全文获取类型
收费全文 | 146篇 |
免费 | 10篇 |
国内免费 | 9篇 |
专业分类
化学 | 52篇 |
力学 | 8篇 |
综合类 | 3篇 |
数学 | 45篇 |
物理学 | 57篇 |
出版年
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 7篇 |
2013年 | 34篇 |
2012年 | 4篇 |
2011年 | 4篇 |
2010年 | 2篇 |
2008年 | 2篇 |
2007年 | 2篇 |
2006年 | 2篇 |
2005年 | 1篇 |
2004年 | 3篇 |
2003年 | 2篇 |
2002年 | 6篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 11篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1972年 | 1篇 |
1971年 | 2篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1958年 | 1篇 |
1955年 | 1篇 |
1948年 | 1篇 |
排序方式: 共有165条查询结果,搜索用时 0 毫秒
11.
The main focus of this work is to model macroscopically the effects of partial saturation upon the permeability of dual scale fibrous media made of fiber bundles when a Newtonian viscous fluid impregnates it. A new phenomenological model is proposed to explain the discrepancies between experimental pressure results and analytical predictions based on Darcy's law. This model incorporates the essential features of relative permeability but without the necessity of measuring saturation of the liquid for its prediction. The model is very relevant for the small scale industrial systems where a liquid is forced to flow through a fibrous porous medium. It requires four parameters. Two of them are the two permeability values based on the two length scales. One length scale is of the order of magnitude of the individual fiber radius and corresponds to the permeability of the completely staurated medium, the other is of the order of magnitude of the distance between the fiber bundles and corresponds to the permeability of the partially saturated medium. The other two parameters are the lengths of the two partially saturated regions of the flow domain. The two lengths of the partially saturated region and the permeability of the fully saturated flow domain can be directly measured from the experiments. The excellent agreement between the model and the experimental results of inlet pressure profile with respect to time suggests that this model may be used to describe the variation of the permeability behind a moving front in such porous media for correct pressure prediction. It may also be used to characterize the fibrous medium by determining the two different permeabilities and the relative importance of the unsaturated portion of the flow domain for a given architecture. 相似文献
12.
保护渣元素的定量分析一般采用传统的湿法化学分析 ,化学分析虽然准确度好 ,但难以做到快速且劳动量大。利用 X-射线荧光光谱法分析保护渣中各元素含量是一种快速、准确的分析方法 ,在国外已得到广泛应用。本文从现场分析的实际出发 ,选择融样条件、最佳仪器参数 ,用基准物质合成标准样品 ,绘制标准工作曲线 ,曲线线性良好 ,用化学分析法对荧光分析值进行验证 ,结果符合化学允许差。1 试验部分1 .1 仪器设备、试剂及工作条件MXF2 1 0 0 - X-射线荧光光谱仪TR- AUTO- BEAD- 1 0 0 0 S/W熔融炉混合熔剂 :4g四硼酸钠 +4g四硼酸锂 +0 .… 相似文献
13.
14.
Maria Luiza LAPA DE Souza 《K-Theory》2002,25(3):233-249
We construct two cohomological invariants associated to pairs of Lagrangian sub-bundles of a symplectic bundle on a compact manifold upon which a compact Lie group is acting. The first invariant, which we call the classical equivariant Maslov H-invariant, provides an obstruction to Lagrangian transversality and lives in the Borel cohomology. The second invariant, which we call the equivariant Maslov U-invariant, generalises the author's results in K-Theory 13 (1998), 347–361 to the equivariant context and provides a necessary and sufficient condition for equivariant Lagrangian transversality, up to homotopic stability, and lives in the U-theory (intermediate between the real complex K-theories). As an application, we show that two Lagrangian sub-bundles of a symplectic bundle on a homogeneous space are always stably transverse. 相似文献
15.
