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143.
P. A. Boyle J. M. Flynn A. Jüttner C. Kelly C. Maynard H. Pedroso de Lima C. T. Sachrajda J. M. Zanotti 《The European Physical Journal C - Particles and Fields》2010,69(1-2):159-167
Using partially twisted boundary conditions we compute the K→π semi-leptonic form factors in the range of momentum transfers $0\lesssim q^{2}\leq q^{2}_{\max}=(m_{K}-m_{\pi})^{2}$ in lattice QCD with N f =2+1 dynamical flavours. In this way we are able to determine $f_{+}^{K\pi}(0)$ without any interpolation in the momentum transfer, thus eliminating one source of systematic error. This study confirms our earlier phenomenological ansatz for the strange quark mass dependence of the scalar form factor. We identify and estimate potentially significant NNLO effects in the chiral expansion that guides the extrapolation of the data to the physical point. Our main result is $f_{+}^{K\pi}(0)=0.9599(34)(^{+31}_{-47})(14)$ , where the first error is statistical, the second error is due to the uncertainties in the chiral extrapolation of the lattice data and the last error is an estimate of potential discretisation effects. 相似文献
144.
Protein-polymer conjugates are important in diverse fields including drug delivery, biotechnology, and nanotechnology. This feature article highlights recent advances in the synthesis and application of protein-polymer conjugates by controlled radical polymerization techniques. Special emphasis on new applications of the materials, particularly in biomedicine, is provided. 相似文献
145.
Branson A. Maynard Kelly S. Lynn Richard E. Sykora Anne E. V. Gorden 《Journal of Radioanalytical and Nuclear Chemistry》2013,296(1):453-457
Simple salts of the tetracyanoplatinate (TCP) anions with the general formula M[Pt(CN)4] x ·H2O have been described for over 200 years. A major structural feature of these compounds are pseudo one dimensional Pt···Pt interactions between the square planar tetracyanoplatinate anions. These interactions form quasi one-dimensional chains in the solid state and are believed to be the source of their unique spectroscopic and emission properties. The lanthanides offer the ability to tune the Pt···Pt spacing of these pseudo one dimensional chains, predictably by taking advantage of the lanthanide contraction. Here, we describe the emission and structural characteristics of new actinide tetracyanometallates. 相似文献
146.
For a linear code over GF(q) we consider two kinds of “subcodes” called residuals and punctures. When does the collection of residuals or punctures determine the isomorphism class of the code? We call such a code residually or puncture reconstructible. We investigate these notions of reconstruction and show that, for instance, selfdual binary codes are puncture and residually reconstructible. A result akin to the edge reconstruction of graphs with sufficiently many edges shows that a code whose dimension is small in relation to its length is puncture reconstructible. © 1998 John Wiley & Sons, Inc. J Combin Designs 6: 285–291, 1998 相似文献
147.
Protein-polymer conjugates exhibit superior properties to unmodified proteins, generating a high demand for these materials in the fields of medicine, biotechnology, and nanotechnology. Multimeric conjugates are predicted to surpass the activity of monomeric conjugates. Herein, we report a straightforward method to synthesize multimeric polymer-conjugates. Four armed poly(N-isopropylacrylamide) (pNIPAAm) was synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of a tetra-functionalized trithiocarbonate chain transfer agent (CTA). The polymer molecular weight, architecture and polydispersity index (PDI) were verified by gel permeation chromatography (GPC), dynamic light scattering gel permeation chromatography (DLS-GPC), and matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrometry. This approach afforded well-defined polymers (PDI's < 1.06) and the ability to target various molecular weights. Maleimide functional groups were introduced at the chain ends by heating the polymers in the presence of a furan-protected azo-initiator. This allowed for site-specific conjugation of V131C T4 lysozyme to the polymers to generate multimeric protein-polymer conjugates. MALDI-TOF mass spectrometry, electrospray ionization gas-phase electrophoretic-mobility macromolecule analysis (ESI-GEMMA), gel electrophoresis, and liquid chromatography tandem mass spectrometry (LC-MS/MS) of the trypsin digests demonstrated that multimeric protein-polymer conjugates had formed. This simple strategy provides ready access to star protein-polymer conjugates for application in the fields of drug discovery, drug delivery, and nanotechnology. 相似文献
148.
Verdoes M Florea BI Menendez-Benito V Maynard CJ Witte MD van der Linden WA van den Nieuwendijk AM Hofmann T Berkers CR van Leeuwen FW Groothuis TA Leeuwenburgh MA Ovaa H Neefjes JJ Filippov DV van der Marel GA Dantuma NP Overkleeft HS 《Chemistry & biology》2006,13(11):1217-1226
The proteasome is an essential evolutionary conserved protease involved in many regulatory systems. Here, we describe the synthesis and characterization of the activity-based, fluorescent, and cell-permeable inhibitor Bodipy TMR-Ahx(3)L(3)VS (MV151), which specifically targets all active subunits of the proteasome and immunoproteasome in living cells, allowing for rapid and sensitive in-gel detection. The inhibition profile of a panel of commonly used proteasome inhibitors could be readily determined by MV151 labeling. Administration of MV151 to mice allowed for in vivo labeling of proteasomes, which correlated with inhibition of proteasomal degradation in the affected tissues. This probe can be used for many applications ranging from clinical profiling of proteasome activity, to biochemical analysis of subunit specificity of inhibitors, and to cell biological analysis of the proteasome function and dynamics in living cells. 相似文献
149.
Heterocyclic studies—XXIV: Mass spectra of some pteridin-4(3H)-ones and 3-methoxypteridin-4(3H)-ones
Mass spectra of pteridin-4(3H)-one and all its mono-, di- and tri-C-methyl derivatives are recorded. Spectra of 3-methoxypteridin-4(3H)-one and four of its mono- and dimethyl derivatives are also recorded. Pteridin-4(3H)-one fragments mainly by loss of CO and HCN in either order. Methyl substitution in the pyrazine ring leads to that ring fragmenting in preference to the oxygen bearing pyrimidine ring. Elucidation of fragmentation pathways was facilitated by changes in peak positions with changing methyl substitution patterns. 3-Methoxypteridin-4(3H)-ones fragment mainly through initial loss of CH2O, but the ions so produced break down differently from isomeric molecular ions of pteridin-4(3H)-ones. Several fragmentation pathways are discussed. 相似文献