Investigation of the Montmorillonite clay-catalyzed [1,3] shift reaction of 3-methyl-2-butenyl phenyl ether

The [1,3] shift reaction of 3-methyl-2-butenyl phenyl ether was catalyzed more effectively by Montmorillonite K10 clay than Montmorillonite KSF clay, and proceeded with greatest ortho-selectivity in carbon tetrachloride at room temperature.     

Arm cavity resonant sideband control for laser interferometric gravitational wave detectors

We present a new optical control scheme for a laser interferometric gravitational wave detector that has a high degree of tolerance to interferometer spatial distortions and noise on the input light. The scheme involves resonating the rf sidebands in an interferometer arm cavity.     

Finite element analysis of flow,heat transfer,and free interfaces in an electron-beam vaporization system for metals

A numerical analysis is made of the liquid flow and energy transport in a system to evaporate metals. The energy from an electron-beam heats an axisymmetric metal disk supported by a water-cooled platform. Metal evaporates from the surface of a hot pool of liquid which is surrounded by a shell of its own solid. Flow in the pool is strongly driven by temperature-induced buoyancy and capillary forces, and is located in the transition region between laminar and turbulent flow. The evaporation rate is strongly influenced by the locations of the free boundaries. A modified finite element method is used to calculate the steady state flow and temperature fields coupled with the interface locations. The mesh is structured with spines that stretch and pivot as the interfaces move. The discretized equations are arranged in an ‘arrow’ matrix and are solved using the Newton–Raphson method. The electron-beam power and platform contact resistance are varied for cases involving the evaporation of aluminum. The results reveal the interaction of liquid flow, heat transfer and free interfaces. © 1998 John Wiley & Sons, Ltd.     

Time-dependent liquid metal flows with free convection and a deformable free surface

The finite element method is employed to investigate time-dependent liquid metal flows with free convection, free surfaces and Marangoni effects. The liquid circulates in a two-dimensional shallow trough with differentially heated vertical walls. The spatial formulation incorporates mixed Lagrangian approximations to the velocity, pressure, temperature and free surface position. The time integration is performed with the backward Euler and trapezoid rule methods with step size control. The Galerkin method is used to reduce the problem to a set of non-linear equations which are solved with the Newton–Raphson method. Calculations are performed for conditions relevant to the electron beam vaporization of refractory metals. The Prandtl number is 0·015 and Grashof number are in the transition range between laminar and turbulent flow. The results reveal the effects of flow intensity, surface tension gradients, mesh refinement and time integration strategy.