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901.
The temperature dependence of the NMR chemical shift of129Xe dissolved in liquid alkanes is examined in the context of the reaction field model. An essential feature of the theory is the inclusion of the temperature dependence of the density of thesolvent. The theory of free volume for liquids is incorporated into the reaction field model to account for this temperature dependence. Comparison of the theory with previously reported measurements indicates the sensitivity of the129Xe chemical shift to the free volume of liquids. Incorporation of free volume improves the agreement between measurement and theory for branched alkane solvents, and resolves the origin of the 62 ppm intercept in the plot of reaction field as a function of129Xe chemical shift for the n-alkanes. 相似文献
902.
903.
904.
A generalized Gibbs-ensemble methodology with a fluctuating particle is used to determine the coexistence vapor-liquid densities for a square-well fluid. It is shown that the presence of the fluctuating particle in sub-states of the Markov chain of states supresses considerably density fluctuations which makes it possible to carry out simulations efficiently even for temperatures very close to the critical temperature. 相似文献
905.
A Monte-Carlo model is described which has been developed for calculation of multiply scattered LIDAR returns. Results are shown for the common problem selected by the MUSCLE (MUltiple SCattering LIDAR Experiments) group for intercomparison, which represents a typical ground-based cloud-sensing scenario. This is contrasted with returns from the same cloud sensed by a space-based LIDAR, where multiple-scattering effects are much greater. The magnitude of multiple-scattering effects is seen to be largely determined by the optical depth across the receiver field of view at the cloud. 相似文献
906.
The problem with unknown boundaries for a first-order semilinear hyperbolic system is studied in the case where the curve of definition of the initial conditions degenerates to a point. An existence and uniqueness theorem for a classical solution of the problem is proved for small t. 相似文献
907.
Diane L. Levesque Eng-Chi Wang Dau-Chang Wei Cherng-Chyi Tzeng Raymond P. Panzica Fardos N. M. Naguib Mahmoud H. El Kouni 《Journal of heterocyclic chemistry》1993,30(5):1399-1404
A new series of potent uridine phosphorylase inhibitors have been prepared from barbituric acid. Among them, 1-[(2-hydroxyethoxy)methyl]-5-)(m--benzyloxy)benzylbarbituric acid ( 37 , BBBA) is the most promising having a Ki value of 1.1 ± 0.2 nM with uridine phosphorylase from human liver. The new inhibitors are easily synthesized and are better inhibitors of human uridine phosphorylase than their uracil counterparts. 相似文献
908.
After carefull analysis in a turbulent zero-pressure gradient flow, various simple algebraic turbulence models were applied to the almost separated flow on the upperside of an airfoil at incidence. The Johnson-King and Horton non-equilibrium (or rate equation) models give clearly improved results. 相似文献
909.
This Review discusses the synthesis and characterization by our Group of new antibiotics belonging to the class of penicillins, cephalosporins and rifamycins with ferrocenyl and 1, 1′-ferrocenilene residues in the molecule. As reactants for 6-aminopenicillanic acid (6-APA) and 7-aminocephalosporanic acid (7-ACA) the following were used: 1, 1-bis(chlorocarbonyl)ferrocene, ferrocenyl sulfochloride, 1, 1′-ferrocenylenedisulfochloride and thioglycolic acids S-modified with ferrocene. In the synthesis of rifamycins, the hydrazides of the thioglycolic acids, S-modified with ferrocene, were employed as nucleophilic agents. The synthesized intermediates were characterized by elemental analysis, TLC, IR, UV and 1H NMR spectra. The characterization of new antibiotics was made by TLC, IR and UV spectral analysis. Biological activity was tested on Gram-negative and Gram-positive bacteria. Good activity is reported towards Gram-positive bacteria in the case of derivatives containing residues of thioglycolic acid S-modified with ferrocene, the antibacterial activity being similar to that of amoxicillin, carbenicillin and cephalothin. All compounds are inactive towards Gram-negative bacteria. 相似文献
910.
Chandhok M. Grizzle J.W. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1998,26(2):181-189
A semianalytical model for capacitively coupled radio frequency (RF) sheaths of asymmetric (unequal electrode area) systems has been developed. It can be applied in the high-frequency (ω > ω pi) regime at different pressures. An analytical approximation to the pressure-dependent ion density profile is used. The time-varying electric field and potential within the sheath are obtained by solving Poisson's equation. The current balance and zero net DC current conditions are applied to solve for the RF sheath parameters and DC bias voltage. The DC voltage ratio between the powered and grounded electrode sheaths increases as the pressure decreases, which results in a larger DC bias voltage at lower pressures 相似文献