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61.
Milton E. McDonnell Alexander M. Jamieson 《Journal of Polymer Science.Polymer Physics》1980,18(8):1781-1790
The porous-sphere model of Debye–Brinkman–Bueche is applied to predict the limiting frictional coefficient f0 and intrinsic viscosity [η] of polystyrene fractions in tetrahydrofuran and random protein coils in 6M guanidine hydrochloride. Following the formulation of Wiegel and Mijnlieff, the molecular permeability is modeled to increase exponentially as the square of the distance from the center of the molecule. A method is developed to obtain this permeability from the translational diffusion coefficient. The experimental values of f0 and [η] are in satisfactory agreement with the calculated values. Also, this analysis predicts values of the Mandelkern–Flory–Scheraga parameter for flexible coils which are significantly smaller than the minimum values permitted by the Kirkwood–Riseman theory. This is in accord with the experimental evidence. 相似文献
62.
63.
We derive a master equation for a mirror interacting with the vacuum field via radiation pressure. The dynamical Casimir effect leads to decoherence of a superposition state in a time scale that depends on the degree of "macroscopicity" of the state components, and which may be much shorter than the relaxation time scale. Coherent states are selected by the interaction as pointer states. 相似文献
64.
Fluoropolymer blends have been widely used as binders for exterior coatings because of their excellent resistance to ultra-violet (UV) radiation as well as to many corrosive chemical agents.It is known that the fluorinated component usually has a lower glass transition temperature and easily crystallizes in the final structure depending upon the blend composition and sample annealing condition.We investigated the effect of blend composition and annealing process (slow and fast cooling) on the surface mor... 相似文献
65.
3-Chloro-4-(dichloromethyl)-5-hydroxy-5H-furan-2-one (Mutagen X, MX) was synthesized in six steps from commercially-available and inexpensive starting materials (27% overall yield). This synthesis enables the preparation of MX analogs and does not require the use of chlorine gas, as do previously reported methods. 相似文献
66.
Norman H. Nemeroff Mark E. McDonnell Jeffrey M. Axten Leonard J. Buckley 《合成通讯》2013,43(22):3271-3275
The syntheses of new ferrocene substituted pyrroles has been carried out by the reaction of TosMIC with an α, β-unsaturated ferrocene derivative. 相似文献
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68.
Gubala V Lynam CC Nooney R Hearty S McDonnell B Heydon K O'Kennedy R MacCraith BD Williams DE 《The Analyst》2011,136(12):2533-2541
In this article, we report on poly(amidoamine) dendrimers (PAMAM) as coupling agents for recombinant single-chain (ScFv) antibodies to nanoparticle (NP) labels, for use in immunoassay. We present a simple theory for the kinetics of particle capture onto a surface by means of an antibody-antigen reaction, in which the important parameter is the fraction of the particle surface that is active for reaction. We describe how increasing the generation number of the linking dendrimers significantly increased the fraction of the NP surface that is active for antigen binding and consequently also increased the assay kinetic rates. Use of dendrimers for conjugation of the NP to the antibody resulted in a significantly higher surface coverage of active antibody, in comparison with mono-valent linker chemistry. As a direct consequence, the increase in effective avidity significantly out-weighed any effect of a decreased diffusion coefficient due to the NP, when compared to that of a molecular dye-labelled antibody. The signal to noise ratio of the G4.5 dendrimer-sensitised nanoparticles out-performed the dye-labelled antibody by approximately four-fold. Particle aggregation experiments with the multi-valent antigen CRP demonstrated reaction-limited aggregation whose rate increased significantly with increasing generation number of the dendrimer linker. 相似文献
69.
70.
A. W. Hall D. Lacey J. S. Hill K. M. Blackwood M. Jones D. G. McDonnell 《Liquid crystals》2013,40(4):437-447
Abstract The recently published Baylis-Hillman methodology has been used to prepare a number of side chain liquid crystalline poly(allylalcohols) incorporating a ferroelectric mesogenic side chain. These poly(allylalcohols) exhibited wide range S?C phases and, in the case of two of these materials, low glass transition temperatures. The transition temperatures and phase behaviour of the SCLC poly(allylalcohols) were compared to acrylate and methacrylate SCLC oligomers containing a similar mesogenic side chain. The response times for two poly(allylalcohols) exhibiting low glass transition temperatures were also measured over a wide temperature range. Although the poly(allylalcohols) had comparable response times to the analogous acrylate and methacrylate SCLCP, they showed the greater temperature dependence of the response time. However, at 39°C one of the SCLC poly(allylalcohols) showed a response time of 65 ms. 相似文献