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981.
Max Ziegler und Günter Pape 《Fresenius' Journal of Analytical Chemistry》1963,196(4):241-246
Zusammenfassung Unter den Hexamethonium [HM]-Übergangsmetall-Halogeniden, bzw. Halogenoiden, von welchen eine Reihe der komplexen Rhodanide beschrieben werden, sind die Verbindungen [HM][PtCl6], [HM][PdCl4] und [HM][IrCl6] zum Nachweis der betreffenden Platinmetalle mit Empfindlichkeiten zwischen 0,2 und 3g Metall geeignet. Das Hexamethonium-Ion kann als [HM][Cr(NCS)4(NH3)2]2 in Mengen ab 1,5 mg gravimetrisch bestimmt werden.
II. Teil:Ziegler, M., u. G.Pape 1.
HerrWolfgang Renner hat in dankenswerter Weise Darstellung und Analysen der Rhodanokomplexe ausgeführt. 相似文献
Summary The hexamethonium [HM] compounds of transition metal halogenides and halogenoides have been examined and some complex rhodanides have been described. The compounds [HM][PtCl6], [HM][PdCl4], and [HM][IrCl6] have proved to be suitable for the detection of the metals concerned with sensitivities between 0,2 and 3g of the metal. The gravimetric determination of the hexamethonium ion in quantities above 1.5mg has been achieved by help of the compound [HM][Cr(NCS)4(NH3)2]2.
II. Teil:Ziegler, M., u. G.Pape 1.
HerrWolfgang Renner hat in dankenswerter Weise Darstellung und Analysen der Rhodanokomplexe ausgeführt. 相似文献
982.
983.
984.
Max Roha 《Algebra Universalis》1960,1(4):512-539
Conclusions This review has brought together the diverse ionic initiators for dienes into a consistent series of four polymerization mechanisms. The ionic freedom characteristic of the electrophilic and free anionic initiators catalyze the rapid formation of 1–4 trans structures. Coordinate initiation produces 1–4 cis structures via a cyclic transition state while anionic initiation produces 1–2 (3–4) structures.The catalytic activity in the coordinate and anionic catalysts depends largely on complex formation. The equilibrium characteristics of complex formation produces the different rate, structure and molecular weight effects observed in coordinate initiation studies.I wish to thank Drs. P. H.Moyer and M. R.Frederick for many helpful discussions of the mechanisms of coordinate polymerizations. 相似文献
985.
Otto Hromatka Max Knollmüller Fritz Sauter 《Monatshefte für Chemie / Chemical Monthly》1962,93(4):807-813
Zusammenfassung Es wird über die Einführung weiterer Substituenten, z. B. Cyanäthyl und Aminopropyl, in Piperazinylalkylphenthiazine und -Piperazinyl-4,10-trimethylenphenthiazin berichtet.18. Mitt. dieser Reihe:O. Hromatka, M. Knollmüller undF. Sauter, Mh. Chem.93, 723 (1962). 相似文献
986.
F. Fehér Max Boëtius A. Schneider O. Faust H. Wienhaus 《Colloid and polymer science》1940,92(2):252-256
Ohne Zusammenfassung 相似文献
987.
988.
David J. Harvey Gemma E. Seabright Snezana Vasiljevic Max Crispin Weston B. Struwe 《Journal of the American Society for Mass Spectrometry》2018,29(5):972-988
Extracted arrival time distributions of negative ion CID-derived fragments produced prior to traveling-wave ion mobility separation were evaluated for their ability to provide structural information on N-linked glycans. Fragmentation of high-mannose glycans released from several glycoproteins, including those from viral sources, provided over 50 fragments, many of which gave unique collisional cross-sections and provided additional information used to assign structural isomers. For example, cross-ring fragments arising from cleavage of the reducing terminal GlcNAc residue on Man8GlcNAc2 isomers have unique collision cross-sections enabling isomers to be differentiated in mixtures. Specific fragment collision cross-sections enabled identification of glycans, the antennae of which terminated in the antigenic α-galactose residue, and ions defining the composition of the 6-antenna of several of the glycans were also found to have different cross-sections from isomeric ions produced in the same spectra. Potential mechanisms for the formation of the various ions are discussed and the estimated collisional cross-sections are tabulated. 相似文献
989.
Ultraparamagnetic Cells Formed through Intracellular Oxidation and Chelation of Paramagnetic Iron 下载免费PDF全文
Pradeep Ramesh Dr. Son‐Jong Hwang Hunter C. Davis Audrey Lee‐Gosselin Vivek Bharadwaj Max A. English Jenny Sheng Vasant Iyer Prof. Mikhail G. Shapiro 《Angewandte Chemie (International ed. in English)》2018,57(38):12385-12389
Making cells magnetic is a long‐standing goal of chemical biology, aiming to enable the separation of cells from complex biological samples and their visualization in vivo using magnetic resonance imaging (MRI). Previous efforts towards this goal, focused on engineering cells to biomineralize superparamagnetic or ferromagnetic iron oxides, have been largely unsuccessful due to the stringent required chemical conditions. Here, we introduce an alternative approach to making cells magnetic, focused on biochemically maximizing cellular paramagnetism. We show that a novel genetic construct combining the functions of ferroxidation and iron chelation enables engineered bacterial cells to accumulate iron in “ultraparamagnetic” macromolecular complexes, allowing these cells to be trapped with magnetic fields and imaged with MRI in vitro and in vivo. We characterize the properties of these cells and complexes using magnetometry, nuclear magnetic resonance, biochemical assays, and computational modeling to elucidate the unique mechanisms and capabilities of this paramagnetic concept. 相似文献
990.
Mimicking Class I b Mn2‐Ribonucleotide Reductase: A MnII2 Complex and Its Reaction with Superoxide 下载免费PDF全文
Adriana M. Magherusan Ang Zhou Erik R. Farquhar Max García‐Melchor Brendan Twamley Lawrence Que Jr. Aidan R. McDonald 《Angewandte Chemie (International ed. in English)》2018,57(4):918-922
A fascinating discovery in the chemistry of ribonucleotide reductases (RNRs) has been the identification of a dimanganese (Mn2) active site in class I b RNRs that requires superoxide anion (O2.?), rather than dioxygen (O2), to access a high‐valent Mn2 oxidant. Complex 1 ([Mn2(O2CCH3)(N‐Et‐HPTB)](ClO4)2, N‐Et‐HPTB=N,N,N′,N′‐tetrakis(2‐(1‐ethylbenzimidazolyl))‐2‐hydroxy‐1,3‐diaminopropane) was synthesised in high yield (90 %). 1 was reacted with O2.? at ?40 °C resulting in the formation of a metastable species ( 2 ). 2 displayed electronic absorption features (λmax=460, 610 nm) typical of a Mn‐peroxide species and a 29‐line EPR signal typical of a MnIIMnIII entity. Mn K‐edge X‐ray absorption near‐edge spectroscopy (XANES) suggested a formal oxidation state change of MnII2 in 1 to MnIIMnIII for 2 . Electrospray ionisation mass spectrometry (ESI‐MS) suggested 2 to be a MnIIMnIII‐peroxide complex. 2 was capable of oxidizing ferrocene and weak O?H bonds upon activation with proton donors. Our findings provide support for the postulated mechanism of O2.? activation at class I b Mn2 RNRs. 相似文献