optimization of separations in capillary electrophoresis. To this end, we use surface modification of the separation fused silica capillary by the covalently attached copolymer of acrylamide (AM) and 2-acrylamido-2-methyl-1-propanesulfonate (AMPS), that is, poly(AM-co-AMPS) or PAMAMPS. Coatings were formed by the in-capillary polymerization of a mixture of the neutral AM and anionic AMPS monomers premixed in various ratios in order to control the charge density of the copolymer. EOF mobility varies in the 0 to ∼40 × 10−9 m2 V−1 s−1 interval for PAMAMPS coatings ranging from 0 to 60 mol.% of charged AMPS monomer. For EOF in PAMAMPS-treated capillaries, we observed (i) a negligible dependence on pH in the 2–10 interval, (ii) a minor variance among background electrolytes (BGEs) in function of their components and (iii) its standard decrease with increasing ionic strength of the BGE. Interest in variable cathodic EOF was demonstrated by the amelioration of separation of two kinds of isomeric anionic analytes, that is, monosaccharides phosphates and helquat enantiomers, in counter-EOF mode. 相似文献
197.
J. A. De Schutter F. De Croo G. Van der Weken W. Van den Bossche P. De Moerloose 《Chromatographia》1985,20(3):185-192
Summary A rapid and specific reversed-phase high-performance liquid chromatographic method (RPHPLC) is described for the determination of mebeverine hydrochloride in tablets. Elution was performed on an octyl silane column with a methanol-water mixture (75-25), containing 0.05% hexylamine as silanol-blocking agent, adjusted to pH 5.0 with phosphoric acid. The method gave accurate, precise and reproducible results. The mean recovery of the drug from six synthetic tablet mixtures was 100.0% with a relative standard deviation (RSD) of 0.94%. In order to test the specificity of the method, the interference of the degradation compounds of mebeverine hydrochloride and of the intermediates from the synthesis was investigated. None of them did interfere. By means of mass spectrometry and UV-spectrophotometry, the degradation compounds of mebeverine were identified as veratric acid and as 4-|ethyl-[2-(4-methoxyphenyl)-1-methylethyl]amino| 1-butanol. The stability study proved that mebeverine hydrochloride is very stable in tablets; the tablets still contain more than 95% of the declared drug potency after storage for more than one year at 50°C.Colofac; Duspatal; Duspatalin 相似文献
198.
199.
B J Koopman G Jansen B G Wolthers J R Beukhof J G Go G K van der Hem 《Journal of chromatography. A》1985,337(2):259-266
The determination of sulphate in plasma is described, making use of reversed-phase high-performance liquid chromatography with ultraviolet detection. The concentration of inorganic sulphate determined in plasma of twenty healthy volunteers was 0.307 +/- 0.092 mmol/l (mean +/- S.D.). In one stable chronic dialysis patient the kinetics of plasma sulphate removal were monitored during and after one single pass dialysis. In addition, plasma sulphate concentrations were determined in three stable chronic dialysis patients during a consecutive scheme of two single pass dialyses, five Redy dialyses and three single pass dialyses. As expected, plasma sulphate accumulates in plasma to a high steady-state level under Redy dialysis, whereas during single pass dialysis sulphate is efficiently removed. 相似文献
200.
Separation of iron-52 from chromium cyclotron targets on the 2% cross-linked anion-exchange resin AG1-X2 in hydrochloric acid 总被引:1,自引:0,他引:1
Iron-52 can be separated from solutions of chromium cyclotron targets by eluting chromium, copper and radioactive impurities with 9.0M hydrochloric acid from a column containing 1.0 g of AG1-X2 anion-exchange resin. Iron-52 is retained and can then be eluted with 6.0M hydrochloric acid containing 0.05M hydrogen iodide or 0.05M sodium iodide. The separations are sharp and quantitative. Less than 2 microg of chromium will remain with the iron-52, from 2.0 g originally present. 相似文献