Dielectric relaxation phenomena of rigid polar liquid molecules under giga hertz electric field

The dielectric relaxation phenomena of rigid polar liquid molecules chloral and ethyltrichloroacetate (j) in benzene, n-hexane and n-heptane (i) under 4.2, 9.8 and 24.6 GHz electric fields at 30°C are studied to show the possible existence of double relaxation times τ ₂ and τ ₁ for rotations of the whole and the flexible parts of molecules. The probability of showing double relaxation is more in aliphatic solvents indicating their nonrigidity. The symmetric and asymmetric distribution parameters γ and δ are obtained from X _ij ^′ /X _0ij and X _ij ^″ /X _0ij and w _j →0 where X _ij ^′ and X _ij ^″ are real and imaginary parts of the complex orientational susceptibility X _i ^* and X _0ij is the low frequency susceptibility which is real. X _ij ’s are involved with the measured dielectric relative permittivities ε _ij ^′ , ε _in ^″ , ε _0ij and ε _∞ij of solutions. The theoretical weighted contributions c ₁ and c ₂ towards dielectric dispersions by Fröhlich’s method are compared with the experimental ones obtained from the graphical variation of X _ij ^′ /X _0ij and X _ij ^″ /X _0ij with weight fractions w _j ’s at w _j → 0. The measured dipole moments μ ₂ and μ ₁ of the whole and the flexible part of a polar molecule in terms of the linear coefficients β’s of X _ij ^′ ’s with w _j ’s and the estimated τ ₂ and τ ₁ reveal their associations with aliphatic solvents. The theoretical dipole moments μ _theo’s from the available bond angles and bond moments of the substituent polar groups of the molecules with the estimated μ’s suggest the mesomeric, inductive and electromeric effects in them under GHz electric field.     

The Optical Frequency Standards for the Realization of the Meter

Optical‐frequency standards with various levels of performance are indispensable in metrology and have many applications from length measurement to atomic clocks and much more. The evolution of optical‐frequency standards has been considerable. Originally introduced as primary realizations for the meter, they have evolved to optical clocks, which surpass the uncertainty and stability of microwave clocks. Herein, the status of the development of optical‐frequency standards as far as length metrology is concerned is reviewed, giving a broad overview of the historical context, as well as an outlook about future evolution.     

Isomerisierung von (all-E)-Cycloviolaxanthin Herstellung und Charakterisierung von (9Z)-und (13Z)-Cycloviolaxanthin

Isomerization of (all-E)-Cycloviolaxanthin. Preparation and Characterization of (9Z)- and (13Z)-Cycloviolaxanthin From (all-E)-cycloviolaxanthin (ex Capsicum annuum), (9Z)- and (13Z)-cycloviolaxanthin were prepared in a highly pure state. The configuration of both isomers was determined by means of UV/VIS, NMR, and CD spectroscopy.     

Ammonolysis ofβ,β-dichloroalkylsilylethyl vinyl ethers

Conclusions Tri- and tetracyclosilazanes, containing vinyloxyethyl substituents attached to the silicon atom, were synthesized by the reaction of-(alkyldichlorosilyl)ethyl vinyl ethers with ammonia.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1664–1665, July, 1973.     

Steady-state vibrations of a thin two-layer plate with delamination

We consider the problem of harmonic vibrations of a thin two-layer plate with horizontal crack. The problem is solved with the help of the null-field approach. The influence of the shape of the crack contour on the amplitude-frequency characteristics of plate vibrations is investigated. Institute of Mathematics, Ukrainian Academy of Sciences, Kiev. Translated from Matematychni Metody ta Fizyko-Mekhanichni Polya, Vol. 41, No. 2, pp. 83–89, April–June, 1998.     

Efficient Transformation of Furfuryl Alcohol Into Ethyl Levulinates via Alcoholysis Reaction Catalyzed by SnO2/H-Mordenite Catalyst

Catalysis Surveys from Asia - Catalytic production of ethyl levulinate by alcoholysis of furfuryl alcohol with ethanol was investigated over H-mordenite supported Sn catalyst under atmospheric N2...