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161.
Capillary Electrophoresis Chiral Separation for Enantiomeric Purity Determination of a Basic Drug in Pharmaceutical Formulations 总被引:1,自引:0,他引:1
Capillary electrophoresis using a running buffer composed of β-cyclodextrin as the chiral selector and ethanolamine mesylate at pH 9.6 is being used to monitor the stereochemical stability of a hydrophobic drug, containing two chiral centers, in two different formulated self-emulsifying drug delivery system (SEDDS) products. The separation takes place in less than 25 min. Strategies for enhancing the method reproducibility and detection sensitivity in the lower potency formulation are presented. The results demonstrating the specificity, assay precision, recovery, linearity and range achieved during the method validation experiments are presented in this paper.Presented at: CE in the Biotechnology and Pharmaceutical Industries: 7th Symposium on the Practical Applications for the Analysis of Proteins, Nucleotides and Small Molecules, Montreal, Canada, August 12–16, 2005. 相似文献
162.
163.
J.R. Cooper 《Journal of Molecular Spectroscopy》2006,239(1):51-58
The ν9 fundamental band of ethane occurs in the 12 μm region. It is the strongest band of ethane in a terrestrial window and is commonly used for the identification of ethane in the Jovian planets. The ν9 + ν4 − ν4 band occurs in the same region; neither can be analysed as an isolated band, since both are embedded in the torsional bath of the ground vibrational state. We report here two global fit models including data from both of these bands as well as the ν3 fundamental and the ν4, 2ν4 − ν4, and 3ν4 torsional transitions. The first is restricted to −5 ? KΔK ? 15 in the hot band and gives an excellent fit to the included data. Three resonant interactions are identified in this fit—a Coriolis interaction with two resonant cases between the ν9 torsional stack and that of the ground vibrational state (gs) and a resonant Fermi interaction between the ν3 fundamental and the gs. Hot band lines with KΔK < −5 are influenced by a fourth perturbation, with a crossing at −11 < KΔK < −10, which has been attributed to an interaction with the ν12 fundamental. A second fit, demonstrating a promising treatment of this interaction, is also presented. 相似文献
164.
The present work has a double aim. On the one hand, we call attention on the relationship existing between the Ashtekar formalism and other gauge-theoretical approaches to gravity, in particular the Poincaré Gauge Theory. On the other hand, we study two kinds of solutions for the constraints of General Relativity, consisting of two mutually independent parts, namely a general three-metric-dependent contribution to the extrinsic curvature K
ab
in terms of the Cotton–York tensor, and besides it further metric independent contributions, which we analyze in particular in the presence of isotropic three-metrics. 相似文献
165.
E. V. Gromachevskaya A. G. Sakhabutdinov V. G. Kul'nevich I. S. Arustamova R. B. Valeev B. A. Bazhenov 《Chemistry of Heterocyclic Compounds》1991,27(5):502-503
It was shown that the reaction of o-hyroxyphenyldiphenylmethanol with benzaldehyde labeled with 17O and 18O isotopes proceeds in such a way that oxygen atoms of the starting phenoloalcohol are retained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 632–633, May, 1991. 相似文献
166.
Procedures for enhancing the intelligibility of a target talker in the presence of a co-channel competing talker were evaluated in tests involving (i) continuously voiced sentences spoken on a monotone, (ii) continuously voiced sentences with time-varying intonation, and (iii) noncontinuously voiced sentences produced with natural intonation. The procedures were based on the methods of harmonic selection and cepstral filtering [R.J. Stubbs and Q. Summerfield, J. Acoust. Soc. Am. 87, 359-372 (1990)]. Target and competing voices were combined at signal-to-noise ratios (SNRs) between -10 dB and +10 dB. Subjects were a group with normal hearing and a heterogeneous group with mild-moderate cochlear hearing impairments. Processing enhanced the target voice over a range of SNRs for each type of sentence and for most listeners. Enhancement was greatest at negative SNRs. Among the impaired listeners, benefit was generally greater for those with milder losses. These results consolidate and extend previous demonstrations that voice-separation algorithms that exploit the harmonic structure of the voiced portions of speech can enhance intelligibility. However, practical application of such algorithms depends on a solution to the problem of tracking the fundamental-frequency contour of one voice in the presence of a competing voice. 相似文献
167.
The instability of the plane interface between two uniform, superposed, electrically conducting and counter-streaming fluids through a porous medium is considered in the presence of a horizontal magnetic field. In the absence of surface tension, perturbations transverse to the direction of streaming are found to be unaffected by the presence of streaming if perturbations in the direction of streaming are ignored. For perturbations in all other directions there exists instability for a certain wavenumber range. The instability of this system is postponed by the presence of magnetic field. The magnetic field and surface tension are able to suppress this Kelvin-Helmholtz instability for small wavelength perturbations and the medium porosity reduces the stability range given in terms of a difference between the streaming velocities and the Alfvén velocity.This research forms a part of the research project awarded to the first author (R.C.S.) by the University Grants Commission. 相似文献
168.
A full exposition of the authors' previously announced results about the extremality index of controls in smooth control systems and a generalization of these results to systems with constraints on the controls.Translated from Itogi Nauki i Tekhniki, Seriya Sovremennye Problemy Matematiki, Noveishie Dostizheniya, Vol. 35, pp. 109–134, 1989. 相似文献
169.
170.
Bairamov R. K. Ermakov A. I. Vedernikova N. R. 《Russian Journal of Applied Chemistry》2002,75(3):408-410
The influence exerted by the nature and concentration of a number of organic and mineral acids on the composition of products formed in electric-spark dispersion of aluminum was studied. 相似文献