The photoelectron spectrum of ethylene sulphide

The He I photoelectron spectrum of ethylene sulphide is reported. There are six ionization potentials below 21 eV, the first, corresponding to ionization from a predominantly sulphur 3p orbital, occurring at 9.05 eV. The orbital types and symmetries have been assigned on the basis of semi-empirical calculations. The results indicate that in this highly strained cyclic compound sulphur d-orbital participation may be important.     

Determination of sampling constants for selenium in biological reference materials by neutron activation

Summary A cyclic instrumental neutron activation analysis method has been used to calculate sampling constants and to evaluate homogeneity for Se in five biological reference and certified reference materials, namely NRC lobster hepatopancreas (RM TORT-1), IAEA horse kidney (RM-H8), and NIST bovine liver (SRM-1577a), oyster tissue (SRM-1566) and mixed diet (RM-8431). The between-weight-range heterogeneity has been observed to be no greater than the within-weight-range heterogeneity. The subsampling standard deviation (S _s) has been found to be less than the measurement standard deviation (S _m) for H-8 (>5 mg sample) and TORT-1 (>50 mg). For 1577a, S _s is almost equal to S _m; while S _s is 2–3 times higher than S _m for the other two materials. The sampling constants varied between 0.04 and 3.0 g for four materials while the mixed diet had a value of 31 g.     

Generalized conjugate directions for unconstrained function minimization

The theory of unconstrained optimization has led to the development of a large class of iterative methods that reduce to conjugate direction methods when they are applied to quadratic functions. The purpose of this paper is to give a generalization of conjugate directions to nonquadratic functions.     

An I = 1 enhancement at a mass of 1550 MeV in the (Λπ) and (Σπ)-systems

Evidence is presented for an I = 1 enhancement observed in the reactions K^?p→Λ(Σ)K⁰₁K^±π^? at $\text{4.2}\text{GeV}\text{c}$ inciden momentum. The mass and width of the proposed new Y¹ are, respectively, (1553 ± 7) MeV) and (80 ± 30) MeV. A decay branching ratio $\text{Σπ}\text{(Σπ + Λπ)}\text{= (35 ± 12)\%}$ is also obtained.     

The ν2 + ν4 band of 12CF4

From a high-resolution diode laser spectrum of cooled ¹²CF₄, line assignments in ν₂ + ν₄ at 1066.4 cm^?1 have been made for tetrahedral subspecies to J = 20, and in many cases to higher J. Spectroscopic constants have been obtained from a least-squares fit of the Hamiltonian, and the relative intensities of the assigned lines have been calculated. The ground- and excited-state rotational constants, Coriolis constant, and splitting of the F₁ and F₂ vibrational substates have the values a.The CF bond length in the ground vibrational state is thus $\text{r}{}_0\text{= 1.31752 ± 0.00007}\text{A}\text{?}$. The analysis of a combination band such as this provides a method of obtaining ground-state spectroscopic constants of spherical-top molecules directly from the infrared spectrum, without the necessity of measuring weak “forbidden” transitions. The assignments allow accurate predictions of the frequencies emitted by the CO₂-pumped CF₄ laser.     

Electron scattering by atoms at intermediate energies II. Theoretical and experimental data for light atoms

Experimental data for the scattering of electrons by selected light atoms at intermediate energies have been collected and compared with the predictions of the theoretical models discussed in part I. The data discussed include elastic scattering and discrete excitation but ionization is not covered. The target atoms include H, He; the alkali metals; the alkaline earths; C, N, O and the rare gases from Ne to Xe, together with certain positive ions isoelectronic with these neutral atoms.     

The photoelectron spectra of the oxalyl halides (COX)2, [X = F,Cl and Br]

We have examined the HeI photoelectron spectra of the oxalyl halides (COX)₂, (X = F, Cl, and Br). We assume the presence of the trans-isomer onWe have used semi-empirical calculations (SCF MO), and Koopmans' Theorem, as aids in assigning the spectral bands.     

Backward production of a spin parity 1+ϱπ enhancement at 1.04 GeV

A spin-parity 1⁺?π enhancement is observed for the 3π mass spectrum in the reaction K^?p → Σ^?π⁺π⁺π^? where events with a small (K^? → Σ^?) momentum transfer are selected. The mass (1040 MeV) and width (230 MeV) of this enhancement are reminiscent of the A₁ → ?π bump which has mainly been observed in the diffractive-like processes. The cross section for this enhancement at 4.15 GeV/c incident K^? momentum is (3.6 ± 0.5) μb.     

X-ray photoelectron spectroscopy of copper compounds

The X-ray photoelectron spectra of some forty-six copper compounds and complexes have been measured. The chemical shifts obtained from accurate determinations of the binding energies have been qualitatively explained on the basis of the Pauling electronegativity concept using the group electronegatives of Huheey for the polyatomic counter anions. The chemical shifts of the copper atoms as well as the atoms in the ligands were found to be dependent not only on the oxidation state but also on the kind and number of ligand atoms.

Intense satellite lines were found in the 2p and 2s bands of the cupric compounds; the number and splitting of the satellites were found to be sensitive to the chemical environment. A correlation was found between the satellite splitting and the binding energies and this is explained by a 3d→4s, 4p ‘shake-up’ mechanism.     

ON AVOIDANCE ACTIVITIES IN FISHERY ENFORCEMENT MODELS

Compliance and enforcement in fisheries are important issues from an economic point of view since management measures are useless without a certain level of enforcement. These conclusions come from the well‐established theoretical literature on compliance and enforcement problems within fisheries and a common result is that, it is efficient to set fines as high as possible and monitoring as low as possible, when fines are costless and offenders are risk neutral. However, this result is sensitive to the assumption that fishermen cannot engage in avoidance activities, e.g., activities to reduce the likelihood of being detected when noncomplying. The paper presents a model of fisheries that allows the fishermen to engage in avoidance activities. The conclusions from the model are that, under certain circumstances, fines are costly transfers to society since they not only have a direct positive effect on the level of deterrence, but also an indirect negative effect in the form of increased avoidance activities to reduce the probability of detection. The paper contributes to the literature on avoidance activities by introducing the externality from the illegal behavior as an endogenous effect on other offenders. For an externality, that has an exogenous effect on other actors, Malik shows that fines are only costly transfers for conditional deterrence (when one actor is deterred while another actor is not). For fisheries, we show that fines are also costly transfers under no deterrence (when no agents are deterred).