α-Amidoaldehydes as Substrates in Rhodium-Catalyzed Intermolecular Alkyne Hydroacylation: The Synthesis of α-Amidoketones

We show that readily available α-amidoaldehydes are effective substrates for intermolecular Rh-catalyzed alkyne hydroacylation reactions. The catalyst [Rh(dppe)(C₆H₅F)][BAr^F₄] provides good reactivity, and allows a broad range of aldehydes and alkynes to be used as substrates, delivering α-amidoketone products. High yields and high levels of regioselectivity are achieved. The use of α-amidoaldehydes as substrates establishes that 1,4-dicarbonyl motifs can be used as controlling groups in Rh-catalyzed hydroacylation reactions.     

An Easy Access to Oxime Ethers by Pd‐Catalyzed C—O Cross‐Coupling of Activated Aryl Bromides with Ketoximes and Chalcone Oximes

An efficient Pd‐catalyzed method for C—O cross‐coupling of ketoximes and chalcone oximes with activated aryl bromides and bromo‐chalcones has been developed. All oxime ethers were obtained in good to excellent yields by [(π‐allyl)PdCl]₂/tBuXPhos ( L7 ) catalyst system. TrixiePhos ( L11 ) was also found to be effective for the oxime coupling. This method offers an easy and smooth coupling of chalcone oximes with activated aryl bromides and bromo‐chalcones, which has not been previously explored.     

Variational theory for the ground state and collective excitations of an elongated dipolar condensate

We develop a variational theory for a dipolar condensate in an elongated(cigar shaped)confinement potential. Our formulation provides an effective one-dimensional extended meanfield theory for the ground state and its collective excitations. We apply our theory to investigate the properties of rotons in the system comparing the variational treatment to a full numerical solution. We consider the effect of quantum fluctuations on the scattering length at which the roton excitation softens to zero energy.     

The effect of variable viscosity on MHD viscoelastic fluid flow and heat transfer over a stretching sheet

An analysis has been carried out to study the momentum and heat transfer characteristics in an incompressible electrically conducting non-Newtonian boundary layer flow of a viscoelastic fluid over a stretching sheet. The partial differential equations governing the flow and heat transfer characteristics are converted into highly non-linear coupled ordinary differential equations by similarity transformations. The effect of variable fluid viscosity, Magnetic parameter, Prandtl number, variable thermal conductivity, heat source/sink parameter and thermal radiation parameter are analyzed for velocity, temperature fields, and wall temperature gradient. The resultant coupled highly non-linear ordinary differential equations are solved numerically by employing a shooting technique with fourth order Runge–Kutta integration scheme. The fluid viscosity and thermal conductivity, respectively, assumed to vary as an inverse and linear function of temperature. The analysis reveals that the wall temperature profile decreases significantly due to increase in magnetic field parameter. Further, it is noticed that the skin friction of the sheet decreases due to increase in the Magnetic parameter of the flow characteristics.     

Lag synchronization and scaling of chaotic attractor in coupled system

We report a design of delay coupling for lag synchronization in two unidirectionally coupled chaotic oscillators. A delay term is introduced in the definition of the coupling to target any desired lag between the driver and the response. The stability of the lag synchronization is ensured by using the Hurwitz matrix stability. We are able to scale up or down the size of a driver attractor at a response system in presence of a lag. This allows compensating the attenuation of the amplitude of a signal during transmission through a delay line. The delay coupling is illustrated with numerical examples of 3D systems, the Hindmarsh-Rose neuron model, the Ro?ssler system, a Sprott system, and a 4D system. We implemented the coupling in electronic circuit to realize any desired lag synchronization in chaotic oscillators and scaling of attractors.     

Observation of bulk like magnetic ordering below the blocking temperature in nanosized zinc ferrite

We investigated the magnetic behavior of nanosized zinc ferrite with the help of vibrating sample magnetometry and in-field Mössbauer spectroscopy. The nanoparticles of zinc ferrite with crystallite size ranging from 10 to 62 nm were synthesized by a nitrate method. The structure and phase were determined with the help of X-ray diffraction. Attributes of cation inversion were found with the calculated values of lattice parameter. The saturation magnetization decreases with the increase in crystallite size at room temperature, while these values are almost the same at 10 K for all the samples except the one with crystallite size of 10 nm. The thermal magnetization measurement shows a decrease in blocking temperature with increase in particle size for these samples. The synthesized samples exhibit the presence of antiferromagnetic ordering below the blocking temperature as investigated by in-field Mössbauer spectroscopy.     

Induction of p-type conduction in sputtered deposited Al-N codoped ZnO thin films

Al and N codoped ZnO thin films were grown on n-Si (100) substrate by sputtering technique. Hall effect measurements of as-grown films exhibited n-type conduction, however 500 °C Ar annealed codoped films showed p-type conductivity with a hole concentration of 9.9 × 10¹⁶ cm^− 3, resistivity of 15.95 Ω-cm and hole mobility of 3.95 cm²/Vs, respectively. Codoped ZnO thin films were found to be highly c-axis oriented with good crystal quality. A neutral acceptor-bound exciton and donor-acceptor-pair emissions that appeared at room temperature photoluminescence measurement verify p-type conduction in Al and N codoped ZnO film. The current-voltage characteristics of p-n heterojunction evidently showed a diode like rectifying behaviour.     

Stress in polycrystalline GaN films prepared by r.f sputtering

Undoped, Be-doped and Si-doped polycrystalline GaN films were deposited by R.F. sputtering onto fused silica substrates. The films were deposited at various deposition temperatures ranging from 300 K to 623 K and characterized by optical measurements while the microstructural information was obtained from SEM and XRD studies. The compositional study for the GaN film was carried out using SIMS. Residual stresses in these films were evaluated from the band tail of the absorption spectra as well as from direct measurements of hardness by commercially available depth sensing indentometer. It was observed that undoped GaN films had the highest hardness followed by that for Be-doped and Si-doped films. The values of hardness obtained form the above optical measurement tallied quite well with those obtained from direct indentation measurement.