Literatur

Ohne Zusammenfassung     

Alignment locking to suspended Fabry-Perot cavity

In this paper we report on the alignment locking of an in vacuum 77 m long suspended mirror Fabry-Perot cavity. Lock was achieved by mode-matching a 500 mW Nd:YAG NPRO onto a pre-mode cleaner, the output of which was then mode-matched to the suspended cavity. The longitudinal locking was achieved by feeding back to the laser frequency actuator to follow the cavity resonance. Subsequent implementation of a hybrid auto-alignment system enhanced the stability of the circulating power inside the cavity. Preliminary results are presented.     

Effect of surface orientation and sulfur coverage on the oxidation of carbon on Ni surfaces

The reaction between adsorbed oxygen and segregated carbon on a cylindrical nickel single-crystal has been examined with Auger electron spectroscopy (AES) and temperature programmed desorption (TPD), for a range of surface orientation, oxygen exposure, and sulfur coverage. It was found that for small oxygen exposures, surface carbon and surface oxygen react during TPD to form a CO desorption peak, labeled β₁. The β₁ CO peak temperature and peak shape vary with orientation. At higher oxygen coverages, the CO desorption peak split into low-temperature and high-temperature peaks. The behavior of the β₁ CO desorption peak for large oxygen exposures is consistent with a model of the carbon-oxygen recombination reaction in which the morphologies of the initial carbon and oxygen phases change during oxygen exposure as a result of repulsive lateral interactions. High oxygen exposures result in the formation of large regions of contact between the two phases; this is believed to produce the low-temperature β₁ CO desorption peak. Small segregated-sulfur coverages, and low oxygen exposures, caused the β₁ CO peak to shift to lower temperatures for all orientations. Sulfur is believed to cause more frequent contact between carbon and oxygen for small oxygen exposures because it compresses the adsorbed oxygen and segregated carbon into the sulfur-free areas of the surface. Large coverages of segregated sulfur inhibited carbon segregation on some, and oxygen adsorption on most, orientations. The absence of reactant species explains the disappearance of the β₁ CO peak during TPD from orientations which had a high sulfur coverage.     

Videofluoroscopic and Laryngoscopic Evaluation of the Upper Airway and Larynx of Professional Bassoon Players

The bassoon is a demanding double-reed woodwind instrument requiring exquisite control of airflow and air pressure to the reed to produce desired tonal characteristics. Little information is available from direct visualization of the vocal tract and larynx of the bassoonist while playing. Of particular interest is the mechanism(s) of vibrato. This study was undertaken to understand more fully the mechanics of the upper airway in bassoonists during music production. Four adult bassoon players served as subjects. Three players were studied with both sound-synchronized videofluoroscopy and fiber-optic nasal endoscopy. The other subject was studied only by fiber-optic endoscopy. All subjects were evaluated while playing various scales and standard passages common in music pedagogy. The results from this study revealed several findings on the mechanics of upper airway activity during playing: (1) firm velopharyngeal closure was a prerequisite for maximal containment of air pressure and regulation of airflow in the oropharyngeal regions; (2) changes in the pitch and intensity were associated with differential expansion of the pharynx; (3) tongue activity was notable because of its shaping the size and shape of the airway, its role in regulating airflow to the reed, and its contributions to conditioning airflow in vibrato; and (4) slight vocal fold displacements from subglottal airflow and epiglottic movements from tongue base activity contributed to airway changes during vibrato. These seemed to further condition subglottal pressure trains derived primarily from expiration.     

An attempted application of the extended hückel molecular orbital approach to reactions involving charged species

The semi-empirical extended Hückel molecular orbital (EHMO) and non-empirical self consistent field molecular orbital (SCF-MO) methods have been used to study protonation reactions of acids, amides and esters. The work has been extended to the charged intermediates and subsequent products in their hydrolysis reactions.

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Zusammenfassung Ein semiempirisches, erweitertes Hückel-Verfahren sowie ab initio SCF-MO-Rechnungen wurden zur Untersuchung der Protonierung von Säuren, Amiden und Estern, deren ladungstragender Ab-kömmlinge und ihrer Folgeprodukte herangezogen.

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Résumé La méthode de Hückel étendue semi-empirique (EHMO) et la méthode du champ selfconsistant non empirique (SCF MO) ont été utilisées pour l'étude des réactions de protonation des acides, des amides et des esters. Ce travail a été étendu aux intermédiaires chargés et aux produits résultants lors de leur «hydrolyse».

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Contribution from the Department of Chemistry, University of Toronto, Toronto 5, Ontario, Canada.     

Compulsive checking behavior of quinpirole-sensitized rats as an animal model of Obsessive-Compulsive Disorder(OCD): form and control

Background

A previous report showed that the open field behavior of rats sensitized to the dopamine agonist quinpirole satisfies 5 performance criteria for compulsive checking behavior. In an effort to extend the parallel between the drug-induced phenomenon and human obsessive-compulsive disorder (OCD), the present study investigated whether the checking behavior of quinpirole rats is subject to interruption, which is an attribute characteristic of OCD compulsions. For this purpose, the rat's home-cage was placed into the open field at the beginning or the middle of a 2-hr test.

Results

Introduction of the home-cage reduced checking behavior, as rats stayed inside the cage. After 40 min, checking resurfaced, as quinpirole rats exited the home-cage often. An unfamiliar cage had no such effects on quinpirole rats or saline controls.

Conclusions

Checking behavior induced by quinpirole is not irrepressible but can be suspended. Results strengthen the quinpirole preparation as an animal model of OCD compulsive checking.     

Laser frequency noise immunity in multiplexed displacement sensing

Digitally enhanced interferometry (DI) can be used to distinguish between interferometric signals and simultaneously monitor in-line object displacements with subnanometer sensitivity. In contrast to conventional interferometry-where these signals interfere with each other and degrade performance-we experimentally show that by using DI, each of these signals can be isolated and measured at the same time. We present what we believe to be the first demonstration of DI's signal multiplexing capabilities, showing simultaneous length sensing of three sections of an optical fiber. The cross talk between length measurements was less than 2.6×10(-3) with a displacement noise floor of 200 pm/√Hz, which corresponds to a strain sensitivity of less than 80 picostrain(p?) in each sensor. We also enhance our system's displacement sensitivity at low frequencies by combining information from multiple lengths to suppress errors due to laser frequency noise.