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161.
Hutzler NR Parsons MF Gurevich YV Hess PW Petrik E Spaun B Vutha AC DeMille D Gabrielse G Doyle JM 《Physical chemistry chemical physics : PCCP》2011,13(42):18976-18985
Cryogenically cooled buffer gas beam sources of the molecule thorium monoxide (ThO) are optimized and characterized. Both helium and neon buffer gas sources are shown to produce ThO beams with high flux, low divergence, low forward velocity, and cold internal temperature for a variety of stagnation densities and nozzle diameters. The beam operates with a buffer gas stagnation density of ~10(15)-10(16) cm(-3) (Reynolds number ~1-100), resulting in expansion cooling of the internal temperature of the ThO to as low as 2 K. For the neon (helium) based source, this represents cooling by a factor of about 10 (2) from the initial nozzle temperature of about 20 K (4 K). These sources deliver ~10(11) ThO molecules in a single quantum state within a 1-3 ms long pulse at 10 Hz repetition rate. Under conditions optimized for a future precision spectroscopy application [A. C. Vutha et al., J. Phys. B: At., Mol. Opt. Phys., 2010, 43, 074007], the neon-based beam has the following characteristics: forward velocity of 170 m s(-1), internal temperature of 3.4 K, and brightness of 3 × 10(11) ground state molecules per steradian per pulse. Compared to typical supersonic sources, the relatively low stagnation density of this source and the fact that the cooling mechanism relies only on collisions with an inert buffer gas make it widely applicable to many atomic and molecular species, including those which are chemically reactive, such as ThO. 相似文献
162.
Maxwell R Ata S Wanless EJ Moreno-Atanasio R 《Journal of colloid and interface science》2012,370(1):1-10
Polymer coatings on nano-sized remediation agents and subsurface heterogeneity will affect their transport, likely in a pH-dependent manner. The effect of pH on the aggregation of polymer-coated nanoscale zerovalent iron (nZVI) and its deposition onto sand and clay (kaolinite) surfaces was studied. nZVI coatings included a high molecular weight (90 kg/mol) strong polyanion, poly(methacrylic acid)-b-(methy methacrylate)-b-(styrenesulfonate) (PMAA-PMMA-PSS) and a low molecular weight (2.5 kg/mol) weak polyanion, polyaspartate. Aggregation and deposition increased with decreasing pH for both polyelectrolytes. The extent was greater for the low MW polyaspartate coated nZVI. Enhanced deposition at lower pH was indicated because the elutability of polyaspartate-modified hematite (which did not aggregate) also decreased at lower pH. The greater deposition onto clay minerals compared to similar sized silica fines is attributed to charge heterogeneity on clay mineral surfaces, which is sensitive to pH. Heteroaggregation between kaolinite particles and nZVI over the pH range 6-8 confirmed this assertion. Excess unadsorbed polyelectrolyte in solution (100mg/L) enhanced the transport of modified nZVI by minimizing aggregation and deposition onto sand and clay. These results indicate that site physical and chemical heterogeneity must be considered when designing an nZVI emplacement strategy. 相似文献
163.
164.
Blakemore JD Schley ND Kushner-Lenhoff MN Winter AM D'Souza F Crabtree RH Brudvig GW 《Inorganic chemistry》2012,51(14):7749-7763
Electrodeposition of iridium oxide layers from soluble precursors provides a route to active thin-layer electrocatalysts for use on water-oxidizing anodes. Certain organometallic half-sandwich aqua complexes of iridium form stable and highly active oxide films upon electrochemical oxidation in aqueous solution. The catalyst films appear as blue layers on the anode when sufficiently thick, and most closely resemble hydrous iridium(III,IV) oxide by voltammetry. The deposition rate and cyclic voltammetric response of the electrodeposited material depend on whether the precursor complex contains a pentamethylcyclopentadieneyl (Cp*) or cyclopentadienyl ligand (Cp), and do not match, in either case, iridium oxide anodes prepared from non-organometallic precursors. Here, we survey our organometallic precursors, iridium hydroxide, and pre-formed iridium oxide nanoparticles. From electrochemical quartz crystal nanobalance (EQCN) studies, we find differences in the rate of electrodeposition of catalyst layers from the two half-sandwich precursors; however, the resulting layers operate as water-oxidizing anodes with indistinguishable overpotentials and H/D isotope effects. Furthermore, using the mass data collected by EQCN and not otherwise available, we show that the electrodeposited materials are excellent catalysts for the water-oxidation reaction, showing maximum turnover frequencies greater than 0.5 mol O(2) (mol iridium)(-1) s(-1) and quantitative conversion of current to product dioxygen. Importantly, these anodes maintain their high activity and robustness at very low iridium loadings. Our organometallic precursors contrast with pre-formed iridium oxide nanoparticles, which form an unstable electrodeposited material that is not stably adherent to the anode surface at even moderately oxidizing potentials. 相似文献
165.