BARB FLORIN DAN; KONING WILLEM DE 《IMA Journal of Mathematical Control and Information》1994,11(1):63-73
In this paper we consider the fixed finite-order digital linear-quadraticcontrol of Pritchard-Salamon infinite-dimensional systems withunbounded input and output operators under gaussian disturbances.A set of necessary conditions is given in terms of the solvabilityof a discrete-time Hyland-Bernstein system of equations (twomodified Riccati equations and two modified Lyapunov equationscoupled by an projection operator). 相似文献
16.
JOSE PITARCH-RUIZ JOSE SANCHEZ-MARIN ALFREDO SANCHEZ DE MERAS DANIEL MAYNAU 《Molecular physics》2013,111(3):483-494
The vertical electronic spectrum of formaldehyde has been studied by means of (SC)2-MR-SDCI and CCLR methods. Two basis sets of atomic natural orbitals (ANOs) complemented with a one-centre series of Rydberg orbitals were used. The first was taken from the CASPT2 study by Merchán, M., and Roos, B. O., 1995, Theoret. Chim. Acta, 92, 221, and may be described as C,O[4s3pld]/H[2slp] with a lslpld Rydberg series centred in the charge centroid of the 2B2 state of the cation. The second was a larger basis set that may be described as C,O[6s5p3d2f]/H[4s3p2d] + 3s3p3d in the same centre. The (SC)2 dressing may be applied efficiently to an MR-SDCI method and comparison with the dressed CAS-SDCI is satisfactory, in spite of the remarkable reduction in the CI space dimension. The consistency of the (SC)2-MR-SDCI results was tested also against the CCLR and CASPT2 results using the same basis sets and against the CCLR results using Dunning's aug- and daug-cc-pVQZ basis sets. The 3A1(π → π *) state is correctly placed as the second excited triplet while the highly multi-configurational nature of the 1A1(π → π *) state is confirmed as well as its greatly mixed valence-Rydberg nature. This state is predicted as lying under the 10 eV level, on top of the (ny → 3d) Rydberg states that are predicted in the 8.9–9.5eV region. The 5 1B2(ny → 4s) Rydberg state and the 1B2(σy → π*) also are predicted in this region. The triplet states also were calculated with the (SC)2-MR-SDCI method. The vertical ordering of the 2 1A1(ny → 3py) and 2 1B2(ny → 3pz) states is discussed, as well as that of the 1B1(σ → π*) and the Rydberg 1B1(ny → 3dxy) states. This work shows the highly reliable values that may be reached applying the dressing method along with a large basis set. Such a procedure is made possible using an MR-SDCI selection of spaces instead of the CAS-SDCI that was used up to now in most (SC)2 dressing applications. 相似文献
17.
The composition-independent virial coefficients of a d-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture (Santos, A., Yuste, S. B., and López de Haro, M., 1999, Molec. Phys., 96, 1) are examined. Good agreement between theoretical estimates and available exact or numerical results is found for d = 2, 3, 4 and 5, except for mixtures whose components are very disparate in size. A slight modification that remedies this deficiency is introduced and the resummation of the associated virial series is carried out, leading to a new proposal for the equation of state. The case of binary hard sphere mixtures (d = 3) is analysed in some detail. 相似文献
18.
19.
Multiconfigurational perturbation theory (CASPT2) and difference dedicated configuration interaction (DDCI) are applied to study the ferrimagnetic coupling in an oxamido-bridged Mn(II)Cu(II) molecular species. CASPT2 reproduces the experimental coupling very well. From the partition of the CASPT2 energy, the most important contributions to the coupling are established. Spin populations are calculated with DDCI. The successive improvement of the N-electron wave function allows us to analyse the contributions to the spin delocalization. 相似文献
20.
BARB FLORIN DAN; DE KONING WILLEM L.; IONESCU VLAD 《IMA Journal of Mathematical Control and Information》1995,12(3):253-298
This paper represents a Popov-theory-based assessment of thecurrent status of the digital control of infinitedimensionalsystems with certain unboundedness in control and/or observation,summarizing some results and indicating which, in the authors'opinion, would be the promising directions for future research. 相似文献