全文获取类型
收费全文 | 1655篇 |
免费 | 49篇 |
国内免费 | 5篇 |
专业分类
化学 | 1298篇 |
晶体学 | 12篇 |
力学 | 82篇 |
数学 | 170篇 |
物理学 | 147篇 |
出版年
2023年 | 11篇 |
2022年 | 38篇 |
2021年 | 33篇 |
2020年 | 17篇 |
2019年 | 25篇 |
2018年 | 13篇 |
2017年 | 18篇 |
2016年 | 43篇 |
2015年 | 48篇 |
2014年 | 41篇 |
2013年 | 70篇 |
2012年 | 92篇 |
2011年 | 94篇 |
2010年 | 66篇 |
2009年 | 45篇 |
2008年 | 126篇 |
2007年 | 120篇 |
2006年 | 120篇 |
2005年 | 111篇 |
2004年 | 105篇 |
2003年 | 72篇 |
2002年 | 66篇 |
2001年 | 35篇 |
2000年 | 19篇 |
1999年 | 17篇 |
1998年 | 22篇 |
1997年 | 13篇 |
1996年 | 33篇 |
1995年 | 19篇 |
1994年 | 15篇 |
1993年 | 12篇 |
1992年 | 9篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1986年 | 5篇 |
1985年 | 12篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1981年 | 18篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 8篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1971年 | 3篇 |
1929年 | 3篇 |
排序方式: 共有1709条查询结果,搜索用时 15 毫秒
51.
Francesca Di Gaudio Sergio Indelicato Roberto Monastero Grazia Ida Altieri Francesca Fayer Ornella Palesano Manuela Fontana Angelo B. Cefalù Massimiliano Greco David Bongiorno Serena Indelicato Angela Aronica Davide Noto Maurizio R. Averna 《Analytical and bioanalytical chemistry》2016,408(9):2215-2226
52.
Dr. Peter Wick Dr. Anna E. Louw‐Gaume Dr. Melanie Kucki Prof. Harald F. Krug Prof. Kostas Kostarelos Prof. Bengt Fadeel Prof. Kenneth A. Dawson Dr. Anna Salvati Prof. Ester Vázquez Dr. Laura Ballerini Dr. Mauro Tretiach Dr. Fabio Benfenati Dr. Emmanuel Flahaut Dr. Laury Gauthier Prof. Maurizio Prato Dr. Alberto Bianco 《Angewandte Chemie (International ed. in English)》2014,53(30):7714-7718
53.
54.
Camille Descour Tibor Macko Dario Cavallo Matthew Parkinson Gerhard Hubner Anne Spoelstra Maurizio Villani Robbert Duchateau 《Journal of polymer science. Part A, Polymer chemistry》2014,52(10):1422-1434
Stereoblock polypropylenes comprising of iPP and sPP segments are synthesized by polymerization of the following binary system of metallocenes: the Cs‐symmetric [2,7‐t‐Bu2(Flu)2Ph2C(Cp)ZrCl2] and the C2‐symmetric rac‐Me2Si(2‐Me‐4‐Ph‐Ind)2ZrCl2. Blends of samples made either by each catalyst individually (solution blend) with materials obtained with the mixed catalyst system (reactor blend) are compared. The simultaneous presence of MAO and DEZ, enhancing fast and reversible transfer of the growing chains between the two active centers, leads to the formation of a stereoblock microstructure. In this case, low molecular weight polymers are obtained. The junction between the blocks is qualitatively observed in 13C NMR. When made in toluene, the stereoblock material consists of a majority of syndiotactic sequences, whereas the ratio is more equilibrated when the polymerization was conducted in the more polar chlorobenzene. This is confirmed by the results obtained with 13C NMR, CRYSTAF, HT HPLC, DSC, SSA, WAXD, and optical microscopy. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1422–1434 相似文献
55.
Paulo R. Olivato Mirta G. Mondino Giuseppe Distefano Maurizio Dal Colle Gabriella Bombieri Antonio Del Pra 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):443-444
ABSTRACT. The analysis of the carbonyl I.R. band and the U.V. phoelectron spectroscopic data along with the ab-initio calculations and X-ray diffraction of α-(methylsulfinyl)- and α-(phenylsulfinyl)-acetophenones indicated the predominance of the cis rotamers over the qauche ones. 相似文献
56.
57.
Caterina Fraschetti Antonello Filippi Maria Elisa Crestoni Tadashi Ema Maurizio Speranza 《Journal of the American Society for Mass Spectrometry》2013,24(4):573-578
The most common protocols for the quantitative determination of the enantiomeric excess (ee) of raw mixtures by ESI-MS reveal inadequate in cases where the distribution of diastereomeric derivatives diverges from the ee of original solutions. This phenomenon is attributable to a matrix effect, i.e., to the stereospecific formation of high order noncovalent adducts in the ESI droplets, which alters the actual availability of the diastereomeric species under MS analysis. In this frame, the assumption of classic protocols that the ionization correction factor q is independent on the composition of the mixture submitted to analysis is questionable. An alternative methodology is presented in this paper, which is aimed at circumventing the problem by excluding any chemical derivatization of the original raw mixture. It is based on the measurement of the actual distribution of ESI-formed proton-bound diastereomeric complexes from the enantiomeric mixture through a careful analysis of their reaction kinetics with a suitable reactant. 相似文献
58.
59.
The synthesis of the title compound is described. The key-step is the photochemical coupling between 5-iodo-2-thienylcarbaldehyde and 2-bromothio-phene to give 5-bromo-2,2′-bithienyl-5′-carbaldehyde. 相似文献
60.
Prof. Giuseppe Alibrandi Dr. Valeria Amendola Dr. Greta Bergamaschi Dr. Riccardo Dollenz Prof. Luigi Fabbrizzi Prof. Maurizio Licchelli Dr. Carmelo Lo Vecchio 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(11):3729-3734
The combined activity of the 1.1.1‐cryptand and of a dicopper(II) bistren cryptate complex including chloride makes the Cl? ion be continuously and slowly delivered to the solution, without any external intervention. The 1.1.1‐cryptand slowly releases OH? ions, according to a defined kinetics, and each OH? ion displaces a Cl? ion from the cryptate. Chloride displacement induces a sharp colour change from bright yellow to aquamarine and can be conveniently monitored spectrophotometrically, even in diluted solutions. The 1.1.1‐cryptand is the motor of a molecular dispenser (the dicopper(II) cryptate) delivering chloride ion automatically, from the inside of the solution. 相似文献