Fluid forces on a very low Reynolds number airfoil and their prediction

This paper presents the measurements of mean and fluctuating forces on an NACA0012 airfoil over a large range of angle (α) of attack (0-90°) and low to small chord Reynolds numbers (Re_c), 5.3 × 10³-5.1 × 10⁴, which is of both fundamental and practical importance. The forces, measured using a load cell, display good agreement with the estimate from the LDA-measured cross-flow distributions of velocities in the wake based on the momentum conservation. The dependence of the forces on both α and Re_c is determined and discussed in detail. It has been found that the stall of an airfoil, characterized by a drop in the lift force and a jump in the drag force, occurs at Re_c ? 1.05 × 10⁴ but is absent at Re_c = 5.3 × 10³. A theoretical analysis is developed to predict and explain the observed dependence of the mean lift and drag on α.     

Natural convection flow of water near its density maximum in a rectangular enclosure having isothermal walls with heat generation

We consider unsteady laminar natural convection flow of water subject to density inversion in a rectangular cavity formed by isothermal vertical walls with internal heat generation. The top and bottom horizontal walls are considered to be adiabatic, whereas the temperature of the left vertical wall is assumed to be greater than that of the right vertical wall. The equations are non-dimensionalized and are solved numerically by an upwind finite difference method together with a successive over-relaxation (SOR) technique. The effects of both heat generation and variations in the aspect ratio on the streamlines, isotherms and the rate of heat transfer from the walls of the enclosure are presented. Investigations are performed for water taking Prandtl number to be Pr=11.58 and the Rayleigh number to be Ra=10⁵.     

A simple in situ visual and tristimulus colorimetric method for the determination of trace arsenic in environmental water after its collection on a mercury(II)-impregnated paper.

A simple in situ visual and tristimulus colorimetric method for the determination of trace arsenic in environmental water after collecting arsenic on a test paper impregnated with mercury(II) bromide and rosaniline chloride by its reduction aeration has been developed. The color development on the test paper is based on the formations of AsH(HgBr)2 (yellow) and/or As(HgBr)3 (brownish yellow) by a reaction between mercury(II) bromide and arsine (AsH3), which is produced through the reduction of As(III) (arsenite ion) and/or As(V) (arsenate ion) in a sample solution. To a sample solution, potassium iodide, tin(II) chloride, zinc sand and 4 ml of 6 M hydrochloric acid solution were added successively. The liberated arsine was collected on the test paper. The yellow or brownish-yellow color intensity on the test paper was measured by a tristimulus colorimeter and also by a visual method. The established method is applicable to the determination of arsenic in environmental water sample such as river, brackish, and seawater types.     

Nonlinear phenomena at mercury Hg electrode/room-temperature ionic liquid (RTIL) interfaces: polarographic streaming maxima and current oscillation

The polarographic streaming maxima and cyclic voltammetric anodic current oscillation (CVACO) at a hanging mercury drop electrode (HMDE) in room-temperature ionic liquid (RTIL) have been studied for the first time using cyclic voltammetric, potential step chronoamperometric and pulse voltammetric techniques. The reversible redox reaction of the 2,1,3-benzothiadiazole (BTD)/BTD*- (an anion radical of BTD) couple with a formal potential (E0') of -1.36 V versus Ag/AgCl/NaCl(saturated) in 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4) RTIL was typically employed for this purpose. A maximum was observed at the rising part of the normal pulse voltammogram for the reduction of BTD to BTD*- as well as of the reversed pulse voltammogram for the reoxidation of BTD*- to BTD at the HMDE. The conditions of the initiation and control of the CVACO at the HMDE in EMIBF4 were extensively investigated. Generally, the CVACO was enhanced by increasing the concentration of BTD at a given potential scan rate (upsilon) and was attenuated by increasing upsilon. An electrocapillary curve was measured using a dropping mercury electrode in EMIBF4, and the potential of zero charge was determined to be -0.23 V. On the basis of the modern theory of the polarographic streaming maxima of the first kind, the observed streaming maxima and CVACO phenomena are successfully explained to originate from the macroscopic instability at the electrode/solution interface wherein the oscillating mode creates the CVACO.     

Relative partial cross sections for single, double, and triple photoionization of C60 and C70

Partial cross sections for the photoion formation from C(60) and C(70) were determined from the yields of singly, doubly, and triply charged ions which were measured by mass spectrometry combined with tunable synchrotron radiation at hnu = 25-120 eV. The dependence of the detection efficiencies on the mass-to-charge ratio was evaluated by using the formula proposed by Twerenbold et al. Corrections of the detection efficiency were found to be critical for obtaining accurate partial cross sections for photoionization of fullerenes. Revisions were made of the partial cross-section curves for single and double photoionization of C(60) and C(70). The curve for triple photoionization of C(70) was newly proposed. The ratios between the cross sections for double and single photoionization increase with hnu and reach saturated values of 0.78 at 85 eV for C(60) and approximately 1.3 at 100 eV for C(70). In contrast, the ratios at 120 eV between the cross sections for triple and single photoionization of C(60) and C(70) amount to 0.14 and approximately 0.38, respectively. The formation mechanism of multiply charged fullerene ions was discussed in terms of valence-electron excitation to antibonding unoccupied orbitals and/or spherical standing waves inside the cavity of a fullerene. This excitation could be followed by Spectator Auger processes and transmission of the excess electronic energy among numerous vibrational degrees of freedom.     

Highly phosphorescent perfect green emitting iridium(iii) complex for application in OLEDs

A novel iridium complex, [bis-(2-phenylpyridine)(2-carboxy-4-dimethylaminopyridine)iridium(iii)] (N984), was synthesized and characterized using spectroscopic and electrochemical methods; a solution processable OLED device incorporating the N984 complex displays electroluminescence spectra with a narrow bandwidth of 70 nm at half of its intensity, with colour coordinates of x = 0.322; y = 0.529 that are very close to those suggested by the PAL standard for a green emitter.