The effect of compatibility on the mechanical properties of polymer mixtures is discussed. From solution thermodynamics we conclude that for compatible mixtures of high molecular weight polymers the excess internal energy of mixing must be negative. For most polymer mixtures, this results in a negative excess volume of mixing. The excess entropy of mixing is therefore also negative. These general conclusions point to a stiffening of the solid lattice and a reduction in chain mobility. In dynamic mechanical behavior, the relaxation of molecular moieties responsible for the specific interaction should be shifted to intermediate temperatures, and the relaxation of other moieties should be shifted to higher temperatures if the potential well is inter-molecular. In finite deformation behavior craze initiation stress and shear yielding stress should both be higher than a linear combination of the properties of the pure components. 相似文献
166.
Molecular force probes conveniently report on mechanical stress and/or strain in polymers through straightforward visual cues. Unlike conventional mechanochromic mechanophores, the mechanically gated photoswitching strategy decouples mechanochemical activation from the ultimate chromogenic response, enabling the mechanical history of a material to be recorded and read on-demand using light. Here we report a completely redesigned, highly modular mechanophore platform for mechanically gated photoswitching that offers a robust, accessible synthesis and late stage diversification through Pd-catalyzed cross-coupling reactions to precisely tune the photophysical properties of the masked diarylethene (DAE) photoswitch. Using solution-phase ultrasonication, the reactivity of a small library of functionally diverse mechanophores is demonstrated to be exceptionally selective, producing a chromogenic response under UV irradiation only after mechanochemical activation, revealing colored DAE isomers with absorption spectra that span the visible region of the electromagnetic spectrum. Notably, mechanically gated photoswitching is successfully translated to solid polymeric materials for the first time, demonstrating the potential of the masked diarylethene mechanophore for a variety of applications in force-responsive polymeric materials.A highly modular and synthetically accessible mechanophore platform enables mechanically gated photoswitching in solution and in solid polymeric materials. 相似文献
167.
168.
This paper compares the viability of over 700 NG108 cells after membrane disruption either with a single 3 ns pulse at 337 nm or with a 5 ms train of 110 fs pulses (80 MHz) at 770 nm. Cell viability was monitored over a period of 12 h so as to understand the effect of laser ablation-induced cell apoptosis. The use of one-photon membrane disruption with the UV–laser resulted in ∼36% cell viability after 12 h while the use of two-photon ablation with the femtosecond laser resulted in a much higher viability of ∼79% after 12 h, which was the same within error of the ∼79% viability of cells in the control group. Changing the laser power to achieve a 90% probability of membrane disruption (PMD) from 50% PMD did not change the percentage of viable cells after 12 h, regardless of whether one- or two-photon ablation was employed. A systematic comparison between different methods of cellular ablation and their effect upon the viability of single cells has not been done before over such a long time frame. These results show the importance of laser choice when cell viability postsurgery is a concern. 相似文献
169.
Sun YE Piot P Johnson A Lumpkin AH Maxwell TJ Ruan J Thurman-Keup R 《Physical review letters》2010,105(23):234801
We report on the experimental generation of a train of subpicosecond electron bunches. The bunch train generation is accomplished using a beam line capable of exchanging the coordinates between the horizontal and longitudinal degrees of freedom. An initial beam consisting of a set of horizontally separated beamlets is converted into a train of bunches temporally separated with tunable bunch duration and separation. The experiment reported in this Letter unambiguously demonstrates the conversion process and its versatility. 相似文献
170.
Vasiliki Demas Anthony Bernhardt Vince Malba Kristl L. Adams Lee Evans Christopher Harvey Robert S. Maxwell Julie L. Herberg 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2009,200(1):56-63
Nuclear magnetic resonance (NMR) offers a non-destructive, powerful, structure-specific analytical method for the identification of chemical and biological systems. The use of radio frequency (RF) microcoils has been shown to increase the sensitivity in mass-limited samples. Recent advances in micro-receiver technology have further demonstrated a substantial increase in mass sensitivity [D.L. Olson, T.L. Peck, A.G. Webb, R.L. Magin, J.V. Sweedler, High-resolution microcoil H-1-NMR for mass-limited, nanoliter-volume samples, Science 270 (5244) (1995) 1967–1970]. Lithographic methods for producing solenoid microcoils possess a level of flexibility and reproducibility that exceeds previous production methods, such as hand winding microcoils. This paper presents electrical characterizations of RF microcoils produced by a unique laser lithography system that can pattern three dimensional surfaces and compares calculated and experimental results to those for wire wound RF microcoils. We show that existing optimization conditions for RF coil design still hold true for RF microcoils produced by lithography. Current lithographic microcoils show somewhat inferior performance to wire wound RF microcoils due to limitations in the existing electroplating technique. In principle, however, when the pitch of the RF microcoil is less than 100 μm lithographic coils should show comparable performance to wire wound coils. In the cases of larger pitch, wire cross sections can be significantly larger and resistances lower than microfabricated conductors. 相似文献