全文获取类型
收费全文 | 442篇 |
免费 | 41篇 |
国内免费 | 1篇 |
专业分类
化学 | 303篇 |
晶体学 | 2篇 |
力学 | 28篇 |
数学 | 90篇 |
物理学 | 61篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 7篇 |
2021年 | 18篇 |
2020年 | 12篇 |
2019年 | 14篇 |
2018年 | 13篇 |
2017年 | 4篇 |
2016年 | 25篇 |
2015年 | 26篇 |
2014年 | 28篇 |
2013年 | 28篇 |
2012年 | 47篇 |
2011年 | 61篇 |
2010年 | 29篇 |
2009年 | 19篇 |
2008年 | 31篇 |
2007年 | 30篇 |
2006年 | 18篇 |
2005年 | 16篇 |
2004年 | 12篇 |
2003年 | 4篇 |
2002年 | 10篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 4篇 |
1993年 | 1篇 |
1988年 | 1篇 |
1984年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有484条查询结果,搜索用时 519 毫秒
41.
We study in this paper the movement of a rigid solid inside an incompressible Navier‐Stokes flow within a bounded domain. We consider the case where slip is allowed at the fluid/solid interface through a Navier condition. Taking into account slip at the interface is very natural within this model, as classical no‐slip conditions lead to unrealistic collisional behavior between the solid and the domain boundary. We prove for this model existence of weak solutions of Leray type, up to collision, in three dimensions. The key point is that, due to the slip condition, the velocity field is discontinuous across the fluid/solid interface. This prevents obtaining global H1 bounds on the velocity, which makes many aspects of the theory of weak solutions for Dirichlet conditions inappropriate. © 2014 Wiley Periodicals, Inc. 相似文献
42.
Matthieu Gendulphe 《Mathematische Annalen》2011,350(4):919-951
We introduce a new tool, the contiguity graph, which enables us to determine the Bers’s constant in genus two. 相似文献
43.
44.
45.
46.
David Gérard-Varet Matthieu Hillairet 《Archive for Rational Mechanics and Analysis》2010,195(2):375-407
We investigate the evolution of rigid bodies in a viscous incompressible fluid. The flow is governed by the 2D Navier–Stokes equations, set in a bounded domain with Dirichlet boundary conditions. The boundaries of the solids and the domain have Hölder regularity C 1,α , 0 < α ≦ 1. First, we show the existence and uniqueness of strong solutions up to the collision. A key ingredient is a BMO bound on the velocity gradient, which substitutes to the standard H 2 estimate for smoother domains. Then, we study the asymptotic behaviour of one C 1,α body falling over a flat surface. We show that a collision is possible in finite time if and only if α < 1/2. 相似文献
47.
We report an intrinsically stable quantum key distribution scheme based on genuine frequency-coded quantum states. The qubits are efficiently processed without fiber interferometers by fully exploiting the nonlinear interaction occurring in electro-optic phase modulators. The system requires only integrated off-the-shelf devices and could be used with a true single-photon source. Preliminary experiments have been performed with weak laser pulses and have demonstrated the feasibility of this new setup. 相似文献
48.
Sonja Kracht Dr. Matthias Messerer Dr. Matthieu Lang Dr. Sonja Eckhardt Dr. Miriam Lauz Prof. Bernard Grobéty Prof. Katharina M. Fromm Prof. Bernd Giese 《Angewandte Chemie (International ed. in English)》2015,54(10):2912-2916
Some microorganisms perform anaerobic mineral respiration by reducing metal ions to metal nanoparticles, using peptide aggregates as medium for electron transfer (ET). Such a reaction type is investigated here with model peptides and silver as the metal. Surprisingly, Ag+ ions bound by peptides with histidine as the Ag+‐binding amino acid and tyrosine as photoinducible electron donor cannot be reduced to Ag nanoparticles (AgNPs) under ET conditions because the peptide prevents the aggregation of Ag atoms to form AgNPs. Only in the presence of chloride ions, which generate AgCl microcrystals in the peptide matrix, does the synthesis of AgNPs occur. The reaction starts with the formation of 100 nm Ag@AgCl/peptide nanocomposites which are cleaved into 15 nm AgNPs. This defined transformation from large nanoparticles into small ones is in contrast to the usually observed Ostwald ripening processes and can be followed in detail by studying time‐resolved UV/Vis spectra which exhibit an isosbestic point. 相似文献
49.
M. Sc. Yasemin Akbulut Hannah J. Gaunt Prof. Katsuhiko Muraki Dr. Melanie J. Ludlow Dr. Mohamed S. Amer Dr. Alexander Bruns Dr. Naveen S. Vasudev Dr. Lea Radtke Dr. Matthieu Willot M. Sc. Sven Hahn M. Sc. Tobias Seitz Dr. Slava Ziegler Prof. Dr. Mathias Christmann Prof. Dr. David J. Beech Prof. Dr. Herbert Waldmann 《Angewandte Chemie (International ed. in English)》2015,54(12):3787-3791
Current therapies for common types of cancer such as renal cell cancer are often ineffective and unspecific, and novel pharmacological targets and approaches are in high demand. Here we show the unexpected possibility for the rapid and selective killing of renal cancer cells through activation of calcium‐permeable nonselective transient receptor potential canonical (TRPC) calcium channels by the sesquiterpene (?)‐englerin A. This compound was found to be a highly efficient, fast‐acting, potent, selective, and direct stimulator of TRPC4 and TRPC5 channels. TRPC4/5 activation through a high‐affinity extracellular (?)‐englerin A binding site may open up novel opportunities for drug discovery aimed at renal cancer. 相似文献
50.
Dr. Vivien Rauch Dr. Yoshihiro Kikkawa Dr. Matthieu Koepf Dr. Ismail Hijazi Dr. Jennifer A. Wytko Dr. Stéphane Campidelli Antoine Goujon Dr. Masatoshi Kanesato Dr. Jean Weiss 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(38):13437-13444
The assembly of imidazole‐functionalized phenanthroline‐strapped zinc porphyrins (ZnPorphen) with alkyl or polyethylene glycol (PEG) side chains was studied in solution and by AFM after casting on highly oriented pyrolytic graphite (HOPG) or mica. The nature of the solvent and its evaporation time influenced the morphology of the objects observed. On HOPG, short rods of about 100 nm were observed after fast evaporation of solutions of the alkyl derivatives in CHCl3, THF, or pyridine, whereas islands of aligned rows of longer wires were obtained from methylcyclohexane (MCH). Slow evaporation of MCH led to a three‐dimensional assembly. The PEG porphyrin assembled into short wires on HOPG or fibers on mica after slow evaporation of solutions in THF. This study shows the role of surface–molecule interactions in the interfacial assembly of ZnPorphen derivatives and contributes to understanding the parameters that control their noncovalent assembly into molecular wires on a surface. 相似文献