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101.
Caitlin N. Rinke Mary R. Williams Christopher Brown Matthieu Baudelet Martin Richardson Michael E. Sigman 《Analytica chimica acta》2012
A method is described for performing discriminant analysis in the presence of interfering background signal. The method is based on performing target factor analysis on a data set comprised of contributions from analyte(s) and interfering components. A library of data from representative analyte classes is tested for possible contributing factors by performing oblique rotations of the principal factors to obtain the best match, in a least-squares sense, between test and predicted vectors. The degree of match between the test and predicted vectors is measured by the Pearson correlation coefficient, r, and the distribution of r for each class is determined. A Bayesian soft classifier is used to calculate the posterior probability based on the distributions of r for each class, which assist the analyst in assessing the presence of one or more analytes. The method is demonstrated by analyses performed on spectra obtained by laser induced breakdown spectroscopy (LIBS). Single and multiple bullet jacketing transfers to steel and porcelain substrates were analyzed to identify the jacketing materials. Additionally, the metal surrounding bullet holes was analyzed to identify the class of bullet jacketing that passed through a stainless steel plate. Of 36 single sample transfers, the copper jacketed (CJ) and non-jacketed (NJ) class on porcelain had an average posterior probability of the metal deposited on the substrate of 1.0. Metal jacketed (MJ) bullet transfers to steel and porcelain were not detected as successfully. Multiple transfers of CJ/NJ and CJ/MJ on the two substrates resulted in posterior probabilities that reflected the presence of both jacketing materials. The MJ/NJ transfers gave posterior probabilities that reflected the presence of the NJ material, but the MJ component was mistaken for CJ on steel, while non-zero probabilities were obtained for both CJ and MJ on porcelain. Jacketing transfer from a bullet to steel as the projectile passed through the steel also proved difficult to analyze. Over 50% of the samples left insufficient transfer to be identified. Transfer from NJ and CJ jacketing was successfully identified by posterior probabilities greater than 0.8. 相似文献
102.
Stijn Dekeukeleire Matthias D’hooghe Matthieu Vanwalleghem Willem Van Brabandt Norbert De Kimpe 《Tetrahedron》2012,68(52):10827-10834
Chiral piperazine and 1,4-diazepane annulated β-lactams, prepared from the corresponding (3R,4S)-4-imidoyl-1-(ω-haloalkyl)azetidin-2-ones through reduction with sodium borohydride in ethanol, were transformed into novel methyl (R)-alkoxy-[(S)-piperazin-2-yl]acetates and methyl (R)-alkoxy-[(S)-1,4-diazepan-2-yl]acetates upon treatment with hydrogen chloride in methanol. On the other hand, bromination of (3R,4R)-1-allyl-4-formyl-β-lactams and (3R,4S)-1-allyl-4-imidoyl-β-lactams in dichloromethane, followed by sodium borohydride reduction of the resulting dibrominated azetidin-2-ones in ethanol, did not afford the envisaged bicyclic β-lactams but unexpectedly furnished (3R,4S)-1-(2-bromo-2-propenyl)azetidin-2-ones instead. 相似文献
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Nadini Matthieu Bongiorno Christian Rizzo Alessandro Porfiri Maurizio 《Nonlinear dynamics》2020,99(1):855-878
Nonlinear Dynamics - Many real systems can be described through time-varying networks of interactions that encapsulate information sharing between individual units over time. These interactions can... 相似文献
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Matthieu Simon 《Stochastics An International Journal of Probability and Stochastic Processes》2020,92(2):275-296
ABSTRACTWe consider a one-sided Markov-modulated Brownian motion perturbed by catastrophes that occur at some rates depending on the modulating process. When a catastrophe occurs, the level drops to zero for a random recovery period. Then the process evolves normally until the next catastrophe. We use a semi-regenerative approach to obtain the stationary distribution of this perturbed MMBM. Next, we determine the stationary distribution of two extensions: we consider the case of a temporary change of regime after each recovery period and the case where the catastrophes can only happen above a fixed threshold. We provide some simple numerical illustrations. 相似文献
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Dr. Matthieu Fonvielle Dr. Inés Li de La Sierra‐Gallay Dr. Afaf H. El‐Sagheer Maxime Lecerf Delphine Patin Dr. Dénia Mellal Dr. Claudine Mayer Dr. Didier Blanot Dr. Nittaya Gale Dr. Tom Brown Dr. Herman van Tilbeurgh Dr. Mélanie Ethève‐Quelquejeu Dr. Michel Arthur 《Angewandte Chemie (International ed. in English)》2013,52(28):7278-7281
